Safety Data Sheet according to (EC) No 1907/2006

Transcription

1 Safety Data Sheet according to (EC) No 1907/2006 Pattex PL 600 Page 1 of 11 sds no. : Revision: printing date: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Pattex PL Relevant identified uses of the substance or mixture and uses advised against Intended use: Reaction adhesives 1.3. Details of the supplier of the safety data sheet Henkel AG & Co. KGaA Henkelstr Düsseldorf Germany Phone: +49 (211) Fax-no.: +49 (211) ua-productsafety.de@henkel.com 1.4. Emergency telephone number The Henkel information service also provides an around-the-clock telephone service on phone no.+49-(0) for exceptional cases. The product is notified at the 'Information Centers for Cases of Poisoning in Germany'. These centers provide information by telephone day and night in poisoning cases. Central emergency phone number: ++49 (0) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (DPD): F - Highly flammable R11 Highly flammable. Dangerous for the environment R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R67 Vapours may cause drowsiness and dizziness Label elements

2 Pattex PL 600 Page 2 of 11 Label elements (DPD): F - Highly flammable Risk phrases: R11 Highly flammable. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R67 Vapours may cause drowsiness and dizziness. Safety phrases: S2 Keep out of the reach of children. S16 Keep away from sources of ignition - No smoking. S29 Do not empty into drains. S46 If swallowed, seek medical advice immediately and show this container or label. S51 Use only in well-ventilated areas Other hazards Solvents contained in the product evaporate during processing and their vapors can form explosive/highly inflammable air/vapor mixtures. Pregnant women should absolutely avoid inhalation and skin contact. General chemical description: 1-Component assembly adhesive Base substances of preparation: Organic solvent Inorganic fillers Styrene-butadiene copolymer SECTION 3: Composition/information on ingredients

3 Pattex PL 600 Page 3 of 11 Declaration of the ingredients according to CLP (EC) No 1272/2008: Hydrocarbon aliphatic C4-11 < 0,1% benzene EC Number REACH-Reg No. content Classification < 15 % Aspiration hazard 1 H304 Skin irritation 2 H315 Specific target organ toxicity - single exposure 3 H336 Flammable liquids 2 H225 Chronic hazards to the aquatic environment 2 H < 15 % Flammable liquids H225 Specific target organ toxicity - single exposure 3 H336 Serious eye irritation 2 H < 0,5 % Flammable liquids 2 H225 Toxic to reproduction 2 H361f Aspiration hazard 1 H304 Specific target organ toxicity - repeated exposure 2 H373 Skin irritation 2 H315 Specific target organ toxicity - single exposure 3 H336 Chronic hazards to the aquatic environment 2 H411 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available. Declaration of ingredients according to DPD (EC) No 1999/45: Hydrocarbon aliphatic C4-11 < 0,1% benzene EC Number REACH-Reg No. content Classification < 15 % F - Highly flammable; R11 Xi - Irritant; R38 Xn - Harmful; R65 R67 N - Dangerous for the environment; R51/ < 15 % F - Highly flammable; R R66 Xi - Irritant; R36 R < 0,5 % F - Highly flammable; R11 Toxic for reproduction - category 3.; R62 Xi - Irritant; R38 R67 Xn - Harmful; R65, R48/20 N - Dangerous for the environment; R51/53 For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available Description of first aid measures General information: In case of adverse health effects seek medical advice. SECTION 4: First aid measures

4 Pattex PL 600 Page 4 of 11 Inhalation: Move to fresh air, consult doctor if complaint persists. Skin contact: Rinse with running water and soap. Apply replenishing cream. Change all contaminated clothing. Eye contact: Rinse immediately with plenty of running water, seek medical advice if necessary. Ingestion: Rinse mouth and throat. Drink 1-2 glasses of water. Seek medical advice Most important symptoms and effects, both acute and delayed Vapors may cause drowsiness and dizziness Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: carbon dioxide, foam, powder, water spray jet, fine water spray Extinguishing media which must not be used for safety reasons: High pressure waterjet 5.2. Special hazards arising from the substance or mixture In the event of a fire, carbon monoxide (CO) and carbon dioxide (CO2) can be released Advice for firefighters Wear self-contained breathing apparatus. Wear protective equipment. Additional information: Cool endangered containers with water spray jet. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Wear protective equipment. Danger of slipping on spilled product Environmental precautions Do not empty into drains / surface water / ground water Methods and material for containment and cleaning up Remove mechanically. Dispose of contaminated material as waste according to Chapter Reference to other sections See advice in chapter 8 SECTION 7: Handling and storage 7.1. Precautions for safe handling Ventilate working rooms thoroughly. Avoid naked flames, sparking and sources of ignition. Switch off electrical devices. Do not smoke, do not weld. Do not empty waste into waste water drains. Also to be noted when processing larger amounts (> 1 kg): during processing and drying after adhesion, ventilate well. Avoid all sources of fire such as stoves and ovens. Switch off all electrical devices such as parabolic heaters, hot plates, storage heaters etc. in good time for them to have cooled down before commencing work. Avoid all sparks, including those occurring at electrical switches and devices.

5 Pattex PL 600 Page 5 of 11 Hygiene measures: Do not eat, drink or smoke while working. Wash hands before work breaks and after finishing work Conditions for safe storage, including any incompatibilities Ensure adequate ventilation. Keep only in the original container. Do not store together with food or other consumables (coffee, tea, tobacco, etc.) Specific end use(s) Reaction adhesives SECTION 8: controls/personal protection 8.1. Control parameters Valid for Germany Ingredient ppm mg/m 3 Type Category Remarks Short Term Classification: Category I: substances for which the localized effect has an assigned OEL or for substances with a sensitizing effect in respiratory passages. TRGS 900 N-HEXANE AGW: 2 If the AGW and BGW values are complied with, there should be no risk of reproductive damage (see Number 2.7). Short Term Category II: substances with a Classification: resorptive effect AGW: 8 If the AGW and BGW values are complied with, there should be no risk of reproductive damage (see Number 2.7) Time Weighted Average Indicative (TWA): TRGS 900 TRGS 900 TRGS 900 ECTLV Predicted No-Effect Concentration (PNEC): Name on list Environmental Compartment STP aqua (freshwater) aqua (marine water) sediment (freshwater) soil sediment (marine water) period mg/l ppm mg/kg others 650 mg/l 0,34 mg/kg 0,22 mg/kg 0,034 mg/kg 0,26 mg/l 0,026 mg/l Remarks

6 Pattex PL 600 Page 6 of 11 Derived No-Effect Level (DNEL): Name on list Application Area Route of Health Effect worker inhalation Acute/short term worker inhalation Acute/short term local effects worker dermal Long term worker inhalation Long term worker inhalation Long term local effects general inhalation Acute/short term general general general general general inhalation dermal inhalation inhalation oral Acute/short term local effects Long term Long term Long term local effects Long term Time 1468 mg/m mg/m3 63 mg/kg bw/day 734 mg/m3 734 mg/m3 734 mg/m3 734 mg/m3 37 mg/kg bw/day 367 mg/m3 367 mg/m3 4,5 mg/kg bw/day Remarks 8.2. controls: Respiratory protection: The product should only be used at workplaces with intensive ventilation/extraction. If intensive ventilation/extraction is not possible then self-contained independent respiratory protection should be worn. Hand protection: Recommended are gloves made from Nitril rubber ( Material thickness >0,1 mm, Perforation time < 30s).Gloves should be replaced after each short time contact or contamination. Available at laboratory specialized trade or at pharmacies / chemist's shops. In the case of longer contact protective gloves made from nitrile rubber are recommended according to EN 374. material thickness > 0.4 mm Perforation time > 10 minutes In the case of longer and repeated contact please note that in practice the penetration times may be considerably shorter than those determined according to EN 374. The protective gloves must always be checked for their suitability for use at the specific workplace (e.g. mechanical and thermal stress, product compatibility, antistatic effects, etc.). The gloves must be replaced immediately at the first signs of wear and tear. The information provided by the manufacturers and given in the relevant trade association regulations for industrial safety must always be observed. We recommend that a hand care plan is drawn up in cooperation with a glove manufacturer and the trade association in accordance with the local operating conditions. Eye protection: Goggles which can be tightly sealed. Skin protection: Suitable protective clothing

7 Pattex PL 600 Page 7 of 11 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance paste solid beige Odor of solvent ph Initial boiling point Flash point Decomposition temperature Vapour pressure Density (20 C (68 F)) Bulk density Viscosity Viscosity (kinematic) Explosive properties Solubility (qualitative) (20 C (68 F); Solvent: Water) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits lower upper Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties 1,23-1,29 g/cm3 partially soluble 2 %(V) 12,8 %(V) 9.2. Other information SECTION 10: Stability and reactivity Reactivity Reaction with acids: production of heat and carbon dioxide Chemical stability Stable under recommended storage conditions Possibility of hazardous reactions See section reactivity Conditions to avoid None if used for intended purpose Incompatible materials None if used properly Hazardous decomposition products None known Information on toxicological effects SECTION 11: Toxicological information General toxicological information: The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following.

8 Pattex PL 600 Page 8 of 11 Inhalative toxicity: The toxicity of the product is due to its narcotic effect after inhalation. In the event of protracted or repeated exposure, damage to health cannot be excluded. Skin irritation: Primary skin irritation: slightly irritating, does not require labeling Acute toxicity: type LD50 LC50 LD mg/kg 200 mg/l > mg/kg Route of application oral inhalation dermal time 1 h Species rat rat rabbit Method Skin corrosion/irritation: Result time Species not irritating 24 h rabbit Method Serious eye damage/irritation: Result time Species Method slightly irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) Respiratory or skin sensitization: not sensitising Result Test type Species Method Guinea pig maximisat ion test guinea pig OECD Guideline 406 (Skin Sensitisation) Germ cell mutagenicity: Repeated dose toxicity Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g Ames test) Metabolic activation / time with and without negative inhalation rat Species Method Result NOAEL=900 mg/kg NOAEL=0,002 mg/l Route of application time / Frequency of treatment oral: gavage 90 d daily rat inhalation 90 d continuous rat Species Method SECTION 12: Ecological information General ecological information: The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Do not empty into drains, soil or bodies of water. Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment.

9 Pattex PL 600 Page 9 of Toxicity Hydrocarbon aliphatic C4-11 < 0,1% benzene Hydrocarbon aliphatic C4-11 < 0,1% benzene Hydrocarbon aliphatic C4-11 < 0,1% benzene type Acute Toxicity Study time Species Method LC mg/l Fish OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 3 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC mg/l Algae OECD Guideline 201 (Alga, Growth Inhibition Test) LC mg/l Fish 48 h Leuciscus idus melanotus EC mg/l Daphnia 48 h Daphnia cucullata OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 > mg/l Algae 96 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) OECD Guideline 201 (Alga, Growth Inhibition Test) LC mg/l Fish OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 2,1 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC mg/l Algae OECD Guideline 201 (Alga, Growth Inhibition Test) Persistence and degradability Result Route of application Degradability Method readily biodegradable aerobic 100 % OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Test) readily biodegradable aerobic > 60 % Bioaccumulative potential / Mobility in soil LogKow Bioconcentration factor (BCF) time Species Temperature Method 0,6 OECD Guideline 107 (Partition Coefficient (noctanol / water), Shake Flask Method) 4 SECTION 13: Disposal considerations Waste treatment methods Product disposal: Dispose of waste and residues in accordance with local authority requirements. Disposal of uncleaned packages: Use packages for recycling only when totally empty. Waste code waste adhesives and sealants containing organic solvents and other dangerous substances

10 Pattex PL 600 Page 10 of 11 SECTION 14: Transport information Road transport ADR: Class: 4.1 Packaging group: II Classification code: F1 Hazard ident. number: 40 UN no.: 3175 Label: 4.1 Technical name: SOLIDS CONTAINING FLAMMABLE LIQUID, N.O.S. (petroleum) Tunnelcode: (E) Railroad transport RID: Class: 4.1 Packaging group: II Classification code: F1 Hazard ident. number: 40 UN no.: 3175 Label: 4.1 Technical name: SOLIDS CONTAINING FLAMMABLE LIQUID, N.O.S. (petroleum) Tunnelcode: Inland water transport ADN: Class: 4.1 Packaging group: II Classification code: F1 Hazard ident. number: UN no.: 3175 Label: 4.1 Technical name: SOLIDS CONTAINING FLAMMABLE LIQUID, N.O.S. (petroleum) Marine transport IMDG: Class: 4.1 Packaging group: II UN no.: 3175 Label: 4.1 EmS: F-A,S-I Seawater pollutant: - Proper shipping name: SOLIDS CONTAINING FLAMMABLE LIQUID, N.O.S. (petroleum) Air transport IATA: Class: 4.1 Packaging group: II Packaging instructions (passenger) 445 Packaging instructions (cargo) 448 UN no.: 3175 Label: 4.1 Proper shipping name: Solids containing flammable liquid, n.o.s. (petroleum) SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content 13,4 % (VOCV VOC regulation CH) National regulations/information (Germany):

11 Pattex PL 600 Page 11 of 11 WGK: 1, slightly water-endangering product. (German VwVwS of May 17, 1999 ) Classification in conformity with the calculation method Storage class VCI: 4.1B SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: R11 Highly flammable. R36 Irritating to eyes. R38 Irritating to skin. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R62 Possible risk of impaired fertility. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. H225 Highly flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. H361f Suspected of damaging fertility. H373 May cause damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.