Material Safety Data Sheet acc. to ISO 11014

Transcription

1 Page 1/7 1 Identification Product identifier Product number: RPNQ0095 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance / the mixture Laboratory chemicals Details of the supplier of the safety data sheet Manufacturer/Supplier: PerkinElmer Inc 549 Albany st Boston, MA Information department: US Technical Support Emergency telephone number: If inside, call CHEMTREC at If outside, call CHEMTREC at Hazard(s) identification Classification of the substance or mixture Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. Additional information: For full text of H-statements and R-phrases: see SECTION 16 Label elements GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS09 Signal word Void Hazard statements Toxic to aquatic life with long lasting effects. Precautionary statements Avoid release to the environment. Collect spillage. Dispose of contents/container in accordance with local/regional/national/international regulations. Classification system: NFPA ratings (scale 0-4) Health = 0 Fire = 0 Reactivity = 0 3 Composition/information on ingredients Chemical characterization: Mixtures Description: Mixture of the substances listed below with nonhazardous additions. (Contd. on page 2)

2 Page 2/7 (Contd. of page 1) Dangerous components: copper sulphate % Additional Components Polyvinyltoluene % 4 First-aid measures Description of first aid measures After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Immediately rinse with water. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: If symptoms persist consult doctor. Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed Follow the advice given in section Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Special hazards arising from the substance or mixture No further relevant information available. Advice for firefighters Protective equipment: Wear self-contained respiratory protective device. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Not required. Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage Precautions for safe handling Store in cool, dry place in tightly closed receptacles. Information about protection against explosions and fires: No special measures required. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and containers: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: None. (Contd. on page 3)

3 Page 3/7 Specific end use(s) No further relevant information available. (Contd. of page 2) 8 Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Exposure controls Personal protective equipment: General protective and hygienic measures: Wash hands before breaks and at the end of work. Respiratory protection: Suitable respiratory protective device recommended. Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Goggles recommended during refilling. 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Fluid Color: According to product specification Odor: Characteristic Odour threshold: ph-value: N/A Change in condition Melting point/melting range: Boiling point/boiling range: Undetermined. Undetermined. Flash point: Not applicable. Flammability (solid, gaseous): Not applicable. Ignition temperature: Decomposition temperature: Auto igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: (Contd. on page 4)

4 Page 4/7 Upper: Vapor pressure: Density: Relative density Vapour density Evaporation rate Solubility in / Miscibility with Water: Not miscible or difficult to mix. Partition coefficient (n-octanol/water): Viscosity: Dynamic: Kinematic: Solvent content: Organic solvents: 0.0 % Solids content: 8.0 % Other information No further relevant information available. (Contd. of page 3) 10 Stability and reactivity Reactivity Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available. Incompatible materials: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known. 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: copper sulphate Oral LD mg/kg (rat) Primary irritant effect: on the skin: No irritant effect. on the eye: No irritating effect. Sensitization: No sensitizing effects known. Additional toxicological information: Carcinogenic categories IARC (International Agency for Research on Cancer) NTP (National Toxicology Program) (Contd. on page 5)

5 Page 5/7 OSHA-Ca (Occupational Safety & Health Administration) (Contd. of page 4) 12 Ecological information Toxicity Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Ecotoxical effects: N/A Remark: Toxic for fish Other information: N/A Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. Other adverse effects No further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation: Must be specially treated adhering to official regulations. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. 14 Transport information UN-Number DOT, ADR, IMDG, IATA UN3082 UN proper shipping name DOT Environmentally hazardous substances, liquid, n.o.s. (copper sulphate) ADR 3082 Environmentally hazardous substances, liquid, n.o.s. (copper sulphate) IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (copper sulphate), MARINE POLLUTANT IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (copper sulphate) Transport hazard class(es) DOT, ADR, IMDG, IATA Class 9 Miscellaneous dangerous substances and articles Label 9 (Contd. on page 6)

6 Page 6/7 Packing group DOT, ADR, IMDG, IATA III (Contd. of page 5) Environmental hazards: Product contains environmentally hazardous substances: copper sulphate Marine pollutant: Yes Symbol (fish and tree) Special marking (ADR): Symbol (fish and tree) Special marking (IATA): Symbol (fish and tree) Special precautions for user Warning: Miscellaneous dangerous substances and articles Danger code (Kemler): 90 EMS Number: F-A,S-F Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. Transport/Additional information: DOT Quantity limitations On passenger aircraft/rail: No limit On cargo aircraft only: No limit Remarks: Special marking with the symbol (fish and tree). ADR Excepted quantities (EQ) Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml IMDG Limited quantities (LQ) 5L Excepted quantities (EQ) Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml UN "Model Regulation": UN3082, Environmentally hazardous substances, liquid, n.o.s. (copper sulphate), 9, III 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): Section 313 (Specific toxic chemical listings): copper sulphate TSCA (Toxic Substances Control Act): All ingredients are listed. Proposition 65 Chemicals known to cause cancer: Chemicals known to cause reproductive toxicity for females: (Contd. on page 7)

7 Page 7/7 Chemicals known to cause reproductive toxicity for males: Chemicals known to cause developmental toxicity: (Contd. of page 6) Carcinogenic categories EPA (Environmental Protection Agency) TLV (Threshold Limit Value established by ACGIH) NIOSH-Ca (National Institute for Occupational Safety and Health) Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information The information provided in this is based on our present knowledge, and believed to be correct at the date of publication. However, no representation is made concerning its accuracy and completeness. It is intended as guidance only, and is not to be considered a warranty or quality specification. All materials may present unknown hazards, and should be used with caution. Although certain hazards are described, we cannot guarantee that these are the only hazards which exist. PerkinElmer, Inc. shall not be held liable for any damage resulting from handling or from contact with the product. Date of preparation / last revision 05/26/2015 / - Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association () LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2