Version: Hauptstr , Aichstetten, Germany. Tel./Fax.: Tel , Fax

Transcription

1 Revised edition: Version: 3.12 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Nigrosin Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Coloring agent for industrial purposes Uses advised against: Details of the Supplier of the (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) This product does not require classification and labelling as hazardous according to CLP/GHS. Classification according to Directive No. 67/548/EC or No. 1999/45/EC Safety Phrases: Possible Environmental Effects: Label Elements Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Hazard designation: No classification required according to the CLP/GHS guidelines. Not applicable Signal word: Hazard designation: Safety designation: Hazardous components for labelling: Other Hazards Dust can form an explosive mixture with air. Dust may be produced when working with this material, which can 2

2 Page 2 cause a mechanical irritation of eyes, nose and respiratory tract Composition/Information on Ingredients Substance Mixture Chemical Characterization: Dye, woodstain. Preparation made of azine dye and azo dye (C.I. Acid Black) Information on Components / Hazardous Ingredients: Hydrochloric acid, reaction products with aniline and nitrobenzene, sulfonated, sodium salts; REACH Reg. No % CAS-Nr: EINECS-Nr: EC-Nr: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: After ingestion: Seek medical attention in case of complaints. Supply fresh air. Consult physician if symptoms persist. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48h. Remove contaminated clothing. Wash off immediately with plenty of water and soap. Rinse open eyes with plenty of water. In case of discomfort seek medical help. Rinse mouth thoroughly with plenty of water. Do not induce vomiting. Consult physician immediately Most important Symptoms and Effects, both Acute and Delayed Symptoms: No further information available. Effects: Indication of any Immediate Medical Attention and special Treatment needed Treatment: No further information available Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Unsuitable extinguishing media: Water mist, extinguishing powder, foam, carbon dioxide. 3

3 Water spray Special Hazards arising from the Substance or Mixture Page Special hazards: Advice for Firefighters Protective equipment: Dust can form explosive mixtures with air. In case of fire: formation of carbon and nitrogen oxides, sulfur oxides, halogenated compounds, metal oxides/oxides. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Environmental Precautions Wear protective clothing Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soil, drains and surface waters Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Clean up mechanically. Transfer liquids and solid diking material to separate suitable containers for recovery or disposal. Protective clothing, see Section 8. Dispose of contaminated material according to Section 13. Wear adequate protective clothing (see para. 8). Avoid formation of dust. Do not inhale dust Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Change contaminated clothing. Preventive skin protection recommended. Wash hands after work. Storage conditions: Store in a cool and dry place. Protect product from direct sunlight. Keep away from ignitable sources and fire. Requirements for storage areas and containers: 4

4 Store the product in the original container. Do not store product in unlabelled containers. Page 4 Information on fire and explosion protection: Storage class (VCI): Do not store together with: foodstuffs and animal feed. Do not store together with: oxidants. Avoid dust formation. Take measures to prevent electrostatic discharge. Ground and bond containers when transferring material. 11; Combustible solids Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): none known Parameters to be controlled: Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation. Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Do not inhale dust. Do not eat, drink or smoke while working. Wash hands before breaks and at the end of work. Remove contaminated clothing immediately. In case of formation of dust. Protective gloves Polypropylene (CR), nitrile rubber (NBR), polyvinyl chloride (PVC). Remove contaminated gloves and discard according to specifications. Safety glasses (EN 166) Body protection: 5

5 Protective clothing. Page Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Prevent from getting into the soil, surface water and sewage system. Form: Color: Odor: Odor threshold: solid black odorless ph-value: 7-12 (10 %) Melting temperature: Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: not available not available not available no information available no information available < hpa (20 C) Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: > 143 g/l < -4.9 (calc.) 310 C (590 F) Explosive properties: 6

6 not available Risk of dust explosion. Page Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: 383 kg/m3 Stable if used according to specifications. None if handled and stored according to specifications. Avoid formation of dust. Oxidizing agents. None if stored and handled according to specifications. Hydrochloric acid, reaction products with aniline and nitrobenzene, sulfonated, sodium salts: > 5000 mg/kg (rat; OECD 401) NOAEL: 1000 mg/kg (rat, 30 days/daily) > 2000 mg/kg (rat; OECD 402) LC50, inhalation: 7

7 Page 7 Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Carcinogenicity: No irritant effect known. Exposure to high ambient dust levels can cause irritation of the eyes. No information available Not sensitizing (OECD 429, Mouse Local Lymph Node Assay (LLNA)) In vitro Bacterial Reverse Mutation Test (OECD 471): negative In vitro Mammalian Cell Gene Mutation Test (OECD 476): negative In vivo genetic-toxicity: micronucleus negative (OECD 487) Oral: > 1000 mg/kg bw/day (28d, rat) No negative effects. Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: No relevant data found. Hydrochloric acid, reaction products with aniline and nitrobenzene, sulfonated, sodium salts: LC50: > 100 mg/l (96h, Danio rerio; OECD 203) EC50: > 100 mg/l (48h, Daphnia magna) EC50: > 1000 mg/l (3h; active sludge; OECD 209) Algae toxicity: IC50: > 100 mg/l (72h, Desmodesmus subspicatus) Persistency and Degradability Not readily biodegradable (30 %, 28d; OECD 302B) Bioaccumulation logpow: < -4.9 (low bioaccumulation) 8

8 Mobility No data available Results of PBT- und vpvp Assessment Not applicable Other Adverse Effects Page 8 Water hazard class: 2 (German Regulation) (Assessment by list): hazardous. Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): Uncleaned packaging: Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: Product does not contain relevant concentrations of heavy metals; does not contain nitrogen, phosphates or phosphor-organic compounds. Product does not contain any organically bound halogens which influence the AOX value of discard water. In accordance with current regulations, product may be taken to waste disposal site or incineration plant, after consultation with site operator and/or with the responsible authority. The waste code is determined according to the kind of waste and industry stated in the European Waste Catalogue. Packaging may be disposed of in the same manner as the product. No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. Tunnel restriction code: 9

9 Page 9 IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards Special Precautions for User None Not classified as a dangerous good under transport regulations Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Do not store together with foodstuffs Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: Local regulations on chemical accidents: 2, hazardous for water (German Regulation, Assessment by list) Seveso III: does not apply Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment is not necessary for this product. EC. REACH, Annex XIV, Candidate List of Substances of very High Concern (SVHC): not regulated / This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.