EPIKURE(TM) 3090 Curing Agent

Transcription

1 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING Product information Trade name : Product code : K814A Product Type : Curing agent. Company : Resolution Europe B. V. Postbus AN Hoogvliet Rt. Nederland Telephone : Emergency telephone number : COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature : Contains a fatty acid amido amine and ethyl alcohol Hazardous components Chemical Name CAS-No. / EINECS-No. Fatty acid amido amine * * 2,4,6-TRIS[DIMETHYLAMINOMETHYL] PHENOL ETHANOL Symbol(s) R-phrase(s) Weight % N R51/ Xn R22; R36/ F R HAZARDS IDENTIFICATION Classification : Dangerous for the environment. Flammable. Risk advice to man and the environment Human health hazards : No specific hazards under normal use conditions. Safety hazards : Flammable. 1/8

2 Environmental hazards : Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. 4. FIRST AID MEASURES Inhalation : Remove to fresh air. If rapid recovery does not occur, obtain medical attention. Skin contact : Remove contaminated clothing. Wash skin with water using soap if available. Eye contact : Flush eye with water. Ingestion : Do not induce vomiting. If rapid recovery does not occur, obtain medical attention. Notes to physician Symptoms : Not expected to give rise to an acute hazard under normal conditions of use. 5. FIRE-FIGHTING MEASURES Unsuitable extinguishing agents Suitable extinguishing media : Water in a jet. : Foam. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Specific hazards during fire fighting Special protective equipment for fire-fighters : Hazardous combustion products may include oxides of nitrogen, carbon monoxide : Full protective clothing and self-contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Avoid contact with skin, eyes and clothing Do not breathe mists, aerosols, fumes, spray Ventilate contaminated area thoroughly. Environmental precautions : Prevent contamination of soil and water. Prevent further leakage or spillage if safe to do so. 2/8

3 Clean-up methods - small spillage Clean-up methods - large spillage : Shut off leaks if without risk Remove ignition sources. Ventilate contaminated area thoroughly. Absorb or contain liquid with sand, earth or spill control material. Shovel up and place in a labelled, sealable container for subsequent safe disposal. Put leaking containers in a labelled drum or overdrum. Scrub contaminated surfaces with detergent solution Retain washings as contaminated waste. : Transfer to a labelled, sealable container for product recovery or safe disposal. Treat residues as for small spillage. Additional advice : See Section 13 for information on disposal. 7. HANDLING AND STORAGE Handling Advice on safe handling : Avoid contact with skin, eyes and clothing Do not breathe mists, aerosols, fumes, spray Only use in well ventilated areas. Take precautionary measures against static discharge. Storage Requirements for storage areas and containers : Keep container tightly closed and in a cool, well-ventilated place. Keep container dry. Do not smoke in storage areas. Keep away from direct sunlight and other sources of heat or ignition. Storage temperature : Ambient. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Components with workplace control parameters Components with workplace control parameters Regulation / Update Exposure time Value Remarks Fatty acid amido amine ACGIH None established. 2,4,6- TRIS[DIMETHYLAMINOM ETHYL] PHENOL ACGIH None established. 3/8

4 ETHANOL ACGIH/2002 Time Weighted Average (TWA): ppm Engineering measures Use local exhaust ventilation. Personal protective equipment Respiratory protection : If risk of inhalation, use approved respirator (e.g. CEN, NIOSH/OSHA, AS) as required to prevent over exposure. Use an air-supplied respirator where high concentrations are expected, or an air-purifying respirator for organic vapours (with combined particulate filter if mist is present). Note: an airsupplied respirator should always be used in confined spaces. Hand protection : Neoprene or nitrile rubber gloves gauntlet type Eye protection : Monogoggles Skin and body protection : Standard issue work clothes Safety boots - chemical resistant without lace holes Protective measures : Wear protective clothing specified for normal operations. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form : Liquid Colour : Amber Odour : Aminic Safety data Boiling point : > 85 C Flash point : 35 C (Setaflash) Density : 982 kg/m3 at 20 C Solubility in water : Partially soluble. Viscosity, dynamic : mpa s at 25 C Brookfield 4/8

5 Other physico-chemical properties : The above properties are typical values only and do not constitute a specification (refer to supplier for supply specification). 10. STABILITY AND REACTIVITY Conditions to avoid Materials to avoid Hazardous decomposition products Hazardous reactions : Heat, flames and sparks. : Strong oxidizing agents. : None known. : Stable under normal use conditions. 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : Expected to be of low toxicity, LD50 > 2000 mg/kg. Acute inhalation toxicity : Expected to be of low toxicity, LC50 > 5 mg/l. Acute dermal toxicity : Expected to be of low toxicity, LD50 > 2000 mg/kg. Eye irritation : Not expected to be irritating. Skin irritation : Not expected to be irritating. Sensitization : Not expected to be a skin sensitiser. Basis for assessment : Information given is based on a knowledge of the constituents and the toxicology of similar substances. Human effects : See Section 4 for information regarding acute effects to humans. 12. ECOLOGICAL INFORMATION Elimination information (persistence and degradability) Biodegradability : Expected to be not readily biodegradable. Bioaccumulation : Not expected to bioaccumulate significantly. Ecotoxicity effects Toxicity to fish : Expected to be toxic, 1 < LC/EC/IC 50 <= 10 mg/l. Mobility : If product enters soil, one or more constituents will be mobile and may contaminate groundwater. 5/8

6 : Floats on water. Sewage treatment : Expected to be practically non toxic, LC/EC/IC 50 > 100 mg/l. Basis for assessment : Ecotoxicological data have not been determined specifically for this product. The information given below is based on a knowledge of the components and the ecotoxicology of similar products. 13. DISPOSAL CONSIDERATIONS Product disposal : Recover or recycle if possible. Otherwise: Incineration with wet scrubbing facilities. Dispose to licensed disposal contractor. Container disposal: : Keep container labelled until cleaned and then remove or deface labels. Drain container thoroughly. Rinse three times with suitable solvent After draining, vent in a safe place away from sparks and fire. Treat rinsings as for product disposal. Send to drum recoverer or metal reclaimer. Local legislation : The recommendations given are considered appropriate for safe disposal. However, local regulations may be more stringent and these must be complied with. 14. TRANSPORT INFORMATION ADR: UN-No: 1866 Class: 3 Classification code: F1 Packaging group: III Labelling No.: 3 Risk No.: 33 Description of the goods RESIN SOLUTION flammable 640 H contains ETHANOL, TRIETHYLENETETRAMINE RID: UN-No: 1866 Class: 3 Classification code: F1 Packaging group: III Labelling No.: 3 Risk No.: 33 Description of the goods RESIN SOLUTION flammable 640 H contains ETHANOL, TRIETHYLENETETRAMINE 6/8

7 ICAO/IATA-DGR: UN-No: 1866 Class: 3 Packaging group: III Labelling No.: 3 Description of the goods RESIN SOLUTION flammable 640 E contains ETHANOL, TRIETHYLENETETRAMINE IMDG: UN-No: 1866 Class: 3 Packaging group: III Labelling No.: 3 Description of the goods RESIN SOLUTION flammable 640 E contains ETHANOL, TRIETHYLENETETRAMINE 15. REGULATORY INFORMATION Classification : Dangerous for the environment. Flammable. Symbol(s) N - Dangerous for the environment R-phrase(s) : R10 Flammable. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s) : S24/25 Avoid contact with skin and eyes. S57 Use appropriate container to avoid environmental contamination. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Notification status EINECS : All components listed or polymer exempt. ENCS (JP) : Not all components listed. TSCA : All components listed. AICS : Not all components listed. 7/8

8 DSL : Not all components listed. TCCL : Not all components listed. IECSC : Not all components listed. PICCS (PH) : Not all components listed. 16. OTHER INFORMATION Further information R-phrase(s): R11 R22 Highly flammable. Harmful if swallowed. R36/38 Irritating to eyes and skin. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Uses and restrictions : Use as a curing agent for epoxy resins. Reference : The content and format of this safety data sheet is in accordance with Commission Directive 2001/58/EC. Other information : EPIKURE is a Resolution trade mark. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. A vertical bar ( ) in the left margin indicates an amendment from the previous version. 8/8