SCALA SC FUNGICIDE 1/10 Version 2.0 / CDN Revision Date: 02/01/ Print Date: 02/02/2017

Transcription

1 SCALA SC FUNGICIDE 1/10 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifier Trade name Product code (UVP) SCALA SC FUNGICIDE SDS Number PCP Registration No Relevant identified uses of the substance or mixture and uses advised against Use Restrictions on use Information on supplier Supplier Responsible Department Emergency telephone no. Emergency Telephone Number (24hr/ 7 days) Product Information Telephone Number Fungicide See product label for restrictions. Bayer CropScience Inc #200, 160 Quarry Park Blvd, SE Calgary, Alberta T2C 3G3 Canada SDSINFO.BCS-NA@bayer.com SECTION 2: HAZARDS IDENTIFICATION Classified in accordance with Part 2 of the Hazardous Products Regulations This material is not hazardous under the criteria of Part 2 of the Hazardous Products Regulation. Hazards Not Otherwise Classified (HNOC) No physical hazards not otherwise classified. No health hazards not otherwise classified. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Component Name CAS-No. Concentration % by weight Pyrimethanil Lignin, alkali, reaction products with formaldehyde and sodium bisulfite

2 SCALA SC FUNGICIDE 2/10 SECTION 4: FIRST AID MEASURES Description of first aid measures General advice Inhalation Skin contact When possible, have the product container or label with you when calling a poison control center or doctor or going for treatment. Move to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a physician or poison control center immediately. Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water for at least 15 minutes. Call a physician or poison control center immediately. Eye contact Hold eye open and rinse slowly and gently with water for minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a physician or poison control center immediately. Ingestion Call a physician or poison control center immediately. Rinse out mouth and give water in small sips to drink. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. Do not leave victim unattended. Most important symptoms and effects, both acute and delayed Symptoms To date no symptoms are known. Indication of any immediate medical attention and special treatment needed Treatment Appropriate supportive and symptomatic treatment as indicated by the patient's condition is recommended. There is no specific antidote. SECTION 5: FIREFIGHTING MEASURES Extinguishing media Suitable Unsuitable Special hazards arising from the substance or mixture Advice for firefighters Special protective equipment for firefighters Further information Flash point Water spray, Foam, Dry chemical, Carbon dioxide (CO2) None known. Dangerous gases are evolved in the event of a fire. Firefighters should wear NIOSH approved self-contained breathing apparatus and full protective clothing. Keep out of smoke. Fight fire from upwind position. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or water courses.

3 SCALA SC FUNGICIDE 3/10 Auto-ignition temperature Lower explosion limit Upper explosion limit Explosivity Not applicable SECTION 6: ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Precautions Methods and materials for containment and cleaning up Methods for cleaning up Additional advice Isolate hazard area. Keep unauthorized people away. Avoid contact with spilled product or contaminated surfaces. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Collect and transfer the product into a properly labelled and tightly closed container. Clean contaminated floors and objects thoroughly, observing environmental regulations. Use personal protective equipment. If material is accidentally spilled, do not allow to enter soil, waterways or waste water canal. Reference to other sections Information regarding safe handling, see section 7. Information regarding personal protective equipment, see section 8. Information regarding waste disposal, see section 13. SECTION 7: HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Hygiene measures Handle and open container in a manner as to prevent spillage. Maintain exposure levels below the exposure limit through the use of general and local exhaust ventilation. Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, using the toilet or applying cosmetics. Remove Personal Protective Equipment (PPE) immediately after handling this product. Before removing gloves clean them with soap and water. Remove soiled clothing immediately and clean thoroughly before using again. Wash thoroughly and put on clean clothing. Conditions for safe storage, including any incompatibilities

4 SCALA SC FUNGICIDE 4/10 Requirements for storage areas and containers Store in a cool, dry place and in such a manner as to prevent cross contamination with other crop protection products, fertilizers, food, and feed. Store in original container and out of the reach of children, preferably in a locked storage area. Protect from freezing. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components CAS-No. Control parameters Update Basis Pyrimethanil mg/m3 OES BCS* (TWA) 1,2-Propanediol mg/m CAD ON (TWA) OEL (Aerosol.) 1,2-Propanediol (Vapor and aerosol.) mg/m3/50 ppm (TWA) *OES BCS: Internal Bayer AG, Crop Science Division "Occupational Exposure Standard" Exposure controls CAD ON OEL Personal protective equipment In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the following recommendations would apply. Respiratory protection When respirators are required, select NIOSH approved equipment based on actual or potential airborne concentrations and in accordance with the appropriate regulatory standards and/or industry recommendations. Hand protection Eye protection Skin and body protection General protective measures Chemical resistant nitrile rubber gloves Safety glasses with side-shields Wear long-sleeved shirt and long pants and shoes plus socks. Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and warm/tepid water. Keep and wash PPE separately from other laundry. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical State Odor Odour Threshold ph brown suspension characteristic at 100 % (23 C)

5 SCALA SC FUNGICIDE 5/10 Vapor Pressure Vapor Density (Air = 1) Density 1.07 g/cm³ at 20 C Evaporation rate Boiling Point Melting / Freezing Point Water solubility Minimum Ignition Energy Decomposition temperature Partition coefficient: n- octanol/water dispersible Viscosity mpa.s at 25 C Flash point Auto-ignition temperature Lower explosion limit Upper explosion limit Explosivity Not applicable SECTION 10: STABILITY AND REACTIVITY Reactivity Thermal decomposition Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products Stable under recommended storage conditions. No hazardous reactions when stored and handled according to prescribed instructions. freezing No decomposition products expected under normal conditions of use. SECTION 11: TOXICOLOGICAL INFORMATION Exposure routes Immediate Effects Inhalation, Skin Absorption, Eye contact, Ingestion

6 SCALA SC FUNGICIDE 6/10 Eye Skin Causes eye irritation. Harmful if absorbed through skin. Irritating to skin. Inhalation Information on toxicological effects Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin irritation Eye irritation Sensitisation Harmful if inhaled. LD50 (Rat) > 5,000 mg/kg LC50 (Rat) > 1.26 mg/l Exposure time: 4 h Determined in the form of liquid aerosol. Highest attainable concentration. No deaths LD50 (Rat) > 4,000 mg/kg Moderate skin irritation. (Rabbit) Minimally irritating. (Rabbit) Non-sensitizing. (Guinea pig) Assessment STOT Specific target organ toxicity repeated exposure Pyrimethanil did not cause any significant specific adverse effects or target organ toxicity in subchronic toxicity studies. Assessment mutagenicity Pyrimethanil was not mutagenic or genotoxic in a battery of in vitro and in vivo tests. Assessment carcinogenicity Pyrimethanil was not carcinogenic in lifetime feeding studies in mice. Pyrimethanil caused at high dose levels an increased incidence of tumours in rats in the following organ(s): Thyroid. The mechanism that triggers tumours in rodents and the type of tumours observed are not relevant to humans. ACGIH NTP IARC OSHA Assessment toxicity to reproduction Pyrimethanil did not cause reproductive toxicity in a two-generation study in rats. Assessment developmental toxicity Pyrimethanil did not cause developmental toxicity in rats and rabbits. Further information

7 SCALA SC FUNGICIDE 7/10 Only acute toxicity studies have been performed on the formulated product. The non-acute information pertains to the active ingredient(s). SECTION 12: ECOLOGICAL INFORMATION Toxicity to fish Toxicity to aquatic invertebrates LC50 (Oncorhynchus mykiss (rainbow trout)) mg/l Exposure time: 96 h The value mentioned relates to the active ingredient pyrimethanil. EC50 (Daphnia magna (Water flea)) 2.9 mg/l Exposure time: 48 h The value mentioned relates to the active ingredient pyrimethanil. Toxicity to aquatic plants Biodegradability IC50 (Raphidocelis subcapitata (freshwater green alga)) 1.2 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient pyrimethanil. Pyrimethanil: Not rapidly biodegradable Koc Pyrimethanil: Koc: 301 Bioaccumulation Mobility in soil Environmental precautions Pyrimethanil: Does not bioaccumulate. Pyrimethanil: Moderately mobile in soils Do not allow to get into surface water, drains and ground water. Do not contaminate surface or ground water by cleaning equipment or disposal of wastes, including equipment wash water. Drift and runoff from treated areas may be hazardous to aquatic organisms in adjacent sites. Apply this product as specified on the label. SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Product Contaminated packaging Follow container label instructions for disposal of wastes generated during use in compliance with the product label. Dispose in accordance with all local, state/provincial and federal regulations. Triple rinse containers. Puncture container to avoid re-use. Dispose of empty container in a sanitary landfill or by incineration, or, if allowed by State/Provincial and local authorities, by burning. If burned, stay out of smoke.

8 SCALA SC FUNGICIDE 8/10 SECTION 14: TRANSPORT INFORMATION TDG UN number 3082 Labels 9 Packaging group III Marine pollutant Proper shipping name Marine pollutant ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PYRIMETHANIL) 49CFR Not dangerous goods / not hazardous material IMDG UN number 3082 Class 9 Packaging group III Marine pollutant Proper shipping name IATA UN number 3082 Class 9 Packaging group III Environm. Hazardous Mark Proper shipping name YES ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PYRIMETHANIL SOLUTION) YES ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PYRIMETHANIL SOLUTION ) This transportation information is not intended to convey all specific regulatory information relating to this product. It does not address regulatory variations due to package size or special transportation requirements. Further Information Exempt from regulation when transported by road or rail, in accordance with TDG Regulations This exemption provides that this product does not require dangerous goods shipping documentation or safety marks when transported on land by road or rail. Freight Classification: INSECTICIDES OR FUNGICIDES, N.O.I., OTHER THAN POISON SECTION 15: REGULATORY INFORMATION PCP Registration No

9 SCALA SC FUNGICIDE 9/10 US Federal Regulations TSCA list US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D) SARA Title III - Section Notification and Information SARA Title III - Section Toxic Chemical Release Reporting US States Regulatory Reporting CA Prop65 This product does not contain any substances known to the State of California to cause cancer. This product does not contain any substances known to the State of California to cause reproductive harm. US State Right-To-Know Ingredients Canadian Regulations Canadian Domestic Substance List Environmental CERCLA Clean Water Section 307 Priority Pollutants Safe Drinking Water Act Maximum Contaminant Levels SECTION 16: OTHER INFORMATION Abbreviations and acronyms 49CFR Code of Federal Regulations, Title 49 ACGIH US. ACGIH Threshold Limit Values ATE Acute toxicity estimate CAS-Nr. Chemical Abstracts Service number CERCLA Comprehensive Environmental Response, Compensation, and Liability Act EINECS European inventory of existing commercial substances ELINCS European list of notified chemical substances IARC International Agency for Research on Cancer IATA International Air Transport Association IMDG International Maritime Dangerous Goods N.O.S. Not otherwise specified NTP US. National Toxicology Program (NTP) Report on Carcinogens OECD Organization for Economic Co-operation and Development TDG Transportation of Dangerous Goods TWA Time weighted average

10 SCALA SC FUNGICIDE 10/10 UN WHO United Nations World health organisation NFPA 704 (National Fire Protection Association): Health - 2 Flammability - 0 Instability - 0 Others - none HMIS (Hazardous Materials Identification System, based on the Third Edition Ratings Guide) Health - 2 Flammability - 0 Physical Hazard - 0 PPE - 0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard Reason for Revision: Revised according to the current Canadian WHMIS standard (WHMIS 2015). Prepared by the HSE Department of Bayer CropScience Inc. (306) Revision Date: 02/01/2017 This information is provided in good faith but without express or implied warranty. The customer assumes all responsibility for safety and use not in accordance with label instructions. The product names are registered trademarks of Bayer.