LOCTITE ECI 1004 E&C BULK MSDS-No. : V001.1 Revision: printing date: LOCTITE ECI 1004 E&C BULK

Transcription

1 Safety Data Sheet Page 1 of 7 LOCTITE ECI 1004 E&C BULK MSDS-No. : Revision: printing date: Section 1. Identification of the substance/preparation and of the company/undertaking Product name: LOCTITE ECI 1004 E&C BULK Identification of manufacturer, importer or distributor Importer: Henkel Vietnam Co., Ltd. Room th Floor, Giay Viet Plaza, Ly Chinh Thang Street, Ward 9- District 3-HCM City, Vietnam. Phone : Fax : address of person responsible for Safety Data Sheet: ap-ua-psra.sea@henkel.com Section 2. Composition / information on ingredients Declaration of ingredients: cobalt bis(2-ethylhexanoate) EINECS content Classification % % Xi - Irritant; R < 0,1 % Xi - Irritant; R43 N - Dangerous for the environment; R50/53 Section 3. Hazards identification Hazard classification: Risk phrases: N - Dangerous for the environment R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Section 4. First aid measures Inhalation: Skin contact: Eye contact: Ingestion: Should not be a problem as product is of low volatility. However, if feeling unwell remove patient to fresh air. Rinse with running water and soap. Obtain medical attention if irritation persists. Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor.

2 LOCTITE ECI 1004 E&C BULK Page 2 of 7 Section 5. Fire fighting measures Suitable extinguishing media: Special protection equipment for firefighters: Particular danger/case of fire: water, carbon dioxide, foam, powder Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. In the event of a fire, carbon monoxide (CO) and carbon dioxide (CO2) can be released. In case of fire, keep containers cool with water spray. Section 6. Accidental release measures Personal precautions: Environmental precautions: Clean-up methods: Avoid contact with skin and e. Wear protective equipment. Do not empty into drains / surface water / ground water. For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal. Section 7. Handling and storage Handling: Storage: Avoid skin and eye contact. See advice in chapter 8 Ensure good ventilation/extraction. Keep container tightly sealed. Section 8. controls / personal protection Ingredient Type ppm mg/m 3 Remarks SILVER, METAL, DUST AND FUME Time Weighted Average 0,1 ACGIH SILVER Time weighted average 0,01 VN OEL SILVER Short-term exposure 0,1 VN OEL limit (STEL): COBALT AND INORGANIC Time Weighted Average 0,02 ACGIH COMPOUNDS, AS CO COBALT AND COMPOUNDS Time weighted average 0,05 VN OEL COBALT AND COMPOUNDS Short-term exposure limit (STEL): 0,1 VN OEL

3 Respiratory protection: LOCTITE ECI 1004 E&C BULK Page 3 of 7 Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Body protection: Engineering controls: Hygienic measures: Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk of splashing. Wear suitable protective clothing. Ensure good ventilation/extraction. Good industrial hygiene practices should be observed. Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. Section 9. Physical and chemical properties Appearance: Odor: Melting point: Boiling point: Flash point: Density: Solubility: Viscosity (dynamic) (; Method: no method) silver liquid, paste Mild -20 C (-4 F) C ( F) 100 C (212 F) 2,45 g/cm3 Solvent:, Slightly soluble mpa.s Section 10. Stability and reactivity Conditions to avoid: Materials to avoid: Stable under recommended storage conditions. No decomposition if stored and applied as directed. Strong oxidizing agents. Peroxides. Hazardous decomposition products: Hydrocarbons carbon oxides.

4 LOCTITE ECI 1004 E&C BULK Page 4 of 7 Section 11. Toxicological information Oral toxicity: Inhalative toxicity: Dermal toxicity: Skin irritation: Eye irritation: May cause irritation to the digestive tract. May cause irritation to respiratory system. Prolonged or repeated skin contact with silver and its salts may cause a blue-gray discoloration of the skin and mucous membranes that is irreversible (Argyria). May produce an allergic reaction. May cause mild irritation to the e. Acute toxicity: Value type Value Route of application Species Method LD50 > mg/kg oral rat OECD Guideline 401 (Acute Oral Toxicity) oralinhalationder mal oralinhalationder mal Skin corrosion/irritation: Result Species Method slightly irritating rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) not irritating rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) not irritating rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) Serious eye damage/irritation: Result Species Method slightly irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) Respiratory or skin sensitization: Result Test type Species Method sensitising guinea pig OECD Guideline 406 (Skin Sensitisation) Section 12. Ecological information Mobility: Cured adhesives are immobile. Ecotoxicity: Do not empty into drains / surface water / ground water. : Very toxic to aquatic organisms.

5 LOCTITE ECI 1004 E&C BULK Page 5 of 7 Toxicity: Value type Value Acute Toxicity Study Species LC mg/l Fish 96 h Brachydanio rerio (new name: Danio rerio) Method OECD Guideline 203 (Fish, Acute Toxicity Test) LC mg/l Fish OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 33,5 mg/l Daphnia Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 3,8 mg/l Algae OECD Guideline 201 (Alga, Growth Inhibition Test) Persistence and degradability: Result Route of application Degradability Method aerobic 60 % OECD Guideline 301 B (Ready Biodegradability: CO2 Evolution Test) Bioaccumulative potential / Mobility in soil: LogKow Bioconcentration factor (BCF) 0,35 4,68 Species Temperature Method Section 13. Disposal considerations Product Method of disposal: Packaging Disposal for uncleaned package: Do not empty into drains / surface water / ground water. Dispose of in accordance with local and national regulations. After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated. Section 14. Transport information Road transport ADR: Classification code: M6 Hazard ident. number: 90 Technical name:

6 LOCTITE ECI 1004 E&C BULK Page 6 of 7 Railroad transport RID: Classification code: M6 Hazard ident. number: 90 Technical name: Inland water transport ADN: Classification code: M6 Hazard ident. number: Technical name: Marine transport IMDG: EmS: F-A,S-F Seawater pollutant: Marine pollutant Proper shipping name: Air transport IATA: Packaging instructions (passenger) 964 Packaging instructions (cargo) 964 Proper shipping name: Environmentally hazardous substance, liquid, n.o.s. () Section 15. Regulations - classification and identification Indication of danger: Risk phrases: Safety phrases: N - Dangerous for the environment R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Global inventory status: Regulatory list EINECS TSCA ENCS (JP) KECI (KR) NZIOC Notification

7 LOCTITE ECI 1004 E&C BULK Page 7 of 7 Section 16. Other information Issue date: Disclaimer This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. This safety data sheet was prepared in accordance with Council Directive 67/548/EEC and it's subsequent amendments, and Commission Directive 1999/45/EC.