2 Hazards identification

Transcription

1 Page 1/7 * 1 Identification of the substance/mixture and of the company/undertaking Product identifier Article number: 9461 Relevant identified uses of the substance or mixture and uses advised against Application of the substance / the preparation Laboratory chemical Details of the supplier of the safety data sheet Manufacturer/Supplier: Carl Roth GmbH + Co. KG Schoemperlenstraße Karlsruhe Telefon: +49/(0) Telefax: +49/(0) info@carlroth.de Further information obtainable from: Department Health, Safety and Environment Emergency telephone number: Poison Centre Munich Telefon +49/(0) Hazards identification Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Skin Corr. 1B H314 Causes severe skin burns and eye damage. Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects. Classification according to Directive 67/548/EEC or Directive 1999/45/EC C; Corrosive R34: Causes burns. N; Dangerous for the environment R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Label elements Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. Hazard pictograms GHS05 GHS09 Signal word Danger Hazard-determining components of labelling: silver nitrate Hazard statements H314 Causes severe skin burns and eye damage. H410 Very toxic to aquatic life with long lasting effects. Precautionary statements P280 Wear protective gloves/protective clothing/eye protection/face protection. P273 Avoid release to the environment. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. Other hazards All chemicals are potentially dangerous. They should only be handled by specially trained personnel. Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. (Contd. on page 2)

2 Page 2/7 (Contd. of page 1) * 3 Composition/information on ingredients Chemical characterization: Mixtures Description: Mixture of substances listed below with nonhazardous additions. Dangerous components: CAS: Silicon dioxide 40-60% EINECS: CAS: 10-25% EINECS: C R34; O R8; N R50/53 Ox. Sol. 2, H272; Chronic 1, H410 Skin Corr. 1B, H314; Aquatic Acute 1, H400; Aquatic Additional information: For the wording of the listed risk phrases refer to section 16. * 4 First aid measures Description of first aid measures General information: Immediately remove any clothing soiled by the product. After inhalation: Supply fresh air or oxygen; call for doctor. After skin contact: Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. After eye contact: Rinse immediately for 15 minutes with plenty of water with the eyelid held wide open. Seek medical advice. After swallowing: Rinse out mouth and drink a glass of water. Do not induce vomiting. Call for a doctor immediately. 5 Firefighting measures Extinguishing media Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions. Special hazards arising from the substance or mixture nitrous gases Oxidising. Keep away from flammable substances. Advice for firefighters Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit. * 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Wear protective clothing. Avoid contact with the eyes and skin. Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Pick up mechanically. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. (Contd. on page 3)

3 Page 3/7 (Contd. of page 2) 7 Handling and storage Handling: Precautions for safe handling Handling corresponding to laboratory safety guidelines. Information about fire - and explosion protection: No special measures required. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store in a cool location. Information about storage in one common storage facility: Store away from foodstuffs. Store away from flammable substances. Further information about storage conditions: Store in the dark. Keep container tightly sealed. * 8 Exposure controls/personal protection Additional information about design of technical facilities: No further data; see item 7. Control parameters Ingredients with limit values that require monitoring at the workplace: WEL (Great Britain) Long-term value: 0.01 mg/m³ as Ag IOELV (EU) Long-term value: 0.01 mg/m³ as Ag Additional information: The lists valid during the making were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Respiratory protection: Required when dusts are generated: filter P2. Protection of hands: Protective gloves Material of gloves Polyethylene or rubber gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles Body protection: Protective work clothing (Contd. on page 4)

4 Page 4/7 (Contd. of page 3) 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Solid Colour: White Odour: Odourless ph-value (100 g/l) at 20 C: 6 Change in condition Melting point/melting range: Undetermined. Boiling point/boiling range: Undetermined. Flash point: Not applicable. Self-igniting: Product is not self-igniting. Danger of explosion: Product does not present an explosion hazard. Density at 20 C: ~ 2.2 g/cm³ Solubility in / Miscibility with water: * 10 Stability and reactivity Partly soluble. Reactivity Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No information available. Incompatible materials: Nonmetals, organic substances, alkali hydroxides, acetylidene, acetylene, aldehydes, nitriles, ammonium compounds, combustible substances, hydrazine, carbides, organic nitro compounds, ethanol, magnesium powder. Hazardous decomposition products: In case of fire: see item Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values relevant for classification: Oral LD mg/kg (rat) Primary irritant effect: on the skin: Caustic effect on skin and mucous membranes. on the eye: Strong caustic effect. after inhalation: Irritations in the respiratory tract, coughing, dyspnoea. Sensitization: No sensitizing effects known. Additional toxicological information: After swallowing nausea and vomiting. Further information: The product should be handled with the care usual when dealing with chemicals. (Contd. on page 5)

5 Page 5/7 (Contd. of page 4) 12 Ecological information Toxicity Acquatic toxicity: Fish toxicity: LC mg/l/96 h (Leuciscus idus) (OECD Test Guideline 203) mg/l/96 h (Onchorhynchus mykiss) Daphnia toxicity: EC mg/l/48 h (Daphnia magna) Algeal toxicity: IC mg/l/8 d (Desmodesmus subspicatus) Ecotoxical effects: Remark: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Damages plankton and fish. Forms, despite dilution, corrosive mixtures with water. Additional ecological information: General notes: Do not allow product to reach ground water, water course or sewage system. Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. 13 Disposal considerations Waste treatment methods Recommendation This material and its container must be disposed of as hazardous waste. The disposal is regionally differently regulated, therefore the kind of disposal is to be inquired at the responsible authorities. Uncleaned packaging: Recommendation: Disposal according to official regulations. * 14 Transport information Land transport ADR/RID (cross-border) ADR/RID class: 8 Corrosive substances. Danger code (Kemler): 80 UN-Number: 3260 Packaging group: II Hazard label 8 Special marking: Symbol (fish and tree) UN proper shipping name: 3260 CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (SILVER NITRATE), ENVIRONMENTALLY HAZARDOUS Limited quantities (LQ) 1 kg Tunnel restriction code E (Contd. on page 6)

6 Page 6/7 Maritime transport IMDG: (Contd. of page 5) IMDG Class: 8 UN Number: 3260 Label 8 Packaging group: II EMS Number: F-A,S-B Marine pollutant: Symbol (fish and tree) Segregation groups Acids Proper shipping name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (SILVER NITRATE) Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: 8 UN/ID Number: 3260 Label 8 Packaging group: II Proper shipping name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (SILVER NITRATE) UN "Model Regulation": UN3260, CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S., ENVIRONMENTALLY HAZARDOUS, 8, II Special precautions for user Warning: Corrosive substances. * 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations: Information about limitation of use: Employment restrictions concerning juveniles must be observed. Employment restrictions concerning pregnant and lactating women must be observed. Waterhazard class: Water hazard class 3 (Self-assessment): extremely hazardous for water. Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases H272 May intensify fire; oxidiser. H314 Causes severe skin burns and eye damage. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. R34 Causes burns. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R8 Contact with combustible material may cause fire. Department issuing MSDS: Department: Health, Safety and Environment Contact: Frau Dr. Rupp (Contd. on page 7)

7 Page 7/7 (Contd. of page 6) Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) ICAO: International Civil Aviation Organization ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO) GHS: Globally Harmonized System of Classification and Labelling of Chemicals LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent * Data compared to the previous version altered.