Safety Data Sheet. according to Regulation (EC) No 1907/2006. Visalys Whitening 30 Chairside

Transcription

1 Page 1 of 7 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Two-part dental whitening system based on hydrogen peroxid with 30 % of hydrogen peroxid in mixture Details of the supplier of the safety data sheet Company name: Street: Place: Im Heerfeld 7 D Eschenburg Telephone: + 49(0) 2774/705-0 Telefax:+49 (0)2774/ info@kettenbach.de Contact person: Regulatory Affairs Manager Telephone: +49 (0)2774/705-0 Internet: Responsible Department: 1.4. Emergency telephone number: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Regulatory Affairs +49 (0) (English/German) Classification according to Directive 67/548/EEC or 1999/45/EC Indications of danger: Xn - Harmful, Xi - Irritant R phrases: Harmful if swallowed. Risk of serious damage to eyes. Classification according to Regulation (EC) No. 1272/2008 [CLP] Hazard Statements: Harmful if swallowed or if inhaled. Causes serious eye damage. Harmful to aquatic life with long lasting effects Label elements Pictograms: GHS05-GHS07 Hazard statements H302+H332 H318 H412 Harmful if swallowed or if inhaled. Causes serious eye damage. Harmful to aquatic life with long lasting effects. Precautionary statements P501 Dispose of contents/container to Refer to any Community provisions relating to waste.. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302+P350 IF ON SKIN: Gently wash with plenty of soap and water. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

2 Page 2 of 7 Special labelling of certain mixtures EUH210 Safety data sheet available on request Other hazards None by intended use. SECTION 3: Composition/information on ingredients 3.2. Mixtures Chemical characterization Preparation of hydrogen peroxid (30%), polyglycoles, organic amines and silicon dioxid. Hazardous components EC No CAS No Index No REACH No Chemical name Classification according to Directive 67/548/EEC Classification according to Regulation (EC) No. 1272/2008 [CLP] Quantity hydrogen peroxide 30 - < 35 % O - Oxidizing, C - Corrosive, Xn - Harmful R /22-35 Full text of R-, H- and EUH-phrases: see section 16. Further Information All statements of ingredients refer to the mixture. SECTION 4: First aid measures 4.1. Description of first aid measures General information Change contaminated clothing. After inhalation Provide fresh air. After contact with skin After contact with skin, wash immediately with: Water and soap. After contact with eyes In case of contact with eyes, rinse immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart. Subsequently consult an ophthalmologist. Remove contact lenses, if present and easy to do. Continue rinsing. Seek medical advice immediately. After ingestion IF SWALLOWED: rinse mouth. Do NOT induce vomiting. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Water. Foam. Carbon dioxide (CO2) Special hazards arising from the substance or mixture In case of fire may be liberated: Gases/vapours, harmful 5.3. Advice for firefighters Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water. In case of fire: Wear self-contained breathing apparatus. SECTION 6: Accidental release measures

3 Page 3 of Personal precautions, protective equipment and emergency procedures Safe handling: see section 7 Personal protection equipment: see section Environmental precautions Do not allow to enter into surface water or drains Methods and material for containment and cleaning up Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Take up mechanically, placing in appropriate containers for disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling Avoid contact with eyes. When using do not eat, drink or smoke. Wash hands thoroughly after handling Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep only in the original container in a cool, well-ventilated place. Keep at temperature not exceeding 12 C (to be specified by the manufacturer). Sensitivity to light. Advice on storage compatibility Keep away from food, drink and animal feedingstuffs. Keep away from combustible material. Further information on storage conditions Keep container tightly closed in a cool, well-ventilated place. Do not store at temperatures over: 10 C SECTION 8: Exposure controls/personal protection 8.1. Control parameters Exposure limits (EH40) CAS No Substance ppm mg/m³ fibres/ml Category Origin Hydrogen peroxide TWA (8 h) WEL 8.2. Exposure controls Protective and hygiene measures Avoid contact with skin and eyes. Draw up and observe skin protection programme. Eye/face protection Tightly sealed safety glasses. Hand protection Single-use gloves. Skin protection Wear protective gloves and protective clothing. Respiratory protection none Environmental exposure controls Do not allow to enter into surface water or drains STEL (15 min) WEL

4 Page 4 of 7 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state: Colour: Odour: Jelly whitish characteristic ph-value (at 4-12 C): ca. 7-8 Test method Changes in the physical state Initial boiling point and boiling range: Vapour pressure: (at 4-12 C) Density (at 20 C): Water solubility: 9.2. Other information Data apply to the main component. ca. 110 C ca. 20 hpa 1,2 g/cm³ miscible. SECTION 10: Stability and reactivity Chemical stability The product is stable under storage at normal ambient temperatures Possibility of hazardous reactions Alkali (lye) Exothermic reaction with: Reducing agents, Alcohol, Amines, Acid, alkali, Alkali (lye), Oxidizing agents Conditions to avoid Keep away from heat Hazardous decomposition products No known hazardous decomposition products. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Harmful if swallowed or if inhaled. Irritation and corrosivity Irritant effect on the eye: Irritant. Risk of serious damage to eyes. Irritant effect on the skin: Irritant. SECTION 12: Ecological information Toxicity Acute fish toxicity LC50: 16,4 mg/l (96h) Pimephales promelas Acute Daphnia toxicity EC50: 7,7 mg/l (24h) Daphnia magna Algae toxicity IC50: 2,5 mg/l (72h) Chlorella vulgaris Persistence and degradability Product is biodegradable. Further information Do not allow uncontrolled leakage of product into the environment.

5 Page 5 of 7 SECTION 13: Disposal considerations Waste treatment methods Advice on disposal Dispose of waste according to applicable legislation. Waste disposal number of waste from residues/unused products WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of plastics, synthetic rubber and man-made fibres; other still bottoms and reaction residues Classified as hazardous waste. Contaminated packaging Cleaned containers may be recycled. SECTION 14: Transport information Land transport (ADR/RID) Transport hazard class(es): Packing group: Hazard label: Hydrogen peroxide, aqueous solution 5.1 II Classification code: OC1 Limited quantity: 1 L Transport category: 2 Hazard No: Tunnel restriction code: 58 E Other applicable information (land transport) E2 Inland waterways transport (ADN) Transport hazard class(es): Packing group: II Hazard label: HYDROGEN PEROXIDE, AQUEOUS SOLUTION with not less than 20% but not more than 60% hydrogen peroxide (stabilized as necessary) Classification code: Limited quantity: OC1 1 L Other applicable information (inland waterways transport) E2 Marine transport (IMDG)

6 Page 6 of Transport hazard class(es): Packing group: Hazard label: HYDROGEN PEROXID, AQUEOUS SOLUTION, from 20% minimum to a maximum of 60% hydrogen peroxid content (stabilization as necessary) 5.1 II 5.1 (8) EmS: Air transport (ICAO) F-H, S-Q Transport hazard class(es): Packing group: Hazard label: HYDROGEN PEROXIDE, AQUEOUS SOLUTION with not less than 20 % but not more than 40 % hydrogen peroxide (stabilized as necessary) 5.1 II Limited quantity Passenger: IATA-packing instructions - Passenger: IATA-max. quantity - Passenger: IATA-packing instructions - Cargo: IATA-max. quantity - Cargo: Other applicable information (air transport) Passenger-LQ: Y540 E2 0.5 L L L SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture National regulatory information Water contaminating class (D): 2 - water contaminating SECTION 16: Other information Relevant R-phrases (Number and full text) 05 Heating may cause an explosion. 08 Contact with combustible material may cause fire. 20/22 Harmful by inhalation and if swallowed. 35 Causes severe burns. Relevant H- and EUH-phrases (Number and full text) H302+H332 Harmful if swallowed or if inhaled. H318 Causes serious eye damage. H412 Harmful to aquatic life with long lasting effects. EUH210 Safety data sheet available on request. Further Information The information is based on present level of our knowledge. It does not, however, give assurances of product properties and establishes no contract legal rights. The receiver of our product is singulary responsible for adhering to existing laws and regulations.

7 Page 7 of 7 (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)