Version 6 Print Date Revision Date IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

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1 ARALDITE 252 RESIN Version 6 Print Date IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING Product information Trade name : ARALDITE 252 RESIN Use : Resin for adhesive systems Company : Huntsman Advanced Materials (Europe)BVBA Everslaan Everberg / Belgium Telephone : Telefax : Emergency telephone : (in France ORFILA : +33(0) ) number For further Product EHS related questions concerning this document or its contents, please contact: global_product_ehs_admat@huntsman.com 2. HAZARDS IDENTIFICATION Irritating to eyes and skin. May cause sensitization by skin contact. Limited evidence of a carcinogenic effect. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature Formulated bisphenol A epoxy resin preparation Hazardous components Chemical Name CAS-No. Symbol(s): R-phrase(s) Concentration [%] Xi, N R36/38 R43 R51/ reaction product: bisphenol A- (epichlorhydrin); epoxy resin (number average molecular weight < 700) antimony trioxide EC-No.: FIRST AID MEASURES Xn R Inhalation Eye contact Skin contact : Move to fresh air. Call a physician immediately. : Rinse immediately with plenty of water for at least 15 minutes. If eye irritation persists, consult a specialist. : Wash off with soap and plenty of water. 1/7

2 ARALDITE 252 RESIN Version 6 Print Date If skin irritation persists, call a physician. Ingestion : Immediately give plenty of water (if possible charcoal slurry). Do not induce vomiting. Obtain medical attention. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Extinguishing media which must not be used for safety reasons Specific hazards during fire fighting Special protective equipment for fire-fighters : Water spray. Dry powder. Carbon dioxide (CO2). Foam. : High volume water jet. : Burning produces obnoxious and toxic fumes. Carbon oxides. : Wear self-contained breathing apparatus and protective suit. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for cleaning up : Do not breathe vapours/dust. Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. : Do not allow material to contaminate ground water system. : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). 7. HANDLING AND STORAGE Handling Advice on safe handling : Provide sufficient air exchange and/or exhaust in work rooms. Handle and open container with care. Storage Further information on storage conditions Storage hazard class Huntsman Advanced Materials : Keep away from food, drink and animal feeding stuffs. Keep container tightly closed. Keep at temperatures between 2 and 40 C. : Storage class 10, Environmentally hazardous liquids 2/7

3 ARALDITE 252 RESIN Version 6 Print Date EXPOSURE CONTROLS / PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Control Update Basis parameters antimony trioxide mg/m3 GB-OES 8H Engineering measures Ensure adequate ventilation, especially in confined areas. Personal protective equipment Respiratory protection : In case of insufficient ventilation wear suitable respiratory equipment. Filter type AX-P2 (organic vapours, particles) Eye protection Hand protection Skin and body protection Hygiene measures Protective measures : goggles : Material of gloves for long term application (BTT>480 min): Butyl rubber Ethyl Vinyl Alcohol Laminate (EVAL) Material of gloves for short term/splash application (10 min<btt<480 min): Nitrile rubber Neoprene rubber Use gloves approved to relevant standards e.g. EN 374 (Europe), F739 (US). Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material and dexterity. Always seek advice from glove suppliers. Additonal information can be found for instance at : long sleeved clothing : Keep away from food, drink and animal feeding stuffs. Wash hands before breaks and immediately after handling the product. : Avoid contact with skin, eyes and clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Colour Odour : paste : blue : slight Thermal decomposition : > 200 C 3/7

4 ARALDITE 252 RESIN Version 6 Print Date Flash point : > 100 C Method: estimated Vapour pressure Density : < 0.01 Pa at 20 C : 0.65 g/cm3 at 20 C Water solubility : at 20 C Note: practically insoluble Miscibility with water : immiscible at 20 C 10. STABILITY AND REACTIVITY Conditions to avoid Materials to avoid Hazardous decomposition products : Note: Take necessary action to avoid static electricity discharge. : Strong acids and strong bases. Strong oxidizing agents. : Burning produces obnoxious and toxic fumes. Carbon oxides. antimony oxide 11. TOXICOLOGICAL INFORMATION Acute oral toxicity Eye irritation Skin irritation Sensitization Further information : LD50 rat Dose: > 5,000 mg/kg Method: OECD 401 : irritating rabbit Method: Data based on tests on similar product. : irritating rabbit Method: Data based on tests on similar product. dermal : Causes sensitization. guinea pig Method: Data based on tests on similar product. : Epoxy resins with an average molecular weight of less than 700 may cause sensitization. 4/7

5 ARALDITE 252 RESIN Version 6 Print Date ECOLOGICAL INFORMATION Elimination information (persistence and degradability) Biodegradability : Result: Not readily biodegradable. Ecotoxicity effects Further information on ecology Additional ecological information : Avoid subsoil penetration. Prevent product from entering drains. Do not contaminate surface water. 13. DISPOSAL CONSIDERATIONS Product : Waste Key Number: Must be incinerated, when in compliance with local regulations. Container : Empty containers can be landfilled after cleaning, when in compliance with the Environmental Protection (Duty of Care) Regulations TRANSPORT INFORMATION Land transport ADR: UN-No: 3082 Class: 9 Classification code: M6 Risk No.: 90 ADR/RID-Labels: 9 Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. BISPHENOL A EPOXY RESIN RID: UN-No: 3082 Class: 9 Risk No.: 90 ADR/RID-Labels: 9 Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. BISPHENOL A EPOXY RESIN Sea transport 5/7

6 ARALDITE 252 RESIN Version 6 Print Date IMDG: UN-No: 3082 Class: 9 ADR/RID-Labels: 9 MFAG: EmS: F-A S-F Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (BISPHENOL A EPOXY RESIN) Air transport IATA-DGR: UN/ID No.: UN 3082 Class: 9 Packing instruction (cargo 914 aircraft): Max. Qty/Pack.: L ( = No limit ) Packing instruction 914 (passenger aircraft): Max. Qty/Pack.: L ( = No limit ) ADR/RID-Labels: 9 Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (BISPHENOL A EPOXY RESIN) 15. REGULATORY INFORMATION Labelling according to EEC Directive Labelling required Symbol(s): : Xn Harmful N Dangerous for the environment R-phrase(s) : R36/38 Irritating to eyes and skin. R43 May cause sensitization by skin contact. R40 Limited evidence of a carcinogenic effect. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s) : S28 After contact with skin, wash immediately with plenty of soap and water. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S61 Avoid release to the environment. Refer to 6/7

7 ARALDITE 252 RESIN Version 6 Print Date special instructions/safety data sheets. Exceptional labelling of special preparations Hazardous components which must be listed on the label : Contains epoxy constituents. See information supplied by the manufacturer. : reaction product: bisphenol A-(epichlorhydrin); epoxy resin (number average molecular weight < 700) antimony trioxide EC-No.: National legislation Notification status : EINECS yes : TSCA yes 16. OTHER INFORMATION List of R-phrases (Section 3) R36/38 Irritating to eyes and skin. R40 Limited evidence of a carcinogenic effect. R43 May cause sensitization by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The provision of Safety Data Sheets comes under Regulation 6 of CHIP (CHIP is the recognised abbreviation for the Chemicals Hazard Information and Packaging Regulations). This is an addition to the Health and Safety at Work Act 1974.Users of products supplied by Huntsman Advanced Materials should take appropriate measures to ensure working practices are in accordance with the Control of Substances Hazardous to Health Regulations (COSHH). All information is based on results gained from experience and tests and is believed to be accurate but is given without acceptance of liability for loss or damage attributable to reliance thereon as conditions of use lie outside our control. Users should always carry out sufficient tests to establish the suitability of any products for their intended applications. No statements shall be incorporated in any contract unless expressly agreed in writing nor construed as recommending the use of any product in conflict of any patent. All goods are supplied subject to Huntsman Advanced Materials General Conditions of Sale. 7/7

8 ARALDITE HARDENER Version 4 Print Date IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING Product information Trade name : ARALDITE HARDENER Use : Hardener for adhesive systems Company : Huntsman Advanced Materials (Europe)BVBA Everslaan Everberg / Belgium Telephone : Telefax : Emergency telephone : (in France ORFILA : +33(0) ) number For further Product EHS related questions concerning this document or its contents, please contact: global_product_ehs_admat@huntsman.com 2. HAZARDS IDENTIFICATION Causes burns. May cause sensitization by skin contact. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature Polyaminoamide preparation Hazardous components Chemical Name CAS-No. Symbol(s): R-phrase(s) Concentration [%] tetraethylenepentamine C, N R21/22 R34 R EC-No.: R51/53 4. FIRST AID MEASURES Inhalation Eye contact Skin contact Ingestion : Move to fresh air. If symptoms persist, call a physician. : Rinse immediately with plenty of water for at least 15 minutes. If eye irritation persists, consult a specialist. : Wash off with soap and plenty of water. If skin irritation persists, call a physician. : Immediately give plenty of water (if possible charcoal slurry). Do not induce vomiting. 1/7

9 ARALDITE HARDENER Version 4 Print Date FIRE-FIGHTING MEASURES Suitable extinguishing media Extinguishing media which must not be used for safety reasons Special protective equipment for fire-fighters Further information : Water spray. Carbon dioxide (CO2). Foam. Dry powder. : High volume water jet. : Wear self-contained breathing apparatus and protective suit. : Burning produces obnoxious and toxic fumes. Carbon oxides. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for cleaning up : Do not breathe vapours/dust. Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. : Do not allow material to contaminate ground water system. : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). 7. HANDLING AND STORAGE Handling Advice on safe handling : Provide sufficient air exchange and/or exhaust in work rooms. Handle and open container with care. Storage Further information on storage conditions Storage hazard class Huntsman Advanced Materials : Keep away from food, drink and animal feeding stuffs. Keep container tightly closed. Keep at temperatures between 2 and 40 C. : Storage class 8, Corrosive substances 2/7

10 ARALDITE HARDENER Version 4 Print Date EXPOSURE CONTROLS / PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Control parameters Update Basis Personal protective equipment Respiratory protection : In case of insufficient ventilation wear suitable respiratory equipment. Filter type AX-P2 (organic vapours, particles) Eye protection Hand protection Skin and body protection Hygiene measures Protective measures : Tightly fitting safety goggles. : Material of gloves for long term application (BTT>480 min): Butyl rubber Ethyl Vinyl Alcohol Laminate (EVAL) Material of gloves for short term/splash application (10 min<btt<480 min): Nitrile rubber Use gloves approved to relevant standards e.g. EN 374 (Europe), F739 (US). Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material and dexterity. Always seek advice from glove suppliers. Additonal information can be found for instance at : long sleeved clothing : Keep away from food, drink and animal feeding stuffs. Wash hands before breaks and immediately after handling the product. : Avoid contact with skin, eyes and clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Colour : paste : off-white Boiling point : > 200 C Thermal decomposition : > 200 C Flash point : > 100 C Method: estimated Density : 0.65 g/cm3 at 20 C 3/7

11 ARALDITE HARDENER Version 4 Print Date Water solubility : at 20 C Note: practically insoluble Miscibility with water : immiscible at 20 C 10. STABILITY AND REACTIVITY Conditions to avoid Materials to avoid Hazardous decomposition products : Note: Take necessary action to avoid static electricity discharge. : Strong acids and strong bases. Strong oxidizing agents. : Carbon oxides. Nitrogen oxides. Burning produces obnoxious and toxic fumes. 11. TOXICOLOGICAL INFORMATION Acute oral toxicity Eye irritation Skin irritation Sensitization : LD50 rat Dose: > 2,000 mg/kg : Corrosive rabbit : Corrosive rabbit dermal : Causes sensitization. guinea pig dermal 12. ECOLOGICAL INFORMATION Ecotoxicity effects Further information on ecology Additional ecological information : Avoid subsoil penetration. Prevent product from entering drains. Do not contaminate surface water. 13. DISPOSAL CONSIDERATIONS Product : Waste Key Number: /7

12 ARALDITE HARDENER Version 4 Print Date Must be incinerated, when in compliance with local regulations. Container : Empty containers can be landfilled after cleaning, when in compliance with the Environmental Protection (Duty of Care) Regulations TRANSPORT INFORMATION Land transport ADR: UN-No: 2735 Class: 8 Classification code: C7 Risk No.: 80 ADR/RID-Labels: 8 Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. TETRAETHYLENE PENTAMINE RID: UN-No: 2735 Class: 8 Risk No.: 80 ADR/RID-Labels: 8 Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. TETRAETHYLENE PENTAMINE Sea transport IMDG: UN-No: 2735 Class: 8 ADR/RID-Labels: 8 MFAG: EmS: F-A S-B Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (TETRAETHYLENE PENTAMINE) Air transport IATA-DGR: UN/ID No.: UN 2735 Class: 8 Packing instruction (cargo 820 aircraft): Max. Qty/Pack.: L 5/7

13 ARALDITE HARDENER Version 4 Print Date ( = No limit ) Packing instruction 818 (passenger aircraft): Max. Qty/Pack.: 5.00 L ( = No limit ) ADR/RID-Labels: 8 Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (TETRAETHYLENE PENTAMINE) 15. REGULATORY INFORMATION Labelling according to EEC Directive Labelling required Symbol(s): : C Corrosive R-phrase(s) : R34 Causes burns. R43 May cause sensitization by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s) : S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). S28 After contact with skin, wash immediately with plenty of soap and water. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Hazardous components which must be listed on the label : tetraethylenepentamine EC-No.: National legislation Notification status : EINECS yes : TSCA yes 6/7

14 ARALDITE HARDENER Version 4 Print Date : AICS yes 16. OTHER INFORMATION List of R-phrases (Section 3) R21/22 Harmful in contact with skin and if swallowed. R34 Causes burns. R43 May cause sensitization by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The provision of Safety Data Sheets comes under Regulation 6 of CHIP (CHIP is the recognised abbreviation for the Chemicals Hazard Information and Packaging Regulations). This is an addition to the Health and Safety at Work Act 1974.Users of products supplied by Huntsman Advanced Materials should take appropriate measures to ensure working practices are in accordance with the Control of Substances Hazardous to Health Regulations (COSHH). All information is based on results gained from experience and tests and is believed to be accurate but is given without acceptance of liability for loss or damage attributable to reliance thereon as conditions of use lie outside our control. Users should always carry out sufficient tests to establish the suitability of any products for their intended applications. No statements shall be incorporated in any contract unless expressly agreed in writing nor construed as recommending the use of any product in conflict of any patent. All goods are supplied subject to Huntsman Advanced Materials General Conditions of Sale. 7/7

15 ARALDITE 252 Version 3 Print Date Revision Date IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING Product information Trade name : ARALDITE 252 Use : 2-Component adhesive system Company : Huntsman Advanced Materials (Europe)BVBA Everslaan Everberg / Belgium Telephone : Telefax : Emergency telephone : (in France ORFILA : +33(0) ) number For further Product EHS related questions concerning this document or its contents, please contact: global_product_ehs_admat@huntsman.com 2. HAZARDS IDENTIFICATION Refer to SDS for individual components of the pack. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature Working pack (preparation) 4. FIRST AID MEASURES General advice : Refer to SDS for individual components of the pack. 5. FIRE-FIGHTING MEASURES Further information : Refer to SDS for individual components of the pack. 6. ACCIDENTAL RELEASE MEASURES Additional advice : Refer to SDS for individual components of the pack. 1/5

16 ARALDITE 252 Version 3 Print Date Revision Date HANDLING AND STORAGE Storage Further information on storage conditions Storage hazard class Huntsman Advanced Materials : Keep at temperatures between 2 and 40 C. : Storage class 8, Corrosive substances 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Control parameters Update Basis Personal protective equipment Protective measures : Refer to SDS for individual components of the pack. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : paste Flash point : > 100 C Method: DIN (Pensky-Martens Closed Cup) Density Miscibility with water : 0.65 g/cm3 at 20 C : immiscible at 20 C 10. STABILITY AND REACTIVITY Hazardous decomposition products : Refer to SDS for individual components of the pack. 11. TOXICOLOGICAL INFORMATION Acute toxicity (other route) : Remarks: Refer to SDS for individual components of the pack. 12. ECOLOGICAL INFORMATION Ecotoxicity effects 2/5

17 ARALDITE 252 Version 3 Print Date Revision Date Further information on ecology 13. DISPOSAL CONSIDERATIONS Product : Waste Key Number: Must be incinerated, when in compliance with local regulations. Container : Empty containers can be landfilled after cleaning, when in compliance with the Environmental Protection (Duty of Care) Regulations TRANSPORT INFORMATION Land transport ADR: UN-No: 2735 Class: 8 Classification code: C7 Risk No.: 80 ADR/RID-Labels: 8 Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. TETRAETHYLENE PENTAMINE RID: UN-No: 2735 Class: 8 Risk No.: 80 ADR/RID-Labels: 8 Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. TETRAETHYLENE PENTAMINE Sea transport IMDG: UN-No: 2735 Class: 8 ADR/RID-Labels: 8 MFAG: EmS: F-A S-B Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (TETRAETHYLENE PENTAMINE) Air transport IATA-DGR: 3/5

18 ARALDITE 252 Version 3 Print Date Revision Date UN/ID No.: UN 2735 Class: 8 Packing instruction (cargo 820 aircraft): Max. Qty/Pack.: L ( = No limit ) Packing instruction 818 (passenger aircraft): Max. Qty/Pack.: 5.00 L ( = No limit ) ADR/RID-Labels: 8 Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (TETRAETHYLENE PENTAMINE) 15. REGULATORY INFORMATION Labelling according to EEC Directive Labelling required Symbol(s): : N Dangerous for the environment C Corrosive R-phrase(s) : R34 Causes burns. R40 Limited evidence of a carcinogenic effect. R43 May cause sensitization by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s) : S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). S28 After contact with skin, wash immediately with plenty of soap and water. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Exceptional labelling of special preparations Hazardous components which must be listed on the label : Contains epoxy constituents. See information supplied by the manufacturer. : reaction product: bisphenol A-(epichlorhydrin); epoxy resin (number average molecular weight < 700) tetraethylenepentamine EC-No.: /5

19 ARALDITE 252 Version 3 Print Date Revision Date National legislation Notification status 16. OTHER INFORMATION The provision of Safety Data Sheets comes under Regulation 6 of CHIP (CHIP is the recognised abbreviation for the Chemicals Hazard Information and Packaging Regulations). This is an addition to the Health and Safety at Work Act 1974.Users of products supplied by Huntsman Advanced Materials should take appropriate measures to ensure working practices are in accordance with the Control of Substances Hazardous to Health Regulations (COSHH). All information is based on results gained from experience and tests and is believed to be accurate but is given without acceptance of liability for loss or damage attributable to reliance thereon as conditions of use lie outside our control. Users should always carry out sufficient tests to establish the suitability of any products for their intended applications. No statements shall be incorporated in any contract unless expressly agreed in writing nor construed as recommending the use of any product in conflict of any patent. All goods are supplied subject to Huntsman Advanced Materials General Conditions of Sale. 5/5