Version: 3. Hauptstr , Aichstetten, Germany. Tel./Fax.: Tel , Fax

Transcription

1 Revised edition: Version: 3 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Product Name: Ethomeen C 25 Page Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Dispersing agent Uses advised against: Details of the Supplier of the (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) H302 Cat.: 4 H318 Cat.: 1 H412 Cat.: 3 Classification according to Directive No. 67/548/EC or No. 1999/45/EC Harmful (Xn) R22 Irritating (Xi) R41 Acute toxicity (oral), hazard category 4 Serious eye damage, hazard category 1 Chronic aquatic toxicity, hazard category 3 Harmful if swallowed. Causes serious eye damage. Harmful to aquatic life with long lasting effects. Harmful if swallowed. Risk of serious damage to eyes. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Hazard designation: 2

2 Page 2 GHS05-2 GHS07 Signal word: Hazard designation: Safety designation: H302 H318 H412 P264 P270 P273 P280 P305+P351+P338 P310 P501 Danger Harmful if swallowed. Causes serious eye damage. Harmful to aquatic life with long lasting effects. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Avoid release to the environment. Wear protective gloves/ clothing/ eye/ face protection. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses and continue rinsing. Immediately call a poison center or physician. Dispose of contents/ container according to regional, national and international regulations Hazardous components for labelling: Amines, coco alkyl, ethoxylated, CAS No Other Hazards Composition/Information on Ingredients Substance This product is a substance: see details under 3.2. Mixture Chemical Characterization: Polyoxyethylene(15) coco amine Information on Components / Hazardous Ingredients: Amines, coco alkyl, ethoxylated (Xn; R22-41; H ) % CAS-Nr: EINECS-Nr: EC-Nr: Additional information: First Aid Measures Description of the First Aid Measures SVHC (Candidate List of Substances of very High Concern): This product does not contain any substances of high concern (REACH Regulation 1907/2006/EC, Article 59). General information: Take person away from hazardous area. 3

3 Immediately get medical help. Page 3 After inhalation: After skin contact: After eye contact: Supply fresh air. If required give artificial respiration. Keep patient warm. Consult physician if symptoms persist. Remove contaminated clothing immediately. Wash off with plenty of water and soap. Consult a physician if irritation persists. Remove contact lens. Rinse open eyes with plenty of water (10-15 min). Consult physician After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with water and give plenty of water to drink. Consult a physician. Never give anything by mouth to an unconscious person. Symptoms: No further information available Effects: Harmful if swallowed. Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Treat symptomatically. Use extinguishing media for surrounding fire Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture None known Special hazards: Advice for Firefighters Protective equipment: Further information: In case of fire: formation of carbon oxides, nitrogen oxides. Do not let extinguishing water enter the sewerage system or water courses. Wear self-contained respiratory protective device. Collect contaminated extinguishing water and debris separately; avoid contamination of sewage system. Contaminated extinguishing water and debris should be disposed of according to local regulations. 4

4 6. Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Page Personal precautions: Environmental Precautions Wear protective clothing. Ensure adequate ventilation Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soils, drains and surface water Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Contain with absorbent material (sand, diatomaceous earth, acid binder, universal absorbent, saw dust) and dispose accordingly. Protective clothing, see Section 8. Wear adequate protective clothing (see para. 8) Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Do not eat or drink during work. Do not smoke Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Storage class (VCI): Further Information: Specific End Use(s) Store in tightly sealed containers in a well ventilated location. Protect product from direct sunlight. No special measures necessary. Keep away from sources of ignition - do not smoke. 3 B; combustible liquids Store in a dry place Further information: Exposure Controls/Personal Protection Parameters to be Controlled Does not contain substances with occupational exposure limits. Parameters to be controlled (DE): 5

5 Parameters to be controlled: Page 5 Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation/exhaust system. Facilities storing or utilizing this material should be equipped with an eyewash and shower facility. Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Body protection: The usual precautionary measures are to be adhered to when handling chemicals. Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Required in case of insufficient ventilation (EN 143 or 149). Recommended: respiratory mask with an ABEK-filter. Protective gloves (EN 374) Neoprene Nitrile rubber Tightly fitting safety goggles (EN 166). Protective clothing, chemical resistant safety shoes Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Prevent contamination of open water ways and sewage system. Avoid contamination of ground water. Form: Color: Odor: Odor threshold: ph-value: Melting temperature: liquid bright brown amine-like 9-11 (1 % solution) -6 C Boiling temperature: > 300 C 6

6 Flash point: C Page 6 Evaporation rate: Flammability (solid, gas): > 150 C Upper explosion limit: no information available Lower explosion limit: no information available Vapor pressure: not determined Vapor density: Density: kg/m3 (20 C) Solubility in water: soluble Coefficient of variation (n- Octanol/Water): no information available Auto-ignition temperature: Decomposition temperature: No data available. Viscosity, dynamic: 200 mpa.s (20 C) Explosive properties: not explosive Oxidizing properties: not oxidizing Bulk density: not applicable Further Information Solubility in solvents: Viscosity, kinematic 190 mm2/s (20 C) Burning class: Solvent content: Solid content: Particle size: Other information: 10. Stability and Reactivity Reactivity Stable if used according to specifications. 7

7 10.2. Chemical Stability Stable if used according to specifications Possibility of Hazardous Reactions None if used according to specifications Conditions to Avoid Page Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: No data available. None known. Amines, coco alkyl, ethoxylated: mg/kg (rat) No information available Risk of severe eye damage. Harmful if swallowed. No relevant data found. No relevant data found. No relevant data found. Carcinogenicity: No relevant data found. 8

8 Teratogenicity: Page Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): No relevant data found. Toxic for aquatic organisms. May cause long-term adverse effects in the aquatic environment. Amines, coco alkyl, ethoxylated: LC50: 1-10 mg/l (96h, Onchorhynchus mykiss; OECD 203) EC50: 1-10 mg/l (48h, Daphnia magna; OECD 202) No data available. NOEC: mg/l (72h, algae) Readily biodegradable (OECD 301B). No bioaccumulation expected. On the basis of available data, the product does not contain and PBT or vpvb in percentage greater than 0.1 %. 3, hazardous Dispose of according to official national and local regulations. Uncleaned packaging: Packaging may be disposed of in the same manner as the product. 9

9 Page 9 Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG Transport Hazard Classes ADR Class: not applicable Hazard no.: Classification code: Tunnel restriction code: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: not applicable Hazard no.: Packaging Group ADR/RID: not applicable IMDG: IATA: Environmental Hazards Special Precautions for User None Not classified as a dangerous good under transport regulations Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code not applicable Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 3, very hazardous for water (German Regulation) Local regulations on chemical accidents: Seveso III Directive: not applicable under Directive 2012/18/EC. 10

10 Employment restrictions: Page Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information Not applicable. A Chemical Safety Assessment is not necessary for this product. Listed in the following inventories: EINECS ( ), TSCA (US), AICS (AUS), DSL (CA), ENCS/ISHL (JP), KECI (KR), PICCS (PH), NZIoC (NZ), INV (CH), IECSC (CN), INV (MY), INV (TR), INV (TW) This product is a substance as defined by the Chemicals Act. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.