: Sentinel X400 Rapid-Dose 400ml

Transcription

1 Date of issue: 01/12/2015 Revision date: 16/02/2018 Supersedes: 31/05/2017 Version: 5.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : Vaporizer : Aerosol Other means of identification : Sentinel X400 Rapid-Dose 400ml 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture : Sludge remover for central heating systems Uses advised against 1.3. Details of the supplier of the safety data sheet Manufacturer Sentinel Performance Solutions LTD 7650 Daresbury Warrington, Cheshire, WA4 4BS - Great Britain T +44 (0) F +44 (0) info.uk@sentinelprotects.com 1.4. Emergency telephone number Emergency number : +44 (0) (24 hours, 7 days) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Aerosol, Category 3 H229 Full text of H statements : see section 16 Adverse physicochemical, human health and environmental effects Pressurised container: May burst if heated Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) : Warning : potassium hydroxide, caustic potash : H229 - Pressurised container: May burst if heated. : P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P251 - Do not pierce or burn, even after use. P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 C/122 F Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures 16/02/2018 GB - en 1/7

2 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] pyridine-2-thiol 1-oxide, sodium salt (CAS-No.) (EC-No.) Full text of H-statements: see section 16 < 0,1 Acute Tox. 4 (Oral), H302 Acute Tox. 3 (Dermal), H311 Acute Tox. 4 (Inhalation), H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Aquatic Acute 1, H400 (M=100) Aquatic Chronic 1, H410 (M=10) SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice. : Remove person to fresh air and keep comfortable for breathing. : Take off immediately all contaminated clothing. Gently wash with plenty of soap and water. Wash skin with plenty of water. : Rinse immediately with plenty of water, also under the eyelids. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse eyes with water as a precaution. : Do NOT induce vomiting. Rinse mouth. Call a poison center or a doctor if you feel unwell Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media 5.2. Special hazards arising from the substance or mixture Explosion hazard Hazardous decomposition products in case of fire : Water spray. Dry powder. Foam. Carbon dioxide. : Pressurised container: May burst if heated. : Carbon monoxide. Carbon dioxide. Nitrogen oxides. Phosphorus oxides Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Do not allow run-off from fire fighting to enter drains or water courses. : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Ventilate spillage area. Evacuate unnecessary personnel. No open flames, no sparks, and no smoking. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Mechanically recover the product. Other information : Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section 8: "Exposure controls/personal protection". For further information refer to section /02/2018 GB - en 2/7

3 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Wear personal protective equipment. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not pierce or burn, even after use. : Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions 7.3. Specific end use(s) See Heading 1. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Store in original container. Keep container closed when not in use. Protect from sunlight. Do not expose to temperatures exceeding 50 C/ 122 F. Store in a well-ventilated place. Keep cool Exposure controls Appropriate engineering controls: Ensure good ventilation of the work station. Hand protection: Protective gloves. EN 374. Choosing the proper glove is a decision that depends not only on the type of material, but also on other quality features, which differ for each manufacturer. Please follow the instructions related to the permeability and the penetration time provided by the manufacturer Eye protection: Chemical goggles or safety glasses. EN 166 Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Appearance Colour Odour Odour threshold : Liquid : Aerosol. : amber. : Barely perceptible. ph : 25 C Relative evaporation rate (butylacetate=1) : < 1 Melting point : -8.5 C Freezing point : -8.5 C Boiling point : 100 C Flash point : > 100 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density : Solubility Log Pow Viscosity, kinematic Viscosity, dynamic : Not flammable : Miscible with water. 16/02/2018 GB - en 3/7

4 Explosive properties Oxidising properties Explosive limits : Product is not explosive. Pressurised container: May burst if heated. : Non oxidizing Other information SECTION 10: Stability and reactivity Reactivity Pressurised container: May burst if heated Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid Extremely high or low temperatures Incompatible materials Hazardous decomposition products Carbon monoxide. Carbon dioxide. Nitrogen oxides. Phosphorus oxides. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard Vaporizer ph: 25 C ph: 25 C Aerosol SECTION 12: Ecological information Toxicity Ecology - general Acute aquatic toxicity Chronic aquatic toxicity : The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment. pyridine-2-thiol 1-oxide, sodium salt ( ) LC50 fish mg/l EC50 Daphnia mg/l Threshold limit algae mg/l Persistence and degradability pyridine-2-thiol 1-oxide, sodium salt ( ) Persistence and degradability Readily degradable. 16/02/2018 GB - en 4/7

5 12.3. Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods Product/Packaging disposal recommendations SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN : Dispose of contents/container in accordance with licensed collector s sorting instructions. : Empty containers should be taken for recycling, recovery or waste in accordance with local regulation. ADR IMDG IATA ADN RID UN number UN proper shipping name AEROSOLS AEROSOLS Aerosols, non-flammable AEROSOLS AEROSOLS Transport document description UN 1950 AEROSOLS, 2.2, UN 1950 AEROSOLS, 2.2 (E) UN 1950 Aerosols, nonflammable, 2.2 UN 1950 AEROSOLS, 2.2 UN 1950 AEROSOLS, Transport hazard class(es) Packing group Not applicable Not applicable Not applicable Not applicable Not applicable Environmental hazards Marine pollutant : No Special precautions for user - Overland transport Classification code (ADR) : 5A Special provisions (ADR) : 190, 327, 344, 625 Limited quantities (ADR) Excepted quantities (ADR) Packing instructions (ADR) Special packing provisions (ADR) Mixed packing provisions (ADR) : 1l No supplementary information available : P207, LP02 : PP87, RR6, L2 : MP9 Transport category (ADR) : 3 Tunnel restriction code (ADR) - Transport by sea Special provisions (IMDG) : 63, 190, 277, 327, 344, 959 Limited quantities (IMDG) Excepted quantities (IMDG) Packing instructions (IMDG) EmS-No. (Fire) : E : SP277 : P207, LP02 : F-D 16/02/2018 GB - en 5/7

6 EmS-No. (Spillage) Stowage and handling (IMDG) Segregation (IMDG) : S-U : SW1, SW22 : SG69 MFAG-No : Air transport PCA Excepted quantities (IATA) PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) : Y203 : 30kgG PCA packing instructions (IATA) : 203 PCA max net quantity (IATA) : 75kg CAO packing instructions (IATA) : 203 CAO max net quantity (IATA) Special provisions (IATA) ERG code (IATA) - Inland waterway transport Classification code (ADN) : 150kg : A98, A145, A167, A802 : 2L : 5A Special provisions (ADN) : 190, 327, 344, 625 Limited quantities (ADN) Excepted quantities (ADN) Equipment required (ADN) Ventilation (ADN) : 1 L : PP Number of blue cones/lights (ADN) : 0 - Rail transport Classification code (RID) : VE04 : 5A Special provisions (RID) : 190, 327, 344, 625 Limited quantities (RID) Excepted quantities (RID) Packing instructions (RID) : 1L Transport category (RID) : 3 Hazard identification number (RID) : 20 : P207, LP Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Abbreviations and acronyms: ADR ATE European Agreement concerning the International Carriage of Dangerous Goods by Road Acute Toxicity Estimate CLP Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008 DNEL Derived-No Effect Level EC50 IARC Median effective concentration International Agency for Research on Cancer 16/02/2018 GB - en 6/7

7 IATA IMDG LC50 LD50 International Air Transport Association International Maritime Dangerous Goods Median lethal concentration Median lethal dose PBT Persistent Bioaccumulative Toxic PNEC Predicted No-Effect Concentration REACH Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006 RID vpvb Regulations concerning the International Carriage of Dangerous Goods by Rail Very Persistent and Very Bioaccumulative Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. Full text of H- and EUH-statements: Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3 Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aerosol 3 Aerosol, Category 3 Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 H229 H302 H311 H315 H319 H332 H400 H410 Pressurised container: May burst if heated. Harmful if swallowed. Toxic in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 16/02/2018 GB - en 7/7