Safety Data Sheet according to Regulation (EC) No1907/2006

Transcription

1 Safety Data Sheet according to Regulation (EC) No1907/2006 LOCTITE ABLESTIK CT PTB Page 1 of 10 SDS No. : Revision: printing date: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier LOCTITE ABLESTIK CT PTB Contains: 2-Ethyl-4-methyl-1H-imidazole-1-propiononitrile 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Adhesive 1.3. Details of the supplier of the safety data sheet Henkel Limited 2 Bishop Square Business Park AL109EY Herfordshire Hatfield Great Britain Phone: Fax-no.: ua-productsafety.uk@uk.henkel.com 1.4. Emergency telephone number 24 Hours Emergency Tel: +44 (0) Classification of the substance or mixture SECTION 2: Hazards identification Classification (CLP): Serious eye damage Category 1 H318 Causes serious eye damage. Classification (DPD): Xi - Irritant R41 Risk of serious damage to eyes Label elements Label elements (CLP): Hazard pictogram:

2 Signal word: Hazard statement: LOCTITE ABLESTIK CT PTB Page 2 of 10 Danger H318 Causes serious eye damage. Precautionary statement: Prevention Precautionary statement: Response P280 Wear eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Label elements (DPD): Xi - Irritant Risk phrases: R41 Risk of serious damage to eyes. Safety phrases: S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S39 Wear eye/face protection Other hazards Self classification: product testing according to Classification, Labelling and Packaging Regulation EC/1272/2008, Annex 1, Part 4. SECTION 3: Composition/information on ingredients

3 LOCTITE ABLESTIK CT PTB Page 3 of 10 Declaration of the ingredients according to CLP (EC) No 1272/2008: Silver >= 99,9 % Ag in powder (< 1 mm) H-Imidazole, 2-methyl-1-(phenylmethyl) Ethyl-4-methyl-1H-imidazole-1- propiononitrile EC Number REACH-Reg No. content Classification >= 80- <= 100 % Acute hazards to the aquatic environment 1 H400 Chronic hazards to the aquatic environment 1 H410 M factor: M factor (Chron Aquat Tox): >= 10- < 20 % Acute toxicity 4; Oral H302 Serious eye irritation 1 H318 Specific target organ toxicity - single exposure 3 H >= 1- < 3 % Acute toxicity 3; Oral H301 Skin irritation 2; Dermal H315 Serious eye damage/eye irritation 1 H >= 1- < 5 % Acute toxicity 4; Oral H302 Serious eye damage/eye irritation 1 H318 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available. Declaration of ingredients according to DPD (EC) No 1999/45: Silver >= 99,9 % Ag in powder (< 1 mm) H-Imidazole, 2-methyl-1- (phenylmethyl) Ethyl-4-methyl-1H-imidazole-1- propiononitrile EC Number content Classification REACH-Reg No >= 80 - <= 100 % N - Dangerous for the environment; R50/ >= 10 - < 20 % Xn - Harmful; R22 Xi - Irritant; R41 R >= 1 - < 3 % Xn - Harmful; R22 Xi - Irritant; R38, R >= 1 - < 5 % Xn - Harmful; R22 Xi - Irritant; R36/38 For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available Description of first aid measures SECTION 4: First aid measures Inhalation: Should not be a problem as product is of low volatility. However, if feeling unwell remove patient to fresh air. Skin contact: Rinse with running water and soap. Obtain medical attention if irritation persists. Eye contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Seek medical advice.

4 LOCTITE ABLESTIK CT PTB Page 4 of 10 Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor Most important symptoms and effects, both acute and delayed Prolonged or repeated skin contact with silver and its salts may cause a blue-gray discoloration of the skin and mucous membranes that is irreversible (Argyria). Prolonged or repeated contact may cause skin irritation. EYE: Irritation, conjunctivitis Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures 5.1. Extinguishing media Suitable extinguishing media: water, carbon dioxide, foam, powder SECTION 5: Firefighting measures Extinguishing media which must not be used for safety reasons: High pressure waterjet 5.2. Special hazards arising from the substance or mixture In the event of a fire, carbon monoxide (CO) and carbon dioxide (CO2) can be released. In case of fire, keep containers cool with water spray Advice for firefighters Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid contact with skin and eyes. Wear protective equipment Environmental precautions Do not empty into drains / surface water / ground water Methods and material for containment and cleaning up For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal Reference to other sections See advice in section Precautions for safe handling Avoid skin and eye contact. See advice in section 8 Hygiene measures: Good industrial hygiene practices should be observed. Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. SECTION 7: Handling and storage 7.2. Conditions for safe storage, including any incompatibilities Ensure good ventilation/extraction. Keep container tightly sealed. Store at room temperature.

5 LOCTITE ABLESTIK CT PTB Page 5 of Specific end use(s) Adhesive SECTION 8: controls/personal protection 8.1. Control parameters Occupational Limits Valid for Great Britain Ingredient ppm mg/m 3 Type Category Remarks SILVER (METALLIC) 0,1 Time Weighted Average EH40 WEL (TWA): SILVER, METALLIC ,1 Time Weighted Average (TWA): Indicative ECTLV Predicted No-Effect Concentration (PNEC): Name on list Environmental Compartment period mg/l ppm mg/kg others aqua 0,056 mg/l (freshwater) aqua (marine 0,0056 mg/l water) aqua 0,56 mg/l (intermittent releases) sediment 0,24 mg/kg (freshwater) sediment 0,02 mg/kg (marine water) soil 0, mg/kg STP 452 mg/l Remarks Derived No-Effect Level (DNEL): Name on list Application Area Route of Health Effect worker inhalation Long term exposure - systemic effects worker Dermal Long term exposure - systemic effects general inhalation Long term population exposure - systemic effects general population Dermal Long term exposure - systemic effects Time 130 mg/m3 19 mg/kg bw/day 28 mg/m3 8 mg/kg bw/day Remarks Biological Indices: None 8.2. controls:

6 LOCTITE ABLESTIK CT PTB Page 6 of 10 Respiratory protection: Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk of splashing. Skin protection: Wear suitable protective clothing. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance liquid Odor Odour threshold silver Slight ph Initial boiling point Flash point Decomposition temperature Vapour pressure Density () Bulk density Viscosity Viscosity (kinematic) Explosive properties Solubility (qualitative) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties Not applicable Not determined > 100 C (> 212 F) 3,3 g/cm3 Insoluble Not determined 9.2. Other information

7 LOCTITE ABLESTIK CT PTB Page 7 of 10 SECTION 10: Stability and reactivity Reactivity Reducing agents. Strong oxidizing agents Chemical stability Stable under recommended storage conditions Possibility of hazardous reactions See section reactivity Conditions to avoid No decomposition if stored and applied as directed Incompatible materials See section reactivity Hazardous decomposition products Hydrocarbons carbon oxides Information on toxicological effects SECTION 11: Toxicological information General toxicological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Oral toxicity: May cause irritation to the digestive tract. Inhalative toxicity: May cause irritation to respiratory system. Dermal toxicity: Prolonged or repeated skin contact with silver and its salts may cause a blue-gray discoloration of the skin and mucous membranes that is irreversible (Argyria). Skin irritation: Prolonged or repeated contact may cause skin irritation. Eye irritation: Causes serious eye damage. Acute oral toxicity: type Route of application time Species Method LD mg/kg oral rat OECD Guideline 401 (Acute Oral Toxicity) Acute inhalative toxicity: type Route of application time Species Method LC50 > 2,68 mg/l inhalation 4 h rat OECD Guideline 403 (Acute Inhalation Toxicity)

8 LOCTITE ABLESTIK CT PTB Page 8 of 10 Acute dermal toxicity: 1H-Imidazole, 2-methyl- 1-(phenylmethyl) Route of Species type application time LD50 > mg/kg dermal rabbit Method Serious eye damage/irritation: Result time Species Method highly irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) SECTION 12: Ecological information General ecological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following Toxicity Ecotoxicity: Self classification: product testing according to Classification, Labelling and Packaging Regulation EC/1272/2008, Annex 1, Part 4. Do not empty into drains / surface water / ground water. type Acute Toxicity Study time Species LC mg/l Fish 96 h Leuciscus idus Method EC50 > 500 mg/l Daphnia 48 h Daphnia magna EU Method C.2 (Acute Toxicity for Daphnia) EC mg/l Algae 72 h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) OECD Guideline 201 (Alga, Growth Inhibition Test) Persistence and degradability Persistence and Biodegradability: The product is not biodegradable. Result Route of application Degradability Method aerobic % OECD Guideline 301 C (Ready Biodegradability: Modified MITI Test (I)) Bioaccumulative potential / Mobility in soil Mobility: Cured adhesives are immobile. Bioaccumulative potential: No data available. LogKow Bioconcentration factor (BCF) time Species Temperature Method -0,566 OECD Guideline 107 (Partition Coefficient (noctanol / water), Shake Flask Method)

9 LOCTITE ABLESTIK CT PTB Page 9 of Results of PBT and vpvb assessment Silver >= 99,9 % Ag in powder (< 1 mm) PBT/vPvB Not fulfilling PBT (persistent/bioaccummulative/toxic) criteria Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria Other adverse effects No data available. SECTION 13: Disposal considerations Waste treatment methods Product disposal: Do not empty into drains / surface water / ground water. Dispose of in accordance with local and national regulations. Disposal of uncleaned packages: After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated. Waste code waste adhesives and sealants containing organic solvents and other dangerous substances The valid EWC waste code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We will be happy to advise you. SECTION 14: Transport information UN number UN proper shipping name Transport hazard class(es) Packaging group Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code not applicable

10 LOCTITE ABLESTIK CT PTB Page 10 of 10 SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content < 15 % (1999/13/EC) Chemical safety assessment A chemical safety assessment has not been carried out. SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: R22 Harmful if swallowed. R36/38 Irritating to eyes and skin. R38 Irritating to skin. R41 Risk of serious damage to eyes. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R67 Vapours may cause drowsiness and dizziness. H301 Toxic if swallowed. H302 Harmful if swallowed. H315 Causes skin irritation. H318 Causes serious eye damage. H336 May cause drowsiness or dizziness. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.