Version: 2. Hauptstr , Aichstetten, Germany. Tel./Fax.: Tel , Fax

Transcription

1 Revised edition: Version: 2 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Uranine Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Laboratory chemicals, manufacture of substances Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Classification according to Directive No. 67/548/EC or No. 1999/45/EC This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Hazard designation: No classification required according to the CLP/GHS guidelines. Not applicable. Signal word: Hazard designation: Safety designation: Hazardous components for labelling: Other Hazards Composition/Information on Ingredients 2

2 Substance Mixture Page 2 Chemical Characterization: Information on Components / Hazardous Ingredients: Fluorescein sodium (C.I ) Fluorescent dye Acid Yellow 73, C.I % CAS-Nr: EINECS-Nr: EC-Nr: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Seek medical attention in case of complaints. Supply fresh air. If required give artificial respiration. Keep patient warm. Wash off with plenty of water and soap. Rinse eyes with water After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with plenty of water. Never give anything by mouth to an unconscious person. Symptoms: No further information available Effects: Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: No further information available. Water mist, extinguishing powder, foam, carbon dioxide Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture Special hazards: Combustible material. 3

3 5. 3. Advice for Firefighters Page 3 When heated or in case of fire: formation of hazard fumes possible. In case of fire: formation of carbon monoxide and dioxide. Protective equipment: Wear self-contained respiratory protective device and protective clothing Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Contaminated extinguishing water and debris should be disposed of according to local regulations Personal precautions: Environmental Precautions Do not inhale dust. Avoid formation of dust. Ensure adequate ventilation Environmental precautions: Methods and Material for Containment and Cleaning Up Do not allow entering sewerage system. Dilute with plenty of water Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Sweep up, then place into a suitable container for disposal. Avoid generating dust. For information for safe handling see Section 7. See Section 13 for information on disposal. Avoid formation and deposition of dust. Provide adequate ventilation. Provide adequate ventilation Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Wash thoroughly after handling. Storage conditions: Store in tightly sealed containers in a dry and cool room. Store containers in a well ventilated location. Requirements for storage areas and containers: Information on fire and explosion protection: No special measures necessary. 4

4 Storage class (VCI): Page Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): none known Parameters to be controlled: Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation in case of dust formation. Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Body protection: The usual precautionary measures are to be adhered to when handling chemicals. Dust mask recommended when very dusty (with particle filter P1). Protective gloves (EN 374) Nitrile rubber (> 480 min, 0.11 mm). Safety glasses with protective shields (EN 166). Protective clothing Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: powder Color: reddish brown Odor: odorless Odor threshold: 5

5 ph-value: 8.3 Page 5 Melting temperature: > 300 C Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: not flammable 500 g/l (20 C) logpow Product presents an explosion hazard. 600 kg/m3 Solvent content: 6

6 Solid content: Page Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Stable if used according to specifications. Unknown. No decomposition if used according to specifications. None known. In the event of fire: see chapter mg/kg (rat) May be harmful when absorbed by skin. May irratate skin. May irritate eyes. May be harmful by inhalation. Can cause irritation of the respiratory system. Can be harmful when swallowed. No relevant data found. Mutagenicity: 7

7 No mutagenic effects observed. Page Reproductive toxicity: Carcinogenicity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods No relevant data found. IARC: No component of this product present at levels greater than or equal to 0.1 % is identified as probable, possible or confirmed human carcinogen by IARC. Single exposure: no information available. Repeated exposure: no information available. Aspiration hazard: LC50: 1372 mg/l (96h, Oncorhynchus mykiss) EC50: 337 mg/l (48h, Daphnia pulex) No data available. Biodegradable. Not applicable. 1, slightly hazardous Product: 8

8 European Waste Code (EWC): Page 8 Dispose of according to official national and local regulations. Uncleaned packaging: Packaging may be disposed of in the same manner as the product Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel restriction code: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG IATA: Environmental Hazards None Special Precautions for User Not classified as a dangerous good under transport regulations. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information 9

9 Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Page 9 Water hazard class: 1, slightly hazardous for water (according to the German Regulation AwSV using the mixing rule) Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment has not been carried out for this product. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.