SAFETY DATA SHEET Silver Rinse / Sølvrens

Transcription

1 SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name Product number Relevant identified uses of the substance or mixture and uses advised against Identified uses Housekeeping Product 1.3. Details of the supplier of the safety data sheet Supplier Premiere Produkter Austbosletta Hundvag Stavanger Norway Emergency telephone number Emergency telephone +44 (0) GMT 9am-5pm Monday-Friday SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification Physical hazards Not Classified Health hazards Environmental hazards Carc. 2 - H351 Aquatic Chronic 3 - H412 Classification (67/548/EEC or 1999/45/EC) Human health Environmental Carc. Cat. 3;R40. R52/53. See Section 11 for additional information on health hazards. The product contains a substance which is harmful to aquatic organisms and which may cause long-term adverse effects in the aquatic environment Label elements Pictogram 1/8

2 Signal word Hazard statements Precautionary statements Contains Supplementary precautionary statements Warning H351 Suspected of causing cancer. H412 Harmful to aquatic life with long lasting effects. P273 Avoid release to the environment. P281 Use personal protective equipment as required. P405 Store locked up. P501 Dispose of contents/container to THIOUREA P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P308+P313 IF exposed or concerned: Get medical advice/attention Other hazards This product does not contain any substances classified as PBT or vpvb. SECTION 3: Composition/information on ingredients 3.2. Mixtures THIOUREA 1-5% CAS number: EC number: Classification Carc. 2 - H351 Repr. 2 - H361d Acute Tox. 4 - H302 Aquatic Chronic 2 - H411 Classification (67/548/EEC or 1999/45/EC) Carc. Cat. 3;R40 Repr. Cat. 3;R63 Xn;R22 N;R51/53 PROPAN-2-OL <1% CAS number: EC number: Classification Flam. Liq. 2 - H225 Eye Irrit. 2 - H319 STOT SE 3 - H336 Classification (67/548/EEC or 1999/45/EC) F;R11 Xi;R36 R67 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Ingestion Skin contact Remove affected person from source of contamination. Move affected person to fresh air at once. Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Get medical attention. Rinse mouth thoroughly with water. Give plenty of water to drink. Give milk instead of water if readily available. Never give anything by mouth to an unconscious person. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention immediately. Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention if irritation persists after washing. 2/8

3 Eye contact Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15 minutes. Continue to rinse for at least 15 minutes. Get medical attention immediately. Continue to rinse Most important symptoms and effects, both acute and delayed Inhalation Ingestion Skin contact Eye contact Vapours may cause headache, fatigue, dizziness and nausea. Ingestion of large amounts may cause unconsciousness. Prolonged or repeated contact with skin may cause irritation, redness and dermatitis. Irritation and redness, followed by blurred vision Indication of any immediate medical attention and special treatment needed Notes for the doctor Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Extinguish with the following media: Carbon dioxide (CO2). Dry chemicals. Foam Special hazards arising from the substance or mixture Hazardous combustion products Does not decompose when used and stored as recommended Advice for firefighters Protective actions during firefighting Special protective equipment for firefighters Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet Environmental precautions Environmental precautions Do not discharge into drains or watercourses or onto the ground. Collect and dispose of spillage as indicated in Section Methods and material for containment and cleaning up Methods for cleaning up Absorb spillage with non-combustible, absorbent material. Collect and place in suitable waste disposal containers and seal securely Reference to other sections Reference to other sections For waste disposal, see section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Usage precautions Avoid inhalation of vapours/spray and contact with skin and eyes. Provide adequate ventilation Conditions for safe storage, including any incompatibilities Storage precautions Store in tightly-closed, original container in a dry and cool place. Do not store near heat sources or expose to high temperatures. Keep away from heat, sparks and open flame. 3/8

4 Storage class Chemical storage Specific end use(s) Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: Exposure Controls/personal protection 8.1. Control parameters Occupational exposure limits PROPAN-2-OL Long-term exposure limit (8-hour TWA): WEL 400 ppm 999 mg/m³ Short-term exposure limit (15-minute): WEL 500 ppm 1250 mg/m³ WEL = Workplace Exposure Limit 8.2. Exposure controls Protective equipment Eye/face protection Hand protection Other skin and body protection Respiratory protection The following protection should be worn: Chemical splash goggles or face shield. Wear protective gloves. Wear appropriate clothing to prevent any possibility of skin contact. Wear apron or protective clothing in case of contact. No specific recommendations. Respiratory protection must be used if the airborne contamination exceeds the recommended occupational exposure limit. SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Appearance Colour Odour Odour threshold ph Melting point Initial boiling point and range Flash point Evaporation rate Evaporation factor Upper/lower flammability or explosive limits Other flammability Vapour pressure Vapour density Clear liquid. Blue. Chemical. : : 4/8

5 Relative density Bulk density Solubility(ies) Partition coefficient Auto-ignition temperature Decomposition Temperature Soluble in water. Viscosity <10 20 C Explosive properties Oxidising properties 9.2. Other information Other information Not known. SECTION 10: Stability and reactivity Reactivity Reactivity The following materials may react with the product: Strong oxidising agents. Acids Chemical stability Stability Stable at normal ambient temperatures and when used as recommended Possibility of hazardous reactions Possibility of hazardous reactions Not known Conditions to avoid Conditions to avoid Avoid exposure to high temperatures or direct sunlight Incompatible materials Materials to avoid Strong oxidising agents. Strong acids Hazardous decomposition products Hazardous decomposition products Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. Oxides of carbon. Oxides of nitrogen. When heated, vapours/gases hazardous to health may be formed. SECTION 11: Toxicological information Information on toxicological effects Toxicological effects Acute toxicity - oral Notes (oral LD₅₀) Acute toxicity - dermal Notes (dermal LD₅₀) Acute toxicity - inhalation Notes (inhalation LC₅₀) Germ cell mutagenicity Genotoxicity - in vitro No information available. 5/8

6 Genotoxicity - in vivo Carcinogenicity Carcinogenicity Reproductive toxicity Reproductive toxicity - fertility Reproductive toxicity - development Specific target organ toxicity - single exposure STOT - single exposure Specific target organ toxicity - repeated exposure STOT - repeated exposure Aspiration hazard Aspiration hazard Inhalation Ingestion Skin contact Eye contact May cause respiratory system irritation. May cause stomach pain or vomiting. Swallowing concentrated chemical may cause severe internal injury. Repeated exposure may cause skin dryness or cracking. May cause severe eye irritation. SECTION 12: Ecological Information Ecotoxicity Dangerous for the environment. May cause long-term adverse effects in the aquatic environment Toxicity Toxicity Very toxic to aquatic organisms Persistence and degradability Persistence and degradability The product is biodegradable Bioaccumulative potential Bioaccumulative potential Partition coefficient The product is not bioaccumulating Mobility in soil Mobility The product is miscible with water and may spread in water systems Results of PBT and vpvb assessment Results of PBT and vpvb assessment This product does not contain any substances classified as PBT or vpvb Other adverse effects Other adverse effects None known. SECTION 13: Disposal considerations Waste treatment methods 6/8

7 General information Disposal methods Waste is classified as hazardous waste. Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority. Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority. SECTION 14: Transport information General Wear protective clothing as described in Section 8 of this safety data sheet UN number UN No. (ADR/RID) UN proper shipping name Not known Transport hazard class(es) IMDG class Packing group IMDG packing group III Environmental hazards Environmentally hazardous substance/marine pollutant Special precautions for user Not known Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No information required. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations EU legislation The Control of Substances Hazardous to Health Regulations 2002 (SI 2002 No. 2677) (as amended). Dangerous Substances Directive 67/548/EEC. System of specific information relating to Dangerous Preparations. 2001/58/EC Chemical safety assessment No chemical safety assessment has been carried out. SECTION 16: Other information Issued by Health & Safety Officer Revision date 25/09/2013 Revision 4 Supersedes date 12/08/2013 7/8

8 SDS number 6 Risk phrases in full Hazard statements in full R11 Highly flammable. R22 Harmful if swallowed. R36 Irritating to eyes. R40 Limited evidence of a carcinogenic effect. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R63 Possible risk of harm to the unborn child. R67 Vapours may cause drowsiness and dizziness. H225 Highly flammable liquid and vapour. H302 Harmful if swallowed. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H361d Suspected of damaging the unborn child. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. 8/8