Safety Data Sheet according to (EC) No 1907/2006

Transcription

1 Safety Data Sheet according to (EC) No 1907/2006 Loctite Hysol ml Page 1 of 13 sds no. : Revision: printing date: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Loctite Hysol ml 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Epoxy adhesive 1.3. Details of the supplier of the safety data sheet Henkel Ltd Wood Lane End HP2 4RQ Hemel Hempstead Great Britain Phone: Fax-no.: ua-productsafety.uk@uk.henkel.com 1.4. Emergency telephone number 24 Hours Emergency Tel: +44 (0) Classification of the substance or mixture SECTION 2: Hazards identification Classification (DPD): Sensitizing R43 May cause sensitisation by skin contact. Xi - Irritant R36/38 Irritating to eyes and skin. N - Dangerous for the environment R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment Label elements

2 Loctite Hysol ml Page 2 of 13 Label elements (DPD): Xi - Irritant N - Dangerous for the environment Risk phrases: R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases: S24 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of water and soap. S37 Wear suitable gloves. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Additional labeling: Contains epoxy constituents. See information supplied by the manufacturer. Contains: RP Bisphenol F-epichlorohydrin resin, MW<=700, Bisphenol-A epichlorhydrin resin MW <= Other hazards None if used properly. General chemical description: Epoxy resin SECTION 3: Composition/information on ingredients

3 Loctite Hysol ml Page 3 of 13 Declaration of the ingredients according to CLP (EC) No 1272/2008: Aluminium powder (stabilised) RP Bisphenol F-epichlorohydrin resin, MW<= Bisphenol-A epichlorhydrin resin MW <= 700 Fenuron EC Number REACH-Reg No. content Classification >= 25- < 50 % Substances and mixtures, which on contact with water, emit flammable gases 2 H261 Flammable solids 1 H228 >= 25- < 50 % Serious eye irritation 2 H319 Skin irritation 2 H315 Skin sensitizer 1 H317 Chronic hazards to the aquatic environment 2 H >= 10- < 20 % Skin sensitizer H Chronic hazards to the aquatic environment 2 H411 Serious eye irritation 2 H319 Skin irritation 2 H >= 2,5- < 5 % Toxic to reproduction 2 H361d Chronic hazards to the aquatic environment 2 H >= 0,1- < 0,25 % Acute hazards to the aquatic environment 1 H400 Chronic hazards to the aquatic environment 1 H410 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available. Declaration of ingredients according to DPD (EC) No 1999/45: Aluminium powder (stabilised) RP Bisphenol F-epichlorohydrin resin, MW<= Bisphenol-A epichlorhydrin resin MW <= 700 Fenuron EC Number content Classification REACH-Reg No >= 25 - < 50 % F - Highly flammable; R11, R >= 25 - < 50 % Xi - Irritant; R36/38, R43 N - Dangerous for the environment; R51/53 >= 10 - < 20 % R43 Xi - Irritant; R36/38 N - Dangerous for the environment; R51/ >= 2,5 - < 5 % N - Dangerous for the environment; R51/53 Toxic for reproduction - category 3.; Xn - Harmful; R63 Xi - Irritant; R36/ >= 0,1 - < 0,25 % N - Dangerous for the environment; R50/ For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available Description of first aid measures SECTION 4: First aid measures Inhalation: Move to fresh air. If symptoms persist, seek medical advice.

4 Loctite Hysol ml Page 4 of 13 Skin contact: Rinse with running water and soap. Seek medical advice. Eye contact: Rinse immediately with plenty of running water (for 10 minutes). Seek medical attention if necessary. Ingestion: Rinse out mouth, drink 1-2 glasses of water, do not induce vomiting. Seek medical advice Most important symptoms and effects, both acute and delayed SKIN: Rash, Urticaria. EYE: Irritation, conjunctivitis. SKIN: Redness, inflammation Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures 5.1. Extinguishing media Suitable extinguishing media: Carbon dioxide, foam, powder SECTION 5: Firefighting measures Extinguishing media which must not be used for safety reasons: None known 5.2. Special hazards arising from the substance or mixture In the event of a fire, carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx) can be released Advice for firefighters Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid skin and eye contact Environmental precautions Do not let product enter drains Methods and material for containment and cleaning up For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal. Wash spillage site thoroughly with soap and water or detergent solution. Dispose of contaminated material as waste according to Chapter Reference to other sections See advice in chapter 8 SECTION 7: Handling and storage 7.1. Precautions for safe handling Use only in well-ventilated areas. Avoid skin and eye contact. Prolonged or repeated skin contact should be avoided to minimise any risk of sensitisation.

5 Loctite Hysol ml Page 5 of 13 Hygiene measures: Good industrial hygiene practices should be observed. Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working Conditions for safe storage, including any incompatibilities For optimum shelf life store in original containers under refrigerated conditions at 2-8 C ( F) 7.3. Specific end use(s) Epoxy adhesive SECTION 8: controls/personal protection 8.1. Control parameters Occupational Limits Valid for Great Britain Ingredient ppm mg/m 3 Type Category Remarks ALUMINIUM METAL, RESPIRABLE DUST Time Weighted Average (TWA): EH40 WEL ALUMINIUM METAL, INHALABLE DUST Time Weighted Average (TWA): EH40 WEL

6 Loctite Hysol ml Page 6 of 13 Predicted No-Effect Concentration (PNEC): Name on list Environmental Compartment aqua (freshwater) aqua (marine water) STP sediment (freshwater) sediment (marine water) aqua (intermittent releases) soil STP sediment (freshwater) oral aqua (marine water) aqua (intermittent releases) aqua (freshwater) period Value mg/l ppm mg/kg others 3 µg/l 0,3 µg/l 10 mg/l 0,5 mg/kg 0,5 mg/kg 0,013 mg/l 1,04 mg/kg 100 mg/l 1,29 mg/kg 16,7 mg/kg 0,4 µg/l 4 µg/l 4 µg/l Remarks

7 Loctite Hysol ml Page 7 of 13 Derived No-Effect Level (DNEL): Name on list Application Area Route of Health Effect worker dermal Acute/short term worker inhalation Acute/short term worker dermal Long term worker inhalation Long term dermal inhalation oral dermal inhalation oral inhalation Acute/short term Acute/short term Acute/short term Long term Long term Long term Long term worker dermal Long term dermal Long term worker inhalation Long term Time Value 8,3 mg/kg bw/day 12,3 mg/m3 8,3 mg/kg bw/day 12,3 mg/m3 3,6 mg/kg bw/day 0,75 mg/m3 0,75 mg/kg bw/day 3,6 mg/kg bw/day 0,75 mg/m3 0,75 mg/kg bw/day 1,74 mg/m3 8,3 mg/kg bw/day 5 mg/kg bw/day 5,8 mg/m3 Remarks Biological Indices: None 8.2. controls: Respiratory protection: Use only in well-ventilated areas.

8 Loctite Hysol ml Page 8 of 13 Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Wear protective glasses. Skin protection: Wear suitable protective clothing. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance paste grey Odor characteristic Odour threshold ph Initial boiling point Flash point Decomposition temperature Vapour pressure Density () Bulk density Viscosity Viscosity (kinematic) Explosive properties Solubility (qualitative) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties > 93,0 C (> F) 1,4300-1,4700 g/cm Other information SECTION 10: Stability and reactivity Reactivity Reaction with strong acids. Reacts with strong oxidants. Reaction with some curing agents may produce an exothermic reaction which in large masses could cause runaway polymerization Chemical stability Stable under recommended storage conditions.

9 Loctite Hysol ml Page 9 of Possibility of hazardous reactions See section reactivity Conditions to avoid Stable under normal conditions of storage and use. Protect from direct sunlight Incompatible materials None if used properly Hazardous decomposition products carbon oxides Information on toxicological effects SECTION 11: Toxicological information General toxicological information: The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Skin irritation: Irritating to the skin. Eye irritation: Irritating to eyes. Sensitizing: May cause sensitization by skin contact. Skin corrosion/irritation: Bisphenol-A epichlorhydrin resin MW <= 700 Result time Species Method slightly irritating 4 h rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) Serious eye damage/irritation: Bisphenol-A epichlorhydrin resin MW <= 700 Result time Species Method not irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) Respiratory or skin sensitization: Bisphenol-A epichlorhydrin resin MW <= 700 sensitising Result Test type Species Method Mouse local lymphnod e assay (LLNA) mouse OECD Guideline 429 (Skin Sensitisation: Local Lymph Node Assay) Germ cell mutagenicity: Bisphenol-A epichlorhydrin resin MW <= 700 Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g Ames test) Metabolic activation / time with and without Species Method OECD Guideline 472 (Genetic Toxicology: Escherichia coli, Reverse Mutation Assay)

10 Loctite Hysol ml Page 10 of 13 SECTION 12: Ecological information General ecological information: The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following Toxicity Ecotoxicity: Toxic to aquatic organisms May cause long-term adverse effects in the aquatic environment. Do not empty into drains / surface water / ground water. Aluminium powder (stabilised) Bisphenol-A epichlorhydrin resin MW <= 700 Fenuron Fenuron Value type Value Acute Toxicity Study time Species Method NOEC > 100 mg/l Fish 96 h Salmo trutta OECD Guideline 203 (Fish, Acute Toxicity Test) LC50 1, mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Acute Toxicity Test) LC mg/l Fish 48 h Poecilia reticulata OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 1,55 mg/l Algae Ankistrodesmus falcatus OECD Guideline 201 (Alga, Growth Inhibition Test) LC0 >= 0,57 mg/l Fish 96 h Brachydanio rerio (new name: Danio rerio) EU Method C.1 (Acute Toxicity for Fish) EC50 0,48 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) Persistence and degradability Persistence and Biodegradability: The product is not biodegradable. Result Route of application Degradability Method aerobic 4,5 % OECD Guideline 301 C (Ready Biodegradability: Modified MITI Test (I)) Bioaccumulative potential / Mobility in soil Mobility: Cured adhesives are immobile. Bioaccumulative potential: No data available. Fenuron LogKow Bioconcentration factor (BCF) 0,98 5,1 time Species Temperature Method Results of PBT and vpvb assessment PBT/vPvB

11 Loctite Hysol ml Page 11 of 13 Bisphenol-A epichlorhydrin resin MW <= 700 Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria. Not fulfilling PBT (persistent/bioaccummulative/toxic) criteria Other adverse effects No data available. SECTION 13: Disposal considerations Waste treatment methods Product disposal: Dispose of in accordance with local and national regulations. Disposal of uncleaned packages: After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated. Disposal must be made according to official regulations. Waste code waste adhesives and sealants containing organic solvents and other dangerous substances

12 Loctite Hysol ml Page 12 of 13 SECTION 14: Transport information UN number ADR 3082 RID 3082 ADNR 3082 IMDG 3082 IATA UN proper shipping name ADR RID ADNR IMDG IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy resin) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy resin) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy resin) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy resin) Environmentally hazardous substance, liquid, n.o.s. (Epoxy resin) Transport hazard class(es) ADR 9 9 RID 9 9 ADNR 9 9 IMDG 9 9 IATA Packaging group ADR RID ADNR IMDG IATA III III III III III Environmental hazards ADR RID ADNR IMDG IATA Marine pollutant Special precautions for user ADR RID ADNR IMDG IATA Tunnelcode: (E) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

13 Loctite Hysol ml Page 13 of 13 SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content < 3,00 % (1999/13/EC) Chemical safety assessment A chemical safety assessment has not been carried out. SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: R11 Highly flammable. R15 Contact with water liberates extremely flammable gases. R36/37 Irritating to eyes and respiratory system. R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R63 Possible risk of harm to the unborn child. H228 Flammable solid. H261 In contact with water releases flammable gases. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H361d Suspected of damaging the unborn child. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. This safety data sheet was prepared in accordance with Council Directive 67/548/EEC and it's subsequent amendments, and Commission Directive 1999/45/EC.