Material Safety Data Sheet

Transcription

1 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Product Use Description: Synonyms: Plant protection agent Rancona V100 (Uncoloured), /Carboxin 25/400 g/l Company: Chemtura Corporation 199 Benson Road Middlebury, CT United States of America Telephone: (US) Emergency telephone number: CHEMTREC: (24 hours) : Chemtura Corporation Emergency Response: CHEMTURA : For additional emergency telephone numbers see section 16 of the Safety Data Sheet. Prepared by 03/18/2014 Product Safety Department (US) MSDSRequest@chemtura.com SECTION 2. HAZARDS IDENTIFICATION Emergency Overview CAUTION! Form: liquid Colour: beige Odour: mild Hazard Summary OSHA Hazards : : Harmful if swallowed. May cause skin irritation. This product is for experimental uses only. The product has not been completely analysed and all of the hazards may not be known. Please use caution while handling this product. HARMFUL BY INGESTION. MILD SKIN IRRITANT WHMIS Classification : : This product is registered under the Pest Control Products Act and is therefore exempt from WHMIS supplier labeling and MSDS requirements. Please read entire MSDS and product label for safety precautions. SAP / 13 SDS Number:

2 Potential Health Effects Primary Routes of Entry Aggravated Medical Condition Inhalation Skin Eyes Ingestion Symptoms of Overexposure : Skin Absorption Inhalation Ingestion : Dermatitis Skin disorders Allergies : Dust may cause irritation of the respiratory tract. : May cause skin irritation. : May cause eye irritation due to nuisance dust. : Harmful if swallowed. : Sweating Dizziness Headache Nausea Vomiting Diarrhoea More severe effects if alcohol is consumed. Carcinogenicity: IARC OSHA NTP ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. Environmental Effects Environmental Effects : Dangerous for the environment SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Component / CAS-No propane-1,2-diol (Sum of vapour and particulates) Weight percent % >= 10 - < 30 % SAP / 13 SDS Number:

3 % SECTION 4. FIRST AID MEASURES First aid procedures Inhalation Skin contact : Remove to fresh air. Obtain medical attention. : Remove contaminated clothing and shoes. Wash off with warm water and soap. If symptoms persist, call a physician. Wash contaminated clothing before re-use. Destroy contaminated shoes. Eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician. Ingestion : Do NOT induce vomiting. Rinse mouth with water. Obtain medical attention. Notes to physician Symptoms : Sweating Dizziness Headache Nausea Vomiting Diarrhoea More severe effects if alcohol is consumed. SECTION 5. FIREFIGHTING MEASURES Flammable properties Flash point Ignition temperature Lower explosion limit Upper explosion limit : Remarks: not applicable : Remarks: not applicable : Remarks: no data available : Remarks: no data available Fire fighting Suitable extinguishing media : Extinguishing media - large fires Alcohol-resistant foam (on small fires) Carbon dioxide (CO2) Dry chemical Water spray SAP / 13 SDS Number:

4 Unsuitable extinguishing media Further information : Water spray jet : Use water spray to cool unopened containers. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Protective equipment and precautions for firefighters Specific hazards during firefighting : Burning produces irritant fumes. Exposure to decomposition products may be a hazard to health. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. Full protective flameproof clothing SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for containment / Methods for cleaning up Additional advice : Wear suitable protective equipment. Avoid contact with skin and eyes. : Should not be released into the environment. Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration. : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Large spills should be collected mechanically (remove by pumping) for disposal. Keep in suitable, closed containers for disposal. : Keep in properly labelled containers. Dispose of rinse water as waste water. SECTION 7. HANDLING AND STORAGE Handling Handling procedures : Use plant protection products safely. Always read the label and product information before use. Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Wear personal protective equipment. Do not breathe vapours or spray mist. Use only in area provided with appropriate exhaust ventilation. Handle and open container with care. Wash thoroughly after handling. Storage Requirements for storage areas and containers : Keep containers tightly closed in a dry, cool and well-ventilated place. Keep only in the original container. SAP / 13 SDS Number:

5 Other data : Stable at normal ambient temperature and pressure. Do not freeze. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Components with workplace control parameters Components / CAS-No. Value / Basis / Update propane-1,2-diol (Sum of vapour and particulates) TWA US WEEL Control parameters 10 mg/m3 Further information Engineering measures Engineering measures : Use mechanical ventilation for general area control. Ensure that extracted air cannot be returned to the workplace through the ventilation system. Ensure that eyewash stations and safety showers are close to the workstation location. Personal protective equipment Eye protection : Safety glasses with side-shields or Safety goggles Hand protection : Impervious gloves Skin and body protection Respiratory protection : impervious clothing Long sleeved clothing To protect against splashes from pouring: Rubber or plastic boots Rubber or plastic apron Remove and wash contaminated clothing before re-use. Discard contaminated shoes. : In the case of vapour formation use a respirator with an approved filter. Respirator with a vapour filter (EN 141) Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes and clothing. Do not inhale aerosol. Wear suitable gloves and eye/face protection. When using do not eat, drink or smoke. Wash thoroughly after handling. Keep working clothes separately. Remove and wash contaminated clothing before re-use. SAP / 13 SDS Number:

6 Contaminated work clothing should not be allowed out of the workplace. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Colour Odour : liquid : beige : mild Safety data Flash point Ignition temperature Lower explosion limit Upper explosion limit Auto-ignition temperature : Note: not applicable : Remarks: not applicable ph : 7-9 Vapour pressure Density Water solubility Partition coefficient: n- octanol/water Solubility in other solvents Viscosity, dynamic Viscosity, kinematic Relative vapour density Evaporation rate : no data available : g/cm3 at 68 F (20 C) : Note: dispersible : Medium: Organic solvents Note: not applicable SECTION 10. STABILITY AND REACTIVITY Conditions to avoid : Remarks: Extremes of temperature and direct sunlight. SAP / 13 SDS Number:

7 Materials to avoid Hazardous decomposition products Thermal decomposition Hazardous reactions : Remarks: Oxidizing agents Strong acids and strong bases : Note: Carbon oxides nitrogen oxides (NOx) Sulphur oxides : Remarks: no data available : Hazardous polymerisation does not occur. SECTION 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50: > 1,750 mg/kg Species: rat Acute inhalation toxicity : LC50: > 5.04 mg/l Exposure time: 4 h Species: rat Acute dermal toxicity : LD50: > 5,000 mg/kg Species: rabbit Skin irritation : Species: rabbit Result: Mild skin irritation Eye irritation : Species: rabbit Result: No eye irritation Sensitisation : LLNA Species: guinea pig Result: Did not cause sensitization on laboratory animals. Repeated dose toxicity : Species: rat, male Application Route: Dermal Exposure time: (28 d) NOEL: 30 mg/kg Species: rat, male Application Route: Oral Exposure time: (90 d) NOEL: 5.5 mg/kg : Species: rat, female Application Route: Oral SAP / 13 SDS Number:

8 Dose: 3.1, 7.0, 15.4 and 33.2 mg/kg Exposure time: 13 weeks () NOEL: 7 mg/kg Lowest observable effect level: 33.2 mg/kg Species: rat, male Application Route: Oral Dose: 2.5, 5.8, 12.6, 25.9 and 52.2 Exposure time: 13 weeks () NOEL: 25.9 mg/kg Lowest observable effect level: 52.2 mg/kg Species: rat, male and female Application Route: Dermal Dose: 0, 2, 10 or 40 mg/kg bw/day Exposure time: 13 weeks () NOEL: 10 mg/kg Lowest observable effect level: 40 mg/kg Species: rat, male and female Application Route: Inhalation Dose: 0, 30, 100, 300 or 1000 mg/m3 Exposure time: 28-day () NOEL: 30 mg/kg Lowest observable effect level: 100 mg/kg Carcinogenicity : Species: rat Toxicology Assessment CMR effects : Carcinogenicity: Not classified due to lack of data. Mutagenicity: Not classified due to lack of data. Reproductive toxicity: Not classified due to lack of data. 12. ECOLOGICAL INFORMATION Ecotoxicity effects Toxicity to fish : LC50: 2.3 mg/l Exposure time: 96 h Species: Oncorhynchus mykiss (rainbow trout) flow-through test : LC50: 1.3 mg/l Exposure time: 96 h Species: Lepomis macrochirus (Bluegill sunfish) flow-through test SAP / 13 SDS Number:

9 Toxicity to daphnia and other aquatic invertebrates : EC50: > 57 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea) flow-through test : EC50: 1.7 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea) Toxicity to algae : EC50: 0.48 mg/l Exposure time: 5 d Species: Pseudokirchneriella subcapitata (green algae) static test : EC50: 0.62 mg/l Exposure time: 72 h Species: Pseudokirchneriella subcapitata (green algae) Toxicity to fish (Chronic toxicity) : NOEC: 0.32 mg/l Exposure time: 21 d Species: Cyprinus carpio (Carp) : NOEC: mg/l Exposure time: 28 d Species: Pimephales promelas (fathead minnow) Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC: 0.32 mg/l Exposure time: 17 d Species: Daphnia magna (Water flea) : NOEC: mg/l Exposure time: 21 d Species: Daphnia magna (Water flea) Elimination information (persistence and degradability) Bioaccumulation : Remarks: not applicable Mobility : Remarks: no data available Biodegradability : Remarks: Not readily biodegradable. Further information on ecology Ecotoxicology Assessment Results of PBT assessment This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). SAP / 13 SDS Number:

10 Additional ecological information : An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Very toxic to aquatic life with long lasting effects. SECTION 13. DISPOSAL CONSIDERATIONS Further information : In accordance with local and national regulations. Do not contaminate ponds, waterways or ditches with chemical or used container. SECTION 14. TRANSPORT INFORMATION DOT UN number : 3082 Description of the goods : Environmentally hazardous substances, liquid, n.o.s. : (, ) Class : 9 Packing group : III ERG Code : 171 IATA UN number : 3082 Description of the goods : Environmentally hazardous substance, liquid, n.o.s. (, ) Class : 9 Packing group : III Labels : 9 Environmentally hazardous : yes IMDG UN number : 3082 Description of the goods : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (, ) Class : 9 Packing group : III EmS Number 1 : F-A EmS Number 2 : S-F Marine pollutant Environmentally hazardous : yes : yes SECTION 15. REGULATORY INFORMATION OSHA Hazards : Harmful by ingestion., Mild skin irritant SAP / 13 SDS Number:

11 WHMIS Classification : CERCLA Reportable Quantity SARA 302 Reportable Quantity SARA 311/312 Hazards : : : Acute Health Hazard EPCRA - EMERGENCY PLANNING COMMUNITY RIGHT - TO - KNOW SARA 302 Reportable : Quantity SARA 304 Components : This material does not contain any components with a section 304 EHS RQ. SARA 313 Components : California Prop. 65 Components : WARNING! This product contains a chemical known to the State of California to cause cancer. quartz (SiO2) quartz (SiO2) The components of this product are reported in the following inventories: US.TSCA Not On TSCA Inventory DSL This product contains the following components that are not on the Canadian DSL nor NDSL lists. AICS Not in compliance with the inventory NZIoC Not in compliance with the inventory ENCS Not in compliance with the inventory KECI Not in compliance with the inventory SAP / 13 SDS Number:

12 PICCS Not in compliance with the inventory IECSC Not in compliance with the inventory SECTION 16. OTHER INFORMATION Further information HMIS Classification : Health hazard: 1 Flammability: 1 Physical hazards: 0 PPI:Ask supervisor or safety specialist for handling instructions NFPA Classification : Health hazard: 1 Fire Hazard: 1 Reactivity Hazard: Other Emergency Phone Number Latin America: Brazil All other countries +44 (0) Mexico: SAP / 13 SDS Number:

13 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. SAP / 13 SDS Number: