1. PRODUCT AND COMPANY IDENTIFICATION

Transcription

1 Creation Date 02-Mar PRODUCT AND COMPANY IDENTIFICATION Revision Number 2 Product Identifier Product Description: Cat No ; ; Synonyms Muriatic acid ; Hydrogen chloride ; HCl Relevant identified uses of the substance or mixture and uses advised against Recommended Use Laboratory chemicals Uses advised against No Information available Details of the supplier of the safety data sheet Company Acros Organics BVBA Janssen Pharmaceuticalaan 3a 2440 Geel, Belgium address begel.sdsdesk@thermofisher.com Emergency Telephone Number For information in the US, call: ACROS-01 For information in Europe, call: Emergency Number, Europe: Emergency Number, US: CHEMTREC Phone Number, US: CHEMTREC Phone Number, Europe: HAZARDS IDENTIFICATION Classification of the substance or mixture REGULATION (EC) No 1272/2008 Not hazardous Classification according to EU Directives 67/548/EEC or 1999/45/EC For the full text of the R phrases mentioned in this Section, see Section 16 R -phrase(s) none Label Elements (invalid picture: C:\Program Files\Wercs50\graphics\EU Small with symbols\blank.png) Signal Word None Hazard Statements Page 1 / 7

2 Other Hazards 3. COMPOSITION/INFORMATION ON INGREDIENTS Component EC No. Weight % CAS-No Classification GHSCLAS REACH Reg. No. Water EEC No Hydrochloric acid C;R34 Xi;R37 Skin Corr. 1B (H314) STOT SE 3 (H335) - For the full text of the R phrases mentioned in this Section, see Section FIRST AID MEASURES Description of first aid measures Eye Contact Skin Contact Ingestion Inhalation Notes to Physician Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes Obtain medical attention Wash off immediately with plenty of water for at least 15 minutes Get medical attention immediately if symptoms occur Do not induce vomiting Call a physician or Poison Control Center immediately Move to fresh air If breathing is difficult, give oxygen Get medical attention immediately if symptoms occur Treat symptomatically 5. FIRE-FIGHTING MEASURES Extinguishing media Suitable Extinguishing Media Substance is nonflammable; use agent most appropriate to extinguish surrounding fire. Extinguishing media which must not be used for safety reasons Special hazards arising from the substance or mixture Thermal decomposition can lead to release of irritating gases and vapors Advice for fire-fighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Page 2 / 7

3 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. Use personal protective equipment. Environmental precautions Should not be released into the environment. Methods and material for containment and cleaning up Soak up with inert absorbent material. Keep in suitable and closed containers for disposal. 7. HANDLING AND STORAGE Precautions for Safe Handling Ensure adequate ventilation Wear personal protective equipment Avoid contact with skin, eyes and clothing Avoid ingestion and inhalation Conditions for safe storage, including any incompatibilities Keep containers tightly closed in a dry, cool and well-ventilated place Do not store in metal containers Corrosives area Specific End Uses Control parameters Exposure limits 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Component European Union The United Kingdom France Belgium Spain Hydrochloric acid STEL: 5 ppm VLCT: 5 ppm STEL: 8 mg/m 3 VLCT: 7.6 mg/m 3 STEL: 15 mg/m 3 TWA: 8 mg/m 3 TWA: 5 ppm VLA-EC: 10 ppm VLA-EC: 15 mg/m 3 VLA-ED: 5 ppm VLA-ED: 7.6 mg/m 3 Component Italy Portugal The Netherlands Finland Denmark Ceiling: 2 ppm STEL: 15 mg/m 3 STEL: 5 ppm Ceiling: 7 mg/m 3 TWA: 8 mg/m 3 STEL: 7.6 mg/m 3 Ceiling: 5 ppm Hydrochloric acid TWA: 8 mg/m 3 TWA: 5 ppm STEL: 15 mg/m 3 Component Austria Switzerland Poland Norway Ireland STEL: 6 mg/m 3 NDSCh: 10 mg/m 3 Ceiling: 5 ppm STEL: 4 ppm NDS: 5 mg/m 3 Ceiling: 7 mg/m 3 MAK: 3.0 mg/m 3 MAK: 2 ppm Hydrochloric acid STEL: 15 mg/m 3 MAK: 5 ppm MAK: 8 mg/m 3 TWA: 5 ppm TWA: 7 mg/m 3 STEL: 14 mg/m 3 Derived No Effect Level (DNEL) Predicted No Effect Concentration (PNEC) Exposure controls Page 3 / 7

4 Engineering Measures Personal protective equipment Eye Protection Hand Protection Skin and body protection Respiratory Protection Ensure adequate ventilation, especially in confined areas Ensure that eyewash stations and safety showers are close to the workstation location Safety glasses with side-shields Protective gloves Wear appropriate protective gloves and clothing to prevent skin exposure Follow the OSHA respirator regulations found in 29 CFR or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced Hygiene Measures Environmental exposure controls Handle in accordance with good industrial hygiene and safety practice 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Appearance Colorless odor odorless ph Boiling Point/Range C / F Melting Point/Range Flash Point Not applicable Specific Gravity Molecular Formula H Cl Molecular Weight STABILITY AND REACTIVITY Reactivity Chemical Stability Stable under normal conditions. Possibility of Hazardous Reactions Hazardous Polymerization Hazardous Reactions. Hazardous polymerization does not occur. Corrosive to metals. Conditions to Avoid Incompatible products, Excess heat. Incompatible Materials Strong oxidizing agents, Reducing agents, Bases, Metals. Hazardous Decomposition Products Hydrogen chloride gas. Carbon monoxide (CO). Carbon dioxide (CO2). 11. TOXICOLOGICAL INFORMATION Information on Toxicological Effects Page 4 / 7

5 11. TOXICOLOGICAL INFORMATION Acute Toxicity Component Information Component LD50 Oral LD50 Dermal LC50 Inhalation Water 90 ml/kg ( Rat ) Hydrochloric acid 700 mg/kg ( Rat ) 5010 mg/kg ( Rabbit ) 3124 ppm ( Rat ) 1 h Chronic Toxicity Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen Component IARC UK Hydrochloric acid group 3 Sensitization Mutagenic Effects Reproductive Effects Developmental Effects Teratogenicity Target Organs Other Adverse Effects Endocrine Disruptor Information Mutagenic effects have occurred in experimental animals. Experiments have shown reproductive toxicity effects on laboratory animals Teratogenic effects have occurred in experimental animals. None known. See actual entry in RTECS for complete information None known 12. ECOLOGICAL INFORMATION Toxicity Ecotoxicity effects Do not empty into drains Component Freshwater Algae Freshwater Fish Microtox Water Flea Water EC50: 13 mg/l 72h Hydrochloric acid 282 mg/l LC50 96 h Persistence and degradability No information available Bioaccumulative potential Component log Pow Page 5 / 7

6 Component log Pow Water Mobility in soil Results of PBT and vpvb assessment Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Waste from Residues / Unused Products Contaminated Packaging Dispose of in accordance with local regulations Empty containers should be taken for local recycling, recovery or waste disposal 14. TRANSPORT INFORMATION IMDG/IMO UN-No UN1789 Hazard Class 8 Packing Group III Proper Shipping Name HYDROCHLORIC ACID, SOLUTION ADR UN-No UN1789 Hazard Class 8 Packing Group III Proper Shipping Name HYDROCHLORIC ACID, SOLUTION IATA UN-No UN1789 Hazard Class 8 Packing Group III Proper Shipping Name HYDROCHLORIC ACID, SOLUTION 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture International Inventories Page 6 / 7

7 All of the components in the product are on the following Inventory lists: Component EINECS ELINCS NLP TSCA DSL NDSL PICCS ENCS CHINA AICS KECL Water X X - X - X X X Hydrochloric acid T X - X X X X KE X Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory EINECS/ELINCS - European Inventory Lists DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List PICCS - Philippines Inventory of Chemicals and Chemical Substances ENCS - Japan Existing and New Chemical Substances CHINA - China Inventory of Existing Chemical Substances AICS - Inventory of Chemical Substances KECL - Existing and Evaluated Chemical Substances Chemical Safety Assessment 16. OTHER INFORMATION Text of R phrases mentioned in Section 2-3 R34 - Causes burns R37 - Irritating to respiratory system Revision Date 24-Nov-2010 Revision Summary Not applicable This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006 Disclaimer The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text End of Safety Data Sheet Page 7 / 7