1. Identification of the substance/preparation and of the company/undertaking

Transcription

1 1. Identification of the substance/preparation and of the company/undertaking Identification of the substance or preparation Use of the substance/preparation Disinfectant for hands Company/undertaking identification Manufacturer Sint-Annadreef 68 b B-1020 Brussels Telephone: Telefax: info@saraya-europe.com Responsible Department: Emergency telephone number: (001) Responsible for the safety data sheet: sds@gbk-ingelheim.de 2. Hazards identification Classification Indications of danger : Irritant R-phrases: Flammable. Risk of serious damage to eyes. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Vapours may cause drowsiness and dizziness.. Composition/information on ingredients Chemical characterization ( Mixture ) Alcoholic, aqueous solution Hazardous components EC-No. CAS-No. Chemical name Quantity Classification Propan-2-ol < 65 % F, Xi R Propan-1-ol < 15 % F, Xi R Polyaminopropyl biguanide < 0,25 % Xn, Xi, N R Full text of each relevant R phrase can be found in heading First aid measures General information Remove contaminated soaked clothing immediately. If you feel unwell, seek medical advice. After inhalation Move to fresh air in case of accidental inhalation of vapours. In the event of symptoms refer for medical treatment. After contact with skin No specific precautions required. After contact with eyes Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek medical treatment by eye specialist. GB - EN Page 1 of 7

2 After ingestion Do not provoke vomiting. Consult physician. Attention in case of vomiting - acute danger of suffocating, produced by foaming ingredients. Rinse mouth. Make drink some glasses of water. The decision whether to provoke vomiting is to be taken by a physician. 5. Fire-fighting measures Suitable extinguishing media Alcohol-resistant foam, dry chemical, carbon dioxide (CO2), water-spray. Extinguishing media which must not be used for safety reasons Full water jet. Special exposure hazards arising from substance or preparation itself, combustion products, resulting gases Fire may produce: Carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx). Chlorine compounds Special protective equipment for fire-fighters Use breathing apparatus with independent air supply. Protective suit. Additional information Vapours are heavier than air and spread along ground. The vapour/air mixture is explosive, even in empty, uncleaned receptacles. Cool containers at risk with water spray jet. Fire residues and contaminated firefighting water must be disposed of in accordance with the local regulations. 6. Accidental release measures Personal precautions In case of vapour formation use respirator. Keep away from heat and sources of ignition. Do not smoke. Ensure adequate ventilation. Environmental precautions Do not discharge into the drains/surface waters/groundwater. Methods for cleaning up/taking up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder). Shovel into suitable container for disposal. 7. Handling and storage Handling Advice on safe handling Ensure adequate ventilation. Keep container tightly closed in a dry, cool and well-ventilated place. When using, do not eat, drink or smoke. Avoid contact with eyes. Advice on protection against fire and explosion Keep product and empty container away from heat and sources of ignition. Do not smoke - volatile. Storage Requirements for storage rooms and vessels Keep container tightly closed in a dry, cool and well-ventilated place. Ensure adequate ventilation, especially in confined areas. Advice on storage compatibility Incompatible with: GB - EN Page 2 of 7

3 Oxidizing agents. Alkaline metals and earth alkaline metals. Further information on storage conditions Keep away from food, drink and animal feeding stuffs. 8. Exposure controls/personal protection Exposure limit values Exposure limits (EH40) CAS-No. Chemical name ml/m³ mg/m³ F/ml Category Origin Propan-1-ol TWA (8 h) WEL STEL (15 min) WEL Propan-2-ol TWA (8 h) WEL Occupational exposure controls Ensure adequate ventilation, especially in confined areas. Protective and hygiene measures Do not inhale vapours. When using, do not eat, drink or smoke. Take off immediately all contaminated clothing. Avoid contact with eyes. Wash hands before breaks and at the end of workday. Respiratory protection No personal respiratory protective equipment normally required. Breathing apparatus in the event of aerosol or mist formation STEL (15 min) WEL Hand protection Protective gloves resistant to chemicals made off butyl, Minimum coat thickness 0,7 mm, Permeation resistance (wear duration) approx. 480 minutes, i.e. protective glove <Butoject 898> made by This recommendation refers exclusively to the chemical compatibility and the lab test conforming to EN 74 carried out under lab conditions. Requirements can vary as a function of the use. Therefore it is necessary to adhere additionally to the recommendations given by the manufacturer of protective gloves. Eye protection Safety goggles with side protection. Eye wash bottle with pure water. Skin protection Long sleeved clothing. 9. Physical and chemical properties General information Physical state: Colour: Odour: Liquid Colourless Alcoholic Important health, safety and environmental information Changes in the physical state Boiling point: Flash point: Lower explosion limits: Upper explosion limits: Test method 82 C *) 21,5 C n.d. GB - EN Page of 7

4 Vapour pressure: (at 20 C) Density (at 25 C): Water solubility: (at 20 C) Solvent content < 80 % Other information Ignition temperature: *) Propan-2-ol 42 hpa *) 0,86 g/cm³ Miscible n.d. 10. Stability and reactivity Conditions to avoid Vapour/air mixtures are explosive at intensive warming. Heating can release vapours which can be ignited. Materials to avoid Oxidizing agents. Alkaline metals and alkaline earth metals. Hazardous decomposition products Carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx) Chlorine compounds Additional information No decomposition if stored and applied as directed. 11. Toxicological information Empirical data on effects on humans Risk of serious damage to eyes. Vapours may cause drowsiness and dizziness. Inhalation of vapours in high concentration can cause narcotic effects. Repeated or prolonged exposure may cause skin irritation and dermatitis, due to degreasing properties of the product. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Further information No toxicological data available. 12. Ecological information Ecotoxicity Polyaminopropyl biguanide LC50/Oncorhynchus mykiss/96 h = 0,026 mg/l EC50/Daphnia magna/48 h = 0,09 mg/l [OECD 202] ErC50/Pseudokirchneriela subcapitata/72 h = 0,0191 mg/l [OECD 201] Other adverse effects Low hazard to waters. Further information This concentrate is not allowed to be released into the sewerage, surface water or groundwater. Low hazard to waters. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Ecological injuries are not known or expected under normal use. 1. Disposal considerations Advice on disposal Can be incinerated, when in compliance with local regulations. Where possible recycling is preferred to disposal. GB - EN Page 4 of 7

5 Waste disposal number of waste from residues/unused products WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of fats, grease, soaps, detergents, disinfectants and cosmetics; other organic solvents, washing liquids and mother liquors Classified as hazardous waste. Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal. Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be taken for reuse. Packaging that cannot be cleaned should be disposed of like the product. 14. Transport information Land transport (ADR/RID) UN number: ADR/RID class: Classification code: Warning plate Hazard-no.: Hazard label: 1987 F1 ADR/RID packing group: Limited quantity: Description of the goods ALCOHOLS, N.O.S. (Propan-2-ol, Propan-1-ol) II LQ4 Other applicable information (land transport) LQ 4: combination packaging: l / 0 kg (total gross mass); trays: 1 l / 20 kg (total gross mass). Tunnel restriction code: D/E Transport category: 2 Marine transport UN number: IMDG code: Hazard label: 1987 IMDG packing group: EmS: Limited quantity: Description of the goods ALCOHOLS, N.O.S. (propan-2-ol, propan-1-ol) II F-E, S-D 1 L / 0 kg Other applicable information (marine transport) Limited quantities (chapter.4): combination packaging: 1 l / 0 kg (total gross mass); trays: 1 l / 20 kg (total gross mass) Air transport UN/ID number: ICAO/IATA-DGR: Hazard label: 1987 GB - EN Page 5 of 7

6 ICAO packing group: Limited quantity Passenger: IATA-packing instructions - Passenger: IATA-max. quantity - Passenger: IATA-packing instructions - Cargo: IATA-max. quantity - Cargo: Description of the goods ALCOHOLS, N.O.S. (propan-2-ol, propan-1-ol, mixture) II Y05 / 1 L 05 5 L L 15. Regulatory information Labelling Additional advice on labelling According to EC-regulations the product is to be labelled as follows: Danger symbols: Xi - Irritant Xi - Irritant R phrases 10 Flammable. 41 Risk of serious damage to eyes. 52/5 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 67 Vapours may cause drowsiness and dizziness. S phrases 07 Keep container tightly closed. 16 Keep away from sources of ignition - No smoking. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 9 Wear eye/face protection. 60 This material and its container must be disposed of as hazardous waste. 61 Avoid release to the environment. Refer to special instructions / Safety data sheets. Special labelling for certain preparations Contains Polyaminopropyl biguanide. May produce an allergic reaction. EU regulatory information 1999/1/EC (VOC): National regulatory information Employment restrictions: Water contaminating class (D): 16. Other information < 80 % Full text of R-phrases referred to under sections 2 and 10 Flammable. 11 Highly flammable. 22 Harmful if swallowed. 6 Irritating to eyes. 8 Irritating to skin. 41 Risk of serious damage to eyes. 4 May cause sensitization by skin contact. Observe employment restrictions for young people. Observe employment restrictions for child bearing mothers and nursing. 1 - slightly water contaminating GB - EN Page 6 of 7

7 50 Very toxic to aquatic organisms. 52/5 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 5 May cause long-term adverse effects in the aquatic environment. 67 Vapours may cause drowsiness and dizziness. Further Information Data of items 4 to 8, as well as 10 to 12, do partly not refer to the use and the regular employing of the product (in this sense consult information on use and on product), but to liberation of major amounts in case of accidents and irregularities. The information describes exclusively the safety requirements for the product(s) and is based on the present level of our knowledge. The delivery specifications are contained in the corresponding product sheet. This data does not constitute a guarantee for the characteristics of the product(s) as defined by the legal warranty regulations. (n.a. = not applicable; n.d. = not determined) (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.) GB - EN Page 7 of 7