Safety Data Sheet. according to Regulation (EC) No 1907/2006 DINITROL VCI UNI O-040 OIL

Size: px
Start display at page:

Download "Safety Data Sheet. according to Regulation (EC) No 1907/2006 DINITROL VCI UNI O-040 OIL"

Transcription

1 Page 1 of 7 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Anti-corrosive coating 1.3. Details of the supplier of the safety data sheet Company name: Street: Place: Pyrmonter Strasse 76 D Luegde Telephone: +49 (0) Telefax:+49 (0) Responsible Department: 1.4. Emergency telephone number: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture msds@dinol.com Classification according to Directive 67/548/EEC or 1999/45/EC Giftnotruf Berlin: (Consultation in German and English) This mixture is not classified as hazardous according to Directive 1999/45/EC. Classification according to Regulation (EC) No. 1272/2008 [CLP] Hazard categories: Skin corrosion/irritation: Skin Irrit. 2 Serious eye damage/eye irritation: Eye Irrit. 2 Hazard Statements: 2.2. Label elements Signal word: Pictograms: Warning GHS07 Hazard statements H315 H319 Precautionary statements P262 Do not get in eyes, on skin, or on clothing. P302+P350 IF ON SKIN: Gently wash with plenty of soap and water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Other hazards SECTION 3: Composition/information on ingredients 3.2. Mixtures

2 Page 2 of 7 Hazardous components EC No CAS No Index No REACH No Chemical name Classification according to Directive 67/548/EEC Classification according to Regulation (EC) No. 1272/2008 [CLP] Octanoic acid/ter. Alkanolamine neutralization product Xn - Harmful, Xi - Irritant R20/21/22-36/38 Flam. Liq. 3, Acute Tox. 3, Acute Tox. 3, Acute Tox. 4, Skin Irrit. 2, Eye Irrit. 2; H226 H311 H331 H302 H315 H319 Acid, ionic equilibrium with organic bases Quantity 1 -< 5 % 1 -< 5 % Skin Irrit. 2, Eye Irrit. 2; H315 H Caprylic Acid 1 -< 5 % C - Corrosive R34 Skin Corr. 1B; H314 Full text of R, H and EUH phrases: see section 16. SECTION 4: First aid measures 4.1. Description of first aid measures After inhalation Provide fresh air. After contact with skin Wash with plenty of water. Take off contaminated clothing and wash it before reuse. After contact with eyes Rinse immediately carefully and thoroughly with eye-bath or water. After ingestion Rinse mouth immediately and drink plenty of water Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Co-ordinate fire-fighting measures to the fire surroundings Special hazards arising from the substance or mixture Non-flammable. Vapours can form explosive mixtures with air Advice for firefighters In case of fire: Wear self-contained breathing apparatus. Additional information Use water spray jet to protect personnel and to cool endangered containers. Suppress gases/vapours/mists with water spray jet. Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water. SECTION 6: Accidental release measures

3 Page 3 of Personal precautions, protective equipment and emergency procedures Provide adequate ventilation Environmental precautions Do not allow to enter into surface water or drains Methods and material for containment and cleaning up Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the recovered material as prescribed in the section on waste disposal Reference to other sections Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section 13 SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling No special measures are necessary. Advice on protection against fire and explosion No special fire protection measures are necessary Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep container tightly closed. Advice on storage compatibility No special measures are necessary Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Protective and hygiene measures Take off contaminated clothing. Wash hands before breaks and after work. When using do not eat or drink. Eye/face protection Eye glasses with side protection (DIN EN 166) Hand protection Tested protective gloves must be worn (DIN EN 374) - Suitable gloves type: NBR (Nitrile rubber) penetration time (maximum wearing period): >480 min When handling with chemical substances, protective gloves must be worn with the CE-label including the four control digits. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.

4 Page 4 of 7 Skin protection Wear suitable protective clothing. Respiratory protection In case of inadequate ventilation wear respiratory protection. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state: Colour: Odour: ph-value: Changes in the physical state Melting point: Initial boiling point and boiling range: Flash point: Flammability Solid: Gas: Lower explosion limits: Upper explosion limits: Auto-ignition temperature Solid: Gas: Decomposition temperature: Oxidizing properties Not oxidizing. Vapour pressure: Density (at 15 C): Water solubility: Solubility in other solvents Partition coefficient: Viscosity / kinematic: (at 40 C) Vapour density: Evaporation rate: 9.2. Other information Solid content: liquid yellow characteristic 61 C 0,91 g/cm³ insoluble 52 mm²/s Test method SECTION 10: Stability and reactivity Reactivity No hazardous reaction when handled and stored according to provisions Chemical stability

5 Page 5 of 7 The product is stable under storage at normal ambient temperatures Possibility of hazardous reactions Conditions to avoid none No known hazardous reactions Incompatible materials Hazardous decomposition products No known hazardous decomposition products. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity CAS No Chemical name Exposure route Method Dose Octanoic acid/ter. Alkanolamine neutralization product oral ATE 500 mg/kg dermal ATE 300 mg/kg inhalative vapour ATE 3 mg/l inhalative aerosol ATE 0,5 mg/l Caprylic Acid oral LD mg/kg dermal LD50 >2001 mg/kg Species Rat Rabbit Source Irritation and corrosivity Sensitising effects STOT-single exposure Severe effects after repeated or prolonged exposure Carcinogenic/mutagenic/toxic effects for reproduction Aspiration hazard Additional information on tests This mixture is classified as not hazardous according to 1999/45/EC. SECTION 12: Ecological information Toxicity The product is not: Ecotoxic Persistence and degradability

6 Page 6 of Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects Further information Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Advice on disposal Do not allow to enter into surface water or drains. Dispose of waste according to applicable legislation. Waste disposal number of waste from residues/unused products WASTES FROM SHAPING AND PHYSICAL AND MECHANICAL SURFACE TREATMENT OF METALS AND PLASTICS; wastes from shaping and physical and mechanical surface treatment of metals and plastics; mineral-based machining oils free of halogens (except emulsions and solutions) Classified as hazardous waste. Contaminated packaging Wash with plenty of water. Completely emptied packages can be recycled. SECTION 14: Transport information Land transport (ADR/RID) UN number: UN proper shipping name: Transport hazard class(es): Packing group: Marine transport (IMDG) UN number: UN proper shipping name: Transport hazard class(es): Packing group: Air transport (ICAO) UN number: UN proper shipping name: Transport hazard class(es): Packing group: Environmental hazards ENVIRONMENTALLY HAZARDOUS: Special precautions for user Transport in bulk according to Annex II of Marpol and the IBC Code no

7 Page 7 of 7 SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulatory information Additional information Observe in addition any national regulations! Directive 98/24/EC of 7 April 1998 on the protection of the health and safety of workers from the risks related to chemical agents at work National regulatory information Water contaminating class (D): Chemical safety assessment 1 - slightly water contaminating Chemical safety assessments for substances in this mixture were not carried out. SECTION 16: Other information Changes This data sheet contains changes from the previous version in section(s): 1,2,3,8,15. Abbreviations and acronyms ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road ) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service LC50: Lethal concentration, 50% LD50: Lethal dose, 50% Relevant R phrases (number and full text) 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. 34 Causes burns. 36/38 Irritating to eyes and skin. Relevant H and EUH statements (number and full text) H226 Flammable liquid and vapour. H302 Harmful if swallowed. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H315 H319 H331 Toxic if inhaled. Further Information The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)