MATERIAL SAFETY DATA SHEET

Transcription

1 SECTION 1 : IDENTIFICATION Product identifier: Product name : Product Use: HERTEL HERTEL Bathroom Cleaner Supplier s name: Address : LAVO Inc Boul. Saint-Jean Baptiste Montréal, Québec Canada H1C 2J3 Telephone : or Emergency phone : CANUTEC (transport) SECTION 2 : HAZARD IDENTIFICATION Classification : POTENTIAL HEALTH EFFECTS: Signs and symptoms of short-term (acute) exposure Inhalation : Skin : Eyes : Ingestion : Effects of long-term (chronic) exposure : Signs and symptoms: Potentiel environmental effects: DANGER. CAUSES EYE BURNS.CAUSES SKIN BURNS. May cause respiratory tract irritation. Harmful if swallowed. May cause chemical burns to mouth, throat and stomach. Prolonged or repeated exposure can cause drying, de fatting and dermatitis. May cause severe irritation or chemical burns. See section 12. SECTION 3 : COMPOSITION/INFORMATION ON INGREDIENTS Ingredients CAS Conc Sulfonated sodium salt, propylene derivatives % Sodium Hypochlorite % SECTION 4 : FIRST AID MEASURES Inhalation : If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention. Skin contact or clothing: Immediately flush with cool water. Wash with soap and water. Obtain medical attention if irritation persists. Eye contact : Ingestion : General advice Notes for physician : Immediately flush with cool water. Remove contact lenses, if applicable, and continue flushing for 15 minutes.. Obtain medical attention if irritation persists. Do not induce vomiting. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth if victim is unconscious, or is convulsing. Obtain medical attention. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of reach of children. Treat symptomatically Page 1 / 5

2 SECTION 5 : FIRE FIGHTING MEASURES Fire hazards/conditions of flammability: Not flammable by WHMIS criteria. Extinguishing media: Protection of firefighters: Hazardous combustion products: Explosion data: SECTION 6 : ACCIDENTAL RELEASE MEASURES Dry chemical. Foam. Carbon dioxide. Firefighters should wear full protective clothing including self contained breathing apparatus. May include and are not limited to: Oxide of nitrogen, Hydrogen chloride. Not available. Personal precautions: Environmental precautions: Methods for containment: Methods for cleaning up: Keep unnecessary personnel away. Do not touch and walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill/leak. Do not discharge into lakes, streams, ponds or public waters. Stop the spill at source if it is safe to do so. Ensure spilled product does not enter drains, sewers, waterways, or confined spaces. Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with non-reactive absorbent and placed in suitable covered labeled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills in original containers for re-use. SECTION 7 : HANDLING AND STORAGE Safe Handling procedures: Storage requirements : Special packaging materials: Use only in well ventilated areas. Avoid contact with skin, eyes and clothing. Wash thoroughly after handling. Keep away from heat and flame. Keep away from incompatibles. Keep containers tightly closed when not in use. Empty containers retain residue (liquid and/or vapor) and can be dangerous. Keep out the reach of children. Store in a cool, dry, well ventilated area. Keep away from incompatibles. Storage area should be clearly identified, clear of obstruction and accessible only to trained and authorized personnel. Inspect periodically for damage or leaks. Protect from sunlight. Do not freeze. Always keep in containers made of the same materials as the supply container. SECTION 8 : EXPOSURE CONTROLS AND PERSONAL PROTECTION Exposure Limits Ingredients CAS ACGIH TLV Sulfonated sodium salt, propylene derivatives Not established Sodium Hypochlorite Not established Ventilation and engineering measures : Respiratory protection : Skin protection : Eye/face protection : General hygiene considerations : General ventilation normally adequate. Respiratory protection is required if the concentrations exceed the TLV. NIOSH approved respirators are recommended. Impervious gloves must be worn when using this product. Advice should be sought from glove suppliers. Chemical splash goggles must be worn when handling this material. A full face shield may also be necessary. Avoid breathing vapor or mist. Avoid contact with skin, eyes and clothing. Do not eat, drink, smoke or use cosmetics while working with this product. Upon completion of work, wash hands before eating, drinking, smoking or use of toilet facilities. Remove soiled clothing and wash it thoroughly before reuse Page 2 / 5

3 SECTION 9 : PHYSICAL AND CHEMICAL PROPERTIES MATERIAL SAFETY DATA SHEET Physical state Liquid Appearance Clear liquid limpid Odor Characteristic Odor threshold N/Av ph Density 1.04g/mL Boiling Point N/Av Coefficient of water/oil distribution N/Av Melting/Freezing Point N/Av Solubility in water Soluble Vapor Pressure N/Av Evaporation rate N/Av Volatile organic Compounds N/Av Absolute pressure of container N/Av Flash Point N/Av Viscosity 5 cps (25 C) Flash Point, method N/Av Auto-ignition temperature N/Av Lower flammable limit N/Av Upper flammable limit N/Av Volatiles (% by weight) N/Av Flashback observed N/Av SECTION 10 : STABILITE AND REACTIVITY Stability/Reactivity: Hazardous polymerization : Conditions to avoid Incompatible materials: Hazardous decomposition products : Reacts vigorously with acids. This product may react with oxidizing agents. Stable under recommended storage conditions. Not expected under prescribed storage and handling conditions. Do not mix with other chemicals. Acids. Oxidizing agents. May include and are not limited to: Oxides of nitrogen. Hydrogen chloride. SECTION 11 : TOXICOLOGICAL INFORMATION Target organs: Toxicological data: Eyes, skin, respiratory system and digestive system. There is no available data for the product itself, only for the ingredients. See below for individual ingredient acute toxicity data. Ingredients CAS CL50(4hr) inh, rat LD50 (Oral, rat) Sulfonated sodium salt, propylene derivatives Not available Not available Sodium Hypochlorite >5250 mg/m ml/kg rat; 5800 mg/kg mouse Effect of acute exposure: Inhalation; May cause respiratory tract irritation. Skin: Eyes; Ingestion: Harmful if swallowed. May cause chemical burns to mouth, throat and stomach. Sensitization to material : Chronic effect: Carcinogenic Status: IARC Group 3 (not classifiable) Sodium Hypochlorite Monograph 52 (1991) (listed under Hypochlorite salts) Mutagenicity : Reproductive effects : Teratogenicity : Synergistic materials: Not available Page 3 / 5

4 SECTION 12 : ECOLOGICAL INFORMATION Ecotoxicity Freshwater Algae Acurate Toxicity MATERIAL SAFETY DATA SHEET Sodium Hypochlorite Hr EC50 Skeletonema costatum: mg/l Ecotoxicity Freshwater Fish Acurate Toxicity Sodium Hypochlorite Hr LC50 Pimephales promelas: mg/l [flow-through]; Ecotoxicity Water Flea Acurate Toxicity 96 Hr LC50 Pimephales promelas: mg/l [static]; 96 Hr LC50 Lepomis macrochirus: mg/l [static]; 96 Hr LC50 Lepomis macrochirus: mg/l [flow-through]; 96 Hr LC50 Oncorhynchus mykiss: mg/l [flow-through]; 96 Hr LC50 Oncorhynchus mykiss: <0.19 mg/l [semi-static]; 96 Hr LC50 Oncorhynchus mykiss: mg/l [static] Sodium Hypochlorite Hr EC50 Daphnia magna: 2.1 mg/l; 48 Hr EC50 Daphnia magna: mg/l [Static] Persistence : Not available. Aquatic toxicity: Not available. Bioaccumulation Potential: Not available. Partition coefficient: Not available. Mobility : Not available. Chemical fate information: Not available. Environmental effects : Not available. Other Adverse effects : Not available. SECTION 13 : DISPOSAL CONSIDERATIONS Handling for Disposal : Handle waste according to recommendations in Section 7. Methods of Disposal: SECTION 14 : TRANSPORT INFORMATION Dispose in accordance with all applicable federal, state, provincial and local regulations. Contact your local, state, provincial or federal environmental agency for specific rules. Transportation of Dangerous Goods (TDG - Canada) : Not regulated as dangerous goods. Proper shipping name Corrosive liquid NOS (Sodium Hypochlorite) Hazard class 8 UN Number UN1760 Packing group III Additionnal information : Special provisions 16 Packaging exceptions Limited quantity 5L SECTION 15 : REGULATORY INFORMATION Canadian federal regulations : This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Canada - WHMIS Ingredient Disclosure List Sodium Hypochlorite % WHMIS classification WHMIS status Class E Corrosive material Controlled WHMIS labeling: Canadian inventory status: All components of this product are either on the Domestic Substances List (DSL), the Non Domestic Substances list (NDSL) or exempt Page 4 / 5

5 SECTION 16 : OTHER INFORMATION HMIS LEGEND 0- Minimal 1-Slight 2-Moderate 3-Serious Other information: Health: 3 Flammability : 0 Reactivity : 0 For an update MSDS, Please contact the supplier/manufacturer listed on the first page of the document. Reference: MSDS of suppliers. SIMDUT regulation Disclaimer of liability: The information in the Material Safety Data Sheet is offered for your consideration and guidance when exposed to this product. Lavo Inc. expressly disclaims all expressed or implied warranties for the accuracy or completeness of the data contained herein and assumes no responsibilities for any involved damages by above data. Product s users have to do their own tests to establish the applicability of the information for a specific use of the product. MSDS data does not apply to use with any other product or in any other process. Prepared by : Lavo Inc Boul. Saint-Jean Baptiste Montréal, QC, Canada H1C 2J3 Telephone : Issuing date: 28-Jan-2016 Due date: Jan Page 5 / 5