Regulatory Affairs Department

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1 MATERIAL SAFETY DATA SHEET COLORTREND F RED OXIDE Specification: Revision Date: Version Number: Product and Company Identification Product identifier Version # 01 Issue date CAS # COLORTREND F RED OXIDE Mixture SAP Specification Product use Pigment dispersion Manufacturer Supplier Chromaflo Technologies Canada Inc. 235 Orenda Road Brampton, ON L6T 1E6 Canada Telephone Telefax CANADA: CANUTEC EMERGENCY NUMBER Product Regulatory Services MSDS prepared by Regulatory Affairs Department 2. Hazards Identification Emergency overview WARNING Potential health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Prolonged exposure may cause chronic effects. If product is in liquid or paste form, physical or health hazards listed related to dust are not considered significant. However, product may contain substances that could be potential hazards if caused to become airborne due to grinding, sanding or other abrasive processes. Inhalation. Ingestion. Skin contact. Eye contact. Avoid contact with eyes. Avoid contact with the skin. Prolonged inhalation may be harmful. Avoid breathing dust/fume/gas/mist/vapors/spray. Components of the product may be absorbed into the body by ingestion. Do not ingest. Cardiac. Central nervous system. Eyes. Respiratory system. Skin. Potential environmental effects May cause long-term adverse effects in the environment. 3. Composition / Information on Ingredients Hazardous components CAS # Percent Ethylene Glycol Diethylene glycol hydrate n-hazardous components CAS # Percent Alpha-(dodecylphenyl)-omega-hydroxy-poly(oxy-1,2-ethanediyl) Other components below reportable levels First Aid Measures First aid procedures Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. If a contact lens is present, DO NOT delay irrigation or attempt to remove the lens. Continue rinsing. Get medical attention immediately. 1 / 6

2 Skin contact Inhalation Ingestion tes to physician General advice 5. Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Fire fighting equipment/instructions Explosion data Sensitivity to static discharge Sensitivity to mechanical impact Remove and isolate contaminated clothing and shoes. Immediately flush skin with plenty of water. Get medical attention immediately. For minor skin contact, avoid spreading material on unaffected skin. Wash clothing separately before reuse. Move to fresh air. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Get medical attention, if needed. Rinse mouth thoroughly. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not use mouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. If ingestion of a large amount does occur, call a poison control center immediately. Symptoms may be delayed. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. t flammable by WHMIS criteria. Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. 6. Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up 7. Handling and Storage Handling Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. For personal protection, see section 8 of the MSDS. Do not contaminate water. Use water spray to reduce vapors or divert vapor cloud drift. Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Should not be released into the environment. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the MSDS. Avoid prolonged exposure. Do not use in areas without adequate ventilation. Wash thoroughly after handling. Avoid release to the environment. Storage Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the MSDS). 2 / 6

3 8. Exposure Controls / Personal Protection Occupational exposure limits US. ACGIH Threshold Limit Values Components Type Value TWA 2 mg/m3 Respirable fraction. Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2) Components Type Value Ceiling 100 mg/m3 TWA 2 mg/m3 Respirable particles. Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) Components Type Value 50 ppm Vapor. STEL 20 mg/m3 Particulate. TWA 10 mg/m3 Particulate. TWA 2 mg/m3 Respirable. Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act) Components Type Value TWA 2 mg/m3 Respirable fraction. Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) Components Type Value TWA 2 fibers/ml 2 mg/m3 Respirable particles. Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) Components Type Value US. OSHA Table Z-3 (29 CFR ) Components Ceiling 127 mg/m3 Vapor and mist. 50 ppm Vapor and mist. TWA 3 mg/m3 Respirable dust. Type Value Biological limit values TWA 0.3 mg/m3 Total dust. biological exposure limits noted for the ingredient(s). 0.1 mg/m3 Respirable. 20 millions of particle 2.4 millions of Respirable. particle 3 / 6

4 Engineering controls Personal protective equipment Eye / face protection Skin protection Respiratory protection Good general ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Ensure adequate ventilation, especially in confined areas. Wear safety glasses with side shields (or goggles). Wear chemical protective equipment that is specifically recommended by the manufacturer. It may provide little or no thermal protection. In the case of respirable dust and/or fumes, use self-contained breathing apparatus. Use a NIOSH/MSHA approved respirator if there is a risk of exposure to vapor/mist at levels exceeding the exposure limits. 9. Physical & Chemical Properties Appearance Physical state Color Odor Odor threshold ph Vapor pressure Vapor density Boiling point Melting point/freezing point Solubility (water) Specific gravity Relative density Flash point Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Auto-ignition temperature Other data Density Liquid. Liquid. Red. Mild. > 212 F (> 100 C) F (207.4 C) estimated F (117.4 C) estimated lbs/gal 10. Chemical Stability & Reactivity Information Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Material is stable under normal conditions. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Strong oxidizing agents. 11. Toxicological Information Toxicological data Product COLORTREND F RED OXIDE (CAS Mixture) Acute Dermal Oral Cat mg/kg estimated mg/kg estimated 4 / 6

5 Product Other Components Acute Dermal Oral Other Dog Guinea pig Cat Dog Guinea pig mg/kg estimated g/kg estimated g/kg estimated g/kg estimated g/kg estimated g/kg estimated mg/kg estimated mg/kg estimated 9530 mg/kg 1650 mg/kg 5500 mg/kg 8.2 g/kg 14.6 g/kg 5.89 g/kg 5.8 g/kg 2800 mg/kg * Estimates for product may be based on additional component data not shown. Chronic effects Carcinogenicity ACGIH Carcinogens IARC Monographs. Overall Evaluation of Carcinogenicity Prolonged inhalation may be harmful. t expected to be hazardous by WHMIS criteria. A4 t classifiable as a human carcinogen. A4 t classifiable as a human carcinogen. 2B Possibly carcinogenic to humans. 3 t classifiable as to carcinogenicity to humans. 12. Ecological Information Ecotoxicological data Components Aquatic Fish LC50 Fathead minnow (Pimephales promelas) 8050 mg/l, 96 hours * Estimates for product may be based on additional component data not shown. Ecotoxicity Environmental effects Persistence and degradability Contains a substance which causes risk of hazardous effects to the environment. An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Partition coefficient Ethylene Glycol / 6

6 13. Disposal Considerations Disposal instructions Waste from residues / unused products Contaminated packaging 14. Transport Information TDG t regulated as dangerous goods. IATA t regulated as dangerous goods. IMDG t regulated as dangerous goods. 15. Regulatory Information Canadian regulations WHMIS status WHMIS classification WHMIS labeling Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Dispose in accordance with all applicable regulations. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. Controlled D2A - Other Toxic Effects-VERY TOXIC Inventory status Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other Information HMIS ratings Health: 2* Flammability: 1 Physical hazard: 0 NFPA ratings Health: 2 Flammability: 1 Instability: 0 Disclaimer The information in the sheet was written based on the best knowledge and experience currently available. 6 / 6