SAFETY DATA SHEET D-Fense NXT

Transcription

1 SAFETY DATA SHEET D-Fense NXT Page 1 of 7 SECTION 1: IDENTIFICATION Product Name: D-Fense NXT EPA Registration No.: Recommended Use: Insecticide; See product label for a complete list of uses and use sites. Restrictions on Use: See product label for any restrictions on the use of this product. Chemical Family: N/A Multiple Active Ingredients Chemical Name of Active Ingredient(s): Deltamethrin Novaluron Manufactured for: Pyriproxyfen Control Solutions, Inc Genoa-Red Bluff Pasadena, TX FOR FIRE, SPILL, AND/OR LEAK EMERGENCIES CONTACT: CHEMTREC FOR MEDICAL EMERGENCIES AND HEALTH AND SAFETY INQUIRIES CONTACT: Safety Call SECTION 2: HAZARD(S) IDENTIFICATION EMERGENCY OVERVIEW: Aerosol with a strong alcohol odor. Inhalation of vapors may cause drowsiness or dizziness. Extremely flammable aerosol. OSHA HCS CLASSIFICATION (29 CFR ) Aspiration Hazard Category 1 Flammable Aerosols Category 1 Specific Target Organ Toxicity Single Exposure Category 3 Signal Word: Hazard Statement(s): Precautionary Statement(s): Prevention: Response: Storage: Disposal: DANGER May be fatal if swallowed and enters airways. Extremely flammable aerosol. May cause drowsiness or dizziness. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing mist/vapors/spray. Use only outdoors or in a well-ventilated area. IF SWALLOWED: Immediately call a poison center/doctor. Do NOT induce vomiting. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50 C/122 F. Dispose of contents/container in accordance with Federal, state and local laws and regulations.

2 Page 2 of 7 SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS Number Weight % Distillates, petroleum, hydrotreated light % Acetone % Novaluron % Deltamethrin % Pyriproxyfen % Carbon dioxide % *Ingredients not listed or listed with a weight % range are considered a trade secret and are withheld under 29 CFR (i). SECTION 4: FIRST AID MEASURES IF IN EYES: Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes; then continue rinsing eye. Call a poison control center or doctor for treatment advice. IF ON SKIN: Take off contaminated clothing. Rinse skin immediately with plenty of water for 1 5 to 20 minutes. Call a poison control center or doctor for treatment advice. IF INHALED: Move person to fresh air. If person is not breathing, call 911 or an ambulance; then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. IF INGESTED: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Most important symptoms/effects, acute and delayed: Moderate but temporary skin irritation. Drowsiness or dizziness if inhaled. Vomiting may cause aspiration pneumonia. Long-term exposure to skin without washing may cause moderate skin effects such as redness, dryness, sloughing and shallow to deep fissuring. Note to Physician: Aspiration of this product during induced emesis can result in lung injury. If evacuation of stomach contents is considered necessary, use method least likely to cause aspiration, such as gastric lavage after endotracheal intubation. SECTION 5: FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Unsuitable Extinguishing Media: Hazardous Combustion Products: Special Protective Equipment & Precautions: Unusual Fire & Explosion Hazards: Foam, dry chemical, carbon dioxide or water fog/spray Water jet Thermal decomposition may produce toxic carbon and nitrogen oxides, and halogenated hydrocarbons. Evacuate area and fight fire upwind from a safe distance to avoid hazardous vapors and decomposition products. Foam and/or dry chemical are preferred to minimize environmental contamination. If water is used, dike and collect water to prevent run-off. Wear selfcontained breathing apparatus and full fire-fighting turn-out gear (Bunker gear). Compressed gas. Containers may burst under fire conditions.

3 Page 3 of 7 SECTION 6: ACCIDENTAL RELEASE MEASURES Personal Precautions: Environmental Precautions: Methods for Containment: Methods for Clean-up: Other Information: SECTION 7: HANDLING AND STORAGE See Section 8 for personal protection equipment. Keep spilled material and any rinsate from contaminating soil or from entering sewage and drainage systems and bodies of water. Isolate the spill area. Keep unnecessary and unprotected personnel from entering. Absorb small spills with sand, vermiculite or other inert absorbent. Dike large spills using absorbent or impervious material such as clay or sand. Recover and contain as much free liquid as possible for reuse. Allow absorbed material to solidify and scrape up for disposal. Place contaminated material in appropriate container for disposal. After removal, flush contaminated area thoroughly with water. Pick up wash liquid with additional absorbent and place in a disposable container. Do not put spilled material back in the original container. This product contains an ingredient regulated by CERCLA ( Superfund ). See Section 15 for additional information. Handling: RECOMMENDATIONS ARE INTENDED FOR MANUFACTURING, PACKAGING AND COMMERCIAL BLENDING WORKERS. PESTICIDE APPLICATORS AND WORKERS must refer to the product label and Directions for Use attached to the product for Agricultural Use Requirements in accordance with the EPA Worker Protection Standard 40 CFR part 170. Handle and open container in a manner as to prevent spillage. Do not eat, drink or smoke while handling this product. Immediately wash off accidental splashes of the concentrate or spray mixture from skin, clothing and out of eyes. Avoid all sources of ignition. Storage: See pesticide label for full information on product storage. Do not contaminate water, food or feed by storage of this product. Store away from sources of heat, out of direct sunlight and away from incompatible materials. Pesticides should be stored in secured areas away from children and animals. Containers may explode at or above listed maximum storage temperature. Storage Temperature (Min/Max): Do not store at temperatures exceeding 122 F (50 C). Product Incompatibilities: Avoid contact with strong oxidizers. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Users of a pesticide product must refer to the product label for personal protective equipment requirements. Exposure Guidelines: COMPONENT OSHA PEL ACGIH TLV NIOSH REL TWA: 500 ppm or Acetone TWA: 1000 ppm or 1210 mg/m mg/m 3 STEL: 750 ppm or 1815 mg/m 3 Petroleum distillates 500 ppm (TWA) 350 mg/m 3 (TWA) 1,800 mg/m 3 (CEIL)(15 min)

4 Page 4 of 7 Carbon dioxide TWA: 5000 ppm or 9000 mg/m 3 TWA: 5000 ppm STEL: ppm IDLH: ppm TWA: 5000 ppm or 9000 mg/m 3 STEL: ppm or mg/m 3 Engineering Controls: Provide general or local exhaust ventilation systems to maintain airborne concentrations below OSHA PELs or other specified exposure limits. Local exhaust ventilation is preferred. Respiratory Protection: Eye Protection: Protective Gloves: Other Protective Clothing: General Safety Measures: In areas of poor ventilation, use a NIOSH approved respirator with cartridges/canisters approved for organic vapors. Chemical goggles or safety glasses and full-face shield. Chemical-resistant gloves such as barrier laminate, butyl rubber, nitrile, neoprene rubber, polyvinyl chloride (PVC) or Viton. Long-sleeved shirt, long pants and shoes plus socks. Wash hands before eating, drinking, chewing gum, using tobacco, or using the toilet. Remove clothing immediately after handling this product. Wash outside of gloves before removing. Discard clothing and other absorbent materials that have been drenched or heavily contaminated with this product s concentrate. Do not reuse them. Follow manufacturer s instructions for cleaning and maintaining PPE. If no such instructions for washables, use detergent and hot water. Keep and wash PPE separately from other laundry. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Appearance: Aerosol Upper/Lower Flammability Limits: Not determined Odor: Strong alcohol Vapor Pressure: Not determined Odor Threshold: Not determined Vapor Density: Not determined ph (1% dispersion): Relative Density (@24 C): (typical) Melting /Freezing Point: Not determined Solubility in Water: Not determined Boiling Point/Range: Not determined Partition Coefficient: Not determined Flash Point: <75 F (concentrate) Auto-ignition Temperature: Not determined Evaporation Rate: Not determined Decomposition Temperature: Not determined Flammability: Not applicable Viscosity: 1.34 cp at 25 C 1.10 cp at 39 C SECTION 10: STABILITY AND REACTIVITY Reactivity: Chemical Stability: Possibility of Hazardous Reactions: Conditions to Avoid: Incompatible Materials: No hazardous chemical reactions known if stored and handled as indicated. Stable under normal storage and handling conditions. No potential for hazardous reactions known if stored and handled as indicated. Exposure to temperatures above 122 F (50 C). Avoid all sources of ignition: heat, sparks, open flames. Avoid prolonged storage. Strong oxidizers

5 Page 5 of 7 Hazardous Decomposition Products: Thermal decomposition may produce toxic carbon and nitrogen oxides, and halogenated hydrocarbons. SECTION 11: TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Symptoms of Exposure: Oral LD 50: Dermal LD 50: Inhalation LC 50: Eye Irritation/Damage: Skin Corrosion/Irritation: Skin Sensitization: Chronic/Subchronic Toxicity: Mutagenicity: Reproductive Toxicity: Neurotoxicity: Target Organs: Aspiration Hazard: Eye contact, Skin contact, Inhalation, Ingestion Moderate but temporary skin irritation. Drowsiness and/or dizziness. >5,000 mg/kg (rat) >5,050 mg/kg (rat) >2.17 mg/l (rats)(no mortality at this concentration) Non-irritant (rabbit) Mild irritation with all effects clearing in 72 hours (rabbit) Non-sensitizer (guinea pig) Contains petroleum distillates so concentrate prior to adding propellant may be an aspiration hazard. Carcinogenicity: Chemical Name ACGIH IARC NTP OSHA Deltamethrin Group 3 SECTION 12: ECOLOGICAL INFORMATION Environmental Hazards Statement from FIFRA Regulated Pesticide Label: This product is toxic to fish and aquatic organisms. Do not apply directly to any body of water. To protect the environment, do not allow pesticide to enter or run off into storm drains, drainage ditches, gutters or surface waters. Applying this product in calm weather when rain is not predicted for the next 24 hours will help to ensure that wind or rain does not blow or wash pesticide off the treatment area. ECOTOXICITY DATA: Fish Toxicity: Aquatic Invertebrate Toxicity: Aquatic Plant Toxicity: Avian Toxicity: Honeybee Toxicity: ENVIRONMENTAL EFFECTS: Persistence and Degradability: Bioaccumulation: Mobility: Other Adverse Effects:

6 Page 6 of 7 SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal: Container Disposal: RCRA Characteristics: Refer to the pesticide label for full information on disposal. Pesticide wastes are toxic. Improper disposal of unused pesticide, spray mixture, or rinse water is a violation of Federal law. If these wastes cannot be used according to label instructions, contact your State Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest EPA Regional Office for guidance in proper disposal methods. Refer to the pesticide label for full information on disposal. When possible, triple rinse the container and offer for recycling if available. It is the responsibility of the individual disposing of this product to determine the RCRA classification and hazard status of the waste. Empty aerosol cans may meet the definition of RCRA D003. Consult local and/or regional EPA for further guidance. SECTION 14: TRANSPORTATION INFORMATION DOT (Ground): IMDG (Sea): IATA (Air): UN1950, Aerosols, flammable, 2.1 This product may be classified as Limited Quantity. UN1950, Aerosols, flammable, 2.1, Marine Pollutant UN1950, Aerosols, flammable, 2.1 SECTION 15: REGULATORY INFORMATION Labeling Requirements Under FIFRA: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION Avoid contact with skin or clothing. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, or using the toilet. TSCA Inventory: This product is exempt from TSCA inventory listing requirements as it is solely for FIFRA regulated use. SARA Title III Information: Section 302 Extremely hazardous substances: None Section 311/312 Hazard Categories: Acute (Immediate); Fire; Sudden release of pressure Section 313 This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical Name CAS Number Weight % None listed

7 Page 7 of 7 CERCLA This product contains the following chemicals which have a reportable quantity (RQ) under the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA): Chemical Name CAS Number RQ Quantity of Finished Product Acetone lbs 3,693 gallons of concentrate CALIFORNIA PROPOSITION 65: Chemical Name CAS Number Prop 65 Category(ies) None listed U.S. STATE RIGHT-TO-KNOW REGULATIONS: Chemical Name New Jersey Massachusetts Pennsylvania Acetone X X X Carbon dioxide X X X Distillates, petroleum, hydrotreated light X X X SECTION 16: OTHER INFORMATION NFPA Health Hazards 2 Flammability 3 Instability 0 Special Hazards None Disclaimer: Control Solutions, Inc. believes the information presented herein is accurate and correct as of the document date. The presented information is based upon available data from reliable sources. Control Solutions, Inc. makes no warranty, express or implied, regarding the accuracy of the data or the results obtained from the use of this product. Nothing herein may be construed as recommending any practice or any product in violation of any law or regulations. The user is solely responsible for determining the suitability of any material or product for a specific purpose and for adopting any appropriate safety precautions. We disclaim all liability for injury or damage stemming from any improper use of the material or product described herein. Document Superseded: N/A New document Revision Note: