SAFETY DATA SHEET. 1/11 Last revised date: Product No.: 1.2. Relevant identified uses of the substance or mixture and uses advised against

Transcription

1 1/11 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier 1.2. Relevant identified uses of the substance or mixture and uses advised against Application: Adhesive Details of the supplier of the safety data sheet Supplier: Responsible for safety data sheet authoring: 1.4. Emergency telephone number Emergency telephone: AEGIS Tools International 2810 Syene Road Madison, WI, USA Poison Control Centers may be available in specific member countries.

2 2/11 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture The product is classified: 67/548/EEC: Xi;R36/37/38 R43 R52/53 GHS/CLP: Eye Irrit. 2;H STOT SE 3;H335 - Skin Sens. 1;H317 - Aquatic Chronic 3;H412 Human health: Environment: 2.2. Label elements Irritating to eyes, respiratory system and skin. May cause sensitisation by skin contact. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Contains: R36/37/38 R43 Irritant 2-Hydroxyethyl methacrylate Irritating to eyes, respiratory system and skin. May cause sensitisation by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S23 Do not breathe vapour/spray. S24/25 Avoid contact with skin and eyes. S26 S37 S41 S Other hazards PBT/vPvB: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves. In case of fire and/or explosion do not breathe fumes. This material and its container must be disposed of as hazardous waste. Contains 2-Hydroxyethyl methacrylate. May produce an allergic reaction. Not relevant.

3 3/11 SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 67/548/EEC: %: CAS-No.: EC No.: REACH Reg. No: Urethane (Meth)acrylate Oligomer Chemical name: Hazard classification: Notes: Xi;R36/ Benzyl methacrylate Xi;R36/37/ Hydroxyethyl methacrylate R43 Xi;R36/38 D Isobornyl acrylate Xi;R36/37/38 N;R Urethane acrylate Oligomer Xi;R36/37/ Urethane (Meth)acrylate Oligomer Xi;R Prop-2-enoic acid R10 C;R35 Xn;R20/21/22 N;R Photoinitiator Xi;R36/37/38 N;R51-53 D < Tripropylene glycol diacrylate R43 Xi;R36/37/38 N;R51-53

4 4/11 GHS/CLP: %: CAS-No.: EC No.: REACH Reg. No: Urethane (Meth)acrylate Oligomer Chemical name: Hazard classification: Notes: Eye Irrit. 2;H Benzyl methacrylate Eye Irrit. 2;H319 STOT SE 3;H Hydroxyethyl methacrylate Eye Irrit. 2;H319 Skin Sens. 1;H Isobornyl acrylate Eye Irrit. 2;H319 STOT SE 3;H335 Aquatic Chronic 2;H Urethane acrylate Oligomer Eye Irrit. 2;H319 STOT SE 3;H Urethane (Meth)acrylate Oligomer Eye Irrit. 2;H Prop-2-enoic acid Flam. Liq. 3;H226 Acute Tox. 4;H332 Acute Tox. 4;H312 Acute Tox. 4;H302 Skin Corr. 1A;H314 Aquatic Acute 1;H Photoinitiator Eye Irrit. 2;H319 STOT SE 3;H335 Aquatic Chronic 2;H411 < Tripropylene glycol diacrylate Eye Irrit. 2;H319 STOT SE 3;H335 Skin Sens. 1;H317 Aquatic Chronic 2;H411 D D References: The full text for all R-phrases and hazard statements are displayed in section 16.

5 5/11 SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation: Skin contact: Eye contact: Ingestion: Move injured person into fresh air and keep person calm under observation. If uncomfortable: Seek hospital and bring along these instructions. Remove contaminated clothing immediately and wash skin with soap and water. Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyelids widely. If irritation persists: Continue flushing during transport to hospital. Bring along these instructions. Immediately rinse mouth and drink plenty of water. Keep person under observation. If person becomes uncomfortable seek hospital and bring these instructions Most important symptoms and effects, both acute and delayed Symptoms/effects: See section 11 for more detailed information on health effects and symptoms Indication of any immediate medical attention and special treatment needed Medical attention/treatments: Not known. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media: 5.2. Special hazards arising from the substance or mixture Specific hazards: 5.3. Advice for firefighters Protective equipment for fire-fighters: Extinguish with foam, carbon dioxide, dry powder or water fog. Use fire-extinguishing media appropriate for surrounding materials. During fire, gases hazardous to health may be formed. Selection of respiratory protection for fire fighting: follow the general fire precautions indicated in the workplace. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions: 6.2. Environmental precautions Environmental precautions: 6.3. Methods and material for containment and cleaning up Methods for cleaning up: 6.4. Reference to other sections Avoid inhalation of vapours and contact with skin and eyes. Wear necessary protective equipment. Do not contaminate water sources or sewer. Contact local authorities in case of spillage to drain/aquatic environment. Provide adequate ventilation. Absorb spillage with non-combustible, absorbing material. References: For personal protection, see section 8. For waste disposal, see section 13.

6 6/11 SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Safe handling advice: Technical measures: Technical precautions: Observe good chemical hygiene practices. Avoid inhalation of vapours and aerosols and contact with skin and eyes. Minimize the risk of formation of aerosols. Immediately change contaminated clothes. Work practice should minimise risk of contact. Mechanical ventilation may be required Conditions for safe storage, including any incompatibilities Storage conditions: 7.3. Specific end use(s) Specific use(s): Store in tightly closed original container. Store at specified temperature. <38 C. Keep away from food, drink and animal feeding stuffs. Not relevant. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Please note that there may be national occupational exposure limits Exposure controls Engineering measures: Personal protection: Respiratory equipment: Hand protection: Eye protection: Skin protection: Hygiene measures: Environmental Exposure Controls: Provide adequate ventilation. Minimise the risk of inhalation of vapours and spray mist. Personal protection equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment. In case of inadequate ventilation and work of brief duration, use suitable respiratory equipment. In case of work of long duration use air-supplied respirator from the beginning of the work.: Use air-supplied respirator. Wear protective gloves. Nitrile gloves are recommended, but be aware that the liquid may penetrate the gloves. Frequent change is advisable. The most suitable glove must be chosen in collaboration with the supplier of gloves, who can inform about the breakthrough time of the glove material. Wear approved chemical safety goggles where eye exposure is reasonably probable. Wear appropriate clothing to prevent reasonably probable skin contact. Wash hands at the end of each work shift and before eating, smoking and using the toilet. Immediately change contaminated clothes. Wash contaminated clothing before reuse. Not available.

7 7/11 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance: Colour Odour: Melting point: Liquid. Boiling point: 120 C Flash point: Explosion limits: Relative density: Solubility: Auto-ignition temperature ( C): 9.2. Other information Refer to product description. characteristic not available >55 C No unusual fire or explosion hazards noted. not available not miscible with water not relevant Other data: Ignition temperature: 214 C SECTION 10: STABILITY AND REACTIVITY Reactivity Reactivity: Chemical stability Stability: None known Possibility of hazardous reactions Hazardous Reactions: Conditions to avoid Stable under the prescribed storage conditions. None known. Conditions/materials to avoid: Heating. Direct sunlight Incompatible materials Incompatible materials: Hazardous decomposition products Hazardous decomposition products: Oxidising materials. Amines. Strong acids. Thermal degradation or combustion may liberate carbon oxides and other toxic gases or vapours.

8 8/11 SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Inhalation: Skin contact: Eye contact: Ingestion: Specific effects: Irritating to respiratory system. Irritating to skin. May cause sensitisation by skin contact. LD50 (dermal rabbit) > 5000 mg/kg. (estimated) Irritating and may cause redness and pain. Irritating. May cause nausea, stomach pain and vomiting. Risk of sensitization or allergic reactions among sensitive individuals. SECTION 12: ECOLOGICAL INFORMATION Toxicity Ecotoxicity: Persistence and degradability Degradability: Bioaccumulative potential Bioaccumulative potential: Mobility in soil Mobility: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The degradability of the product has not been stated. No data available on bioaccumulation. No data available Results of PBT and vpvb assessment PBT/vPvB: Other adverse effects Other adverse effects: Not relevant. None known. SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. Waste is classified as hazardous waste. Note that fully cured material is not considered as hazardous waste. Waste from residues: EWC-code:

9 9/11 SECTION 14: TRANSPORT INFORMATION The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID) UN number UN-No: UN proper shipping name Proper Shipping Name: Transport hazard class(es) Class: Packing group PG: Environmental hazards Marine pollutant: - Environmentally Hazardous substance: Special precautions for user Special precautions: - None known Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Transport in bulk: Not relevant.

10 10/11 SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture National regulation: As a general rule, persons under 18 years of age are not allowed to work with this product. Users must be carefully instructed in the proper work procedure, the dangerous properties of the product and the necessary safety instructions. This Safety Data Sheet has been prepared according to the EU-regulation Chemical Safety Assessment CSA status: Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments. Directives 67/548/EEC on dangerous substances and 1999/45/EC on dangerous preparations, including amendments. Council Directive 98/24/EC of 7 April 1998 on the protection of the health and safety of workers from the risks related to chemical agents at work. Council Directive 94/33/EC of 22 June 1994 on the protection of young people at work. Commission Decision 2000/532/EC as amended by Decision 2001/118/EC establishing a list of wastes and hazardous waste pursuant to Council Directive 75/442/EEC on waste and Directive 91/689/EEC on hazardous waste with amendments. Not relevant.

11 11/11 SECTION 16: OTHER INFORMATION For restrictions on use see section 15. Wording of R-phrases/H-statements: R10 R20/21/22 R35 R36 R36/37/38 Flammable. Harmful by inhalation, in contact with skin and if swallowed. Causes severe burns. Irritating to eyes. Irritating to eyes, respiratory system and skin. R36/38 Irritating to eyes and skin. R43 R50 May cause sensitisation by skin contact. Very toxic to aquatic organisms. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. H226 H302 H312 H314 H315 H317 H319 H332 H335 H400 H411 Flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation. Very toxic to aquatic life. Toxic to aquatic life with long lasting effects. The information on this data sheet represents our current data and is reliable provided that the product is used under the prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. Made by DHI - Environment and Toxicology, Agern Allé 5, DK-2970 Hørsholm, Denmark.