Version: 1.5 Revision Date: Identification of the substance/mixture and of the company/undertaking

Transcription

1 1. Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name : 1.2 Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Mixture : Fertilizer 1.3 Details of the supplier of the safety data sheet Company : COMPO EXPERT GmbH Gildenstraße 38 D Münster Telephone : / Telefax : +49 (0)251/ address : info@compo.de 1.4 Emergency telephone number Central Safety & Environment Telephone: Hazards identification 2.1 Classification of the substance or mixture Classification (REGULATION (EC) No 1272/2008) Acute toxicity, Category 4 Skin irritation, Category 2 Serious eye damage, Category 1 Specific target organ toxicity - repeated exposure, Category 2 Acute aquatic toxicity, Category 1 Chronic aquatic toxicity, Category 1 Classification(67/548/EEC,1999/45/EC) Harmful Irritant Dangerous for the environment 2.2 Label elements Labelling(REGULATION (EC) No 1272/2008) H302: Harmful if swallowed. H315: Causes skin irritation. H318: Causes serious eye damage. H373: May cause damage to organs through prolonged or repeated exposure. H400: Very toxic to aquatic life. H410: Very toxic to aquatic life with long lasting effects. R22: Harmful if swallowed. R48/20/22: Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. R41: Risk of serious damage to eyes. R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 1/13 Print Date:

2 Hazard pictograms : Signal word : Danger Hazard statements : H302 Harmful if swallowed. H315 Causes skin irritation. H318 Causes serious eye damage. H373 May cause damage to organs through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects. Precautionary statements : P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. Prevention: P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: P301 + P312 P305 + P351 + P338 P310 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. 2.3 Other hazards 3. Composition/information on ingredients 3.2 Mixtures Chemical nature : Mixture of inorganic salts. Hazardous components Chemical Name CAS-No. EC-No. Registration number copper sulphate XXXX Classification (67/548/EEC) Xn; R22 Xi; R36/38 N; R50-R53 Classification (REGULATION (EC) No 1272/2008) Eye Irrit. 2; H319 Skin Irrit. 2; H315 Aquatic Acute 1; H400 Aquatic Chronic 1; H410 Acute Tox. 4; H302 Concentration [%] >= 10 - <= 15 2/13 Print Date:

3 zinc sulphate XXXX Xn; R22 Xi; R41 N; R50-R53 Acute Tox. 4; H302 Eye Dam. 1; H318 Aquatic Acute 1; H400 Aquatic Chronic 1; H410 >= 5 - <= 10 manganese sulphate XXXX Xn; R48/20/22 N; R51-R53 STOT RE 2; H373 Aquatic Chronic 2; H411 >= 10 - <= 15 tetrasodium ethylene diamine tetraacetate Xn; R22 Xi; R41 Acute Tox. 4; H302 Eye Dam. 1; H318 >= 10 - <= 25 iron (II) sulfate XXXX Xn; R22 Xi; R36/38 Acute Tox. 4; H302 Eye Irrit. 2; H319 Skin Irrit. 2; H315 >= 5 - <= 10 citric acid XXXX Xi; R36 Eye Irrit. 2; H319 >= 2,5 - <= 5 For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section First aid measures 4.1 Description of first aid measures General advice : Take off immediately all contaminated clothing. Wash contaminated clothing before re-use. If inhaled In case of skin contact In case of eye contact If swallowed : Move to fresh air. Keep patient warm and at rest. If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. : Flush with plenty of water. : Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. : Clean mouth with water and drink afterwards plenty of water. 4.2 Most important symptoms and effects, both acute and delayed Symptoms : No information available. 4.3 Indication of any immediate medical attention and special treatment needed Treatment : Treat symptomatically. 3/13 Print Date:

4 5. Firefighting measures 5.1 Extinguishing media Suitable extinguishing media : The product is not flammable. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. 5.2 Special hazards arising from the substance or mixture Specific hazards during firefighting 5.3 Advice for firefighters Special protective equipment for firefighters : Heating or fire can release toxic gas. : In the event of fire, wear self-contained breathing apparatus. In the event of fire and/or explosion do not breathe fumes. Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions : Avoid dust formation. Ensure adequate ventilation. Use personal protective equipment. Keep people away from and upwind of spill/leak. Keep away from sources of ignition - No smoking. 6.2 Environmental precautions Environmental precautions : Do not empty into drains. Do not flush into surface water or sanitary sewer system. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3 Methods and materials for containment and cleaning up Methods for cleaning up 6.4 Reference to other sections For personal protection see section 8. : Use mechanical handling equipment. Sweep up or vacuum up spillage and collect in suitable container for disposal. 7. Handling and storage 7.1 Precautions for safe handling Advice on safe handling : Provide appropriate exhaust ventilation at machinery and at places where dust can be generated. Avoid dust formation. Keep away from sources of ignition - No smoking. Avoid dust accumulation in enclosed space. 4/13 Print Date:

5 Advice on protection against fire and explosion : Keep away from sources of ignition - No smoking. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers Further information on storage conditions Advice on common storage : Keep in a dry, cool and well-ventilated place. : humid air and water : Keep away from food, drink and animal feed. German storage class : 13 Non Combustible Solids 7.3 Specific end uses : Always read the label and product information before use. 8. Exposure controls/personal protection 8.1 Control parameters no data available DNEL iron (II) sulfate : End Use: Workers Exposure routes: Skin contact Potential health effects: Acute effects, systemic effects Exposure time: 24 h Value: 2,8 mg/kg End Use: Workers Exposure routes: Inhalation Potential health effects: Acute effects, systemic effects Value: 9,9 mg/m3 End Use: Workers Exposure routes: Skin contact Potential health effects: Chronic effects, systemic effects Exposure time: 24 h 2,8 mg/kg End Use: Workers Exposure routes: Inhalation Potential health effects: Chronic effects, systemic effects Value: 9,9 mg/m3 End Use: Consumers Exposure routes: Ingestion Potential health effects: Acute effects, systemic effects Exposure time: 24 h 1,4 mg/kg End Use: Consumers Exposure routes: Skin contact Potential health effects: Acute effects, systemic effects Exposure time: 24 h 1,4 mg/kg 5/13 Print Date:

6 End Use: Consumers Exposure routes: Inhalation Potential health effects: Acute effects, systemic effects Value: 2,5 mg/m3 End Use: Consumers Exposure routes: Ingestion Potential health effects: systemic effects, Chronic effects Exposure time: 24 h 1,4 mg/kg End Use: Consumers Exposure routes: Skin contact Potential health effects: Chronic effects, systemic effects Exposure time: 24 h 1,4 mg/kg End Use: Consumers Exposure routes: Inhalation Potential health effects: Chronic effects, systemic effects Value: 2,5 mg/m3 PNEC iron (II) sulfate : Water This product has no known eco-toxicological effects. Behaviour in waste water treatment plants Value: 2483 mg/l Fresh water sediment Value: mg/kg Marine sediment Value: mg/kg Soil Value: mg/kg 8.2 Exposure controls Engineering measures Provide adequate ventilation. Personal protective equipment Respiratory protection Hand protection Eye protection Skin and body protection Hygiene measures : In case of insufficient ventilation, wear suitable respiratory equipment. Half mask with a particle filter P2 (EN 143). : For prolonged or repeated contact use protective gloves. Preventive skin protection : Wear suitable gloves and eye/face protection. : Protective suit : Keep away from food, drink and animal feed. Wash hands before breaks and at the end of workday. 6/13 Print Date:

7 Do not breathe dust. Use protective skin cream before handling the product. Protective measures : Handle in accordance with good industrial hygiene and safety practice. Environmental exposure controls General advice : Do not empty into drains. Do not flush into surface water or sanitary sewer system. If the product contaminates rivers and lakes or drains inform respective authorities. 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance Colour Odour ph Melting point/range Boiling point/boiling range Flash point Evaporation rate Flammability (solid, gas) Lower explosion limit Upper explosion limit Vapour pressure Relative vapour density : powder : light blue : characteristic : no data available : no data available : no data available : The product is not flammable. Density : 1,347 g/m³, 20 C Water solubility Partition coefficient: n- octanol/water Autoignition temperature Ignition temperature Thermal decomposition Viscosity, dynamic Explosive properties Oxidizing properties 9.2 Other information : soluble : not auto-flammable : no data available : No decomposition if stored and applied as directed. : Not explosive : Not considered an oxidizing substance 10. Stability and reactivity 10.1 Reactivity 7/13 Print Date:

8 No decomposition if stored and applied as directed Chemical stability No decomposition if stored and applied as directed Possibility of hazardous reactions Hazardous reactions : None known. GLP: No information available Conditions to avoid Conditions to avoid 10.5 Incompatible materials Materials to avoid : Keep away from heat and sources of ignition. : Amines Strong oxidizing agents Strong acids 10.6 Hazardous decomposition products Hazardous decomposition products : nitrogen oxides (NOx) 11. Toxicological information 11.1 Information on toxicological effects Product Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Further information : May cause skin irritation and/or dermatitis. : May irritate eyes. : None known. : Irritant, Harmful copper sulphate : Acute oral toxicity Skin corrosion/irritation Serious eye damage/eye irritation : LD50 Oral: 300 mg/kg, rat : Classification: Irritant : Classification: Irritant zinc sulphate : Acute oral toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye irritation : LD50: mg/kg, rat : LD50 Dermal: > mg/kg, rat : rabbit, Classification: Irritating to skin. : rabbit, Result: Risk of serious damage to eyes. manganese sulphate : Acute oral toxicity : LD50: mg/kg, rat tetrasodium ethylene diamine tetraacetate : 8/13 Print Date:

9 Acute oral toxicity Skin corrosion/irritation Serious eye damage/eye irritation : LD50: > mg/kg, rat : Classification: non-irritant : Classification: Irritant Acute oral toxicity : LD50: > mg/kg, rat, OECD Test Guideline 401 Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization STOT - repeated exposure STOT - repeated exposure STOT - repeated exposure STOT - repeated exposure : LD50: mg/kg, rat, Calculation method : This information is not available. : LD50: > mg/kg, rat, Converted acute toxicity point estimate : Result: Skin irritation, OECD Test Guideline 404, Irritating to skin and mucous membranes : Result: Eye irritation, OECD Test Guideline 405 : Result: Did not cause sensitization on laboratory animals., OECD TG 429 : rat, Oral, Exposure time: 90 d, NOAEL: mg/kg, Information given is based on data obtained from similar substances. : rat, Oral, Exposure time: 49 d, NOAEL: 100 mg/kg : by inhalation, This information is not available. : Dermal, This information is not available. : Remarks: No known effect. citric acid : Acute oral toxicity : LD50 Oral: mg/kg, rat 12. Ecological information 12.1 Toxicity copper sulphate : Toxicity to fish Toxicity to daphnia and other aquatic invertebrates. Toxicity to algae zinc sulphate : Toxicity to fish Toxicity to daphnia and other aquatic invertebrates. : LC50: 0,1-2,5 mg/l, 96 h, Salmo sp. : EC50: 0,024 mg/l, 48 h, Daphnia magna (Water flea) : EC50: 0,1 mg/l, 4 h, Scenedesmus quadricauda (Green algae) : LC50: 0,43 mg/l, 96 h, Oncorhynchus mykiss (rainbow trout) : EC50: 1,86 mg/l, 48 h, Daphnia magna (Water flea) 9/13 Print Date:

10 Toxicity to algae Toxicity to bacteria : EC50: 0,52 mg/l, 120 h, Scenedesmus quadricauda (Green algae) : EC50: 22,75 mg/l, 0,5 h, Bacteria manganese sulphate : Toxicity to daphnia and other : EC50: 30 mg/l, Daphnia magna (Water flea) aquatic invertebrates. tetrasodium ethylene diamine tetraacetate : Toxicity to fish : LC50: 135 mg/l, 96 h, Lepomis macrochirus (Bluegill sunfish), static test Toxicity to daphnia and other aquatic invertebrates. Toxicity to algae Ecotoxicology Assessment Acute aquatic toxicity citric acid : Toxicity to fish Toxicity to daphnia and other aquatic invertebrates. Toxicity to algae Toxicity to bacteria : EC50: > 100 mg/l, 48 h, Daphnia magna (Water flea) : EC50: > 100 mg/l, 72 h, Algae, static test, Algal inhibition test. : This product has no known eco-toxicological effects. : LC50: 440 mg/l, 96 h, golden orfe, static test : EC50: mg/l, 24 h, Daphnia magna (Water flea) : 640 mg/l, 7 DAY, Scenedesmus quadricauda (Green algae) : EC0: mg/l, 16 h, Pseudomonas putida 12.2 Persistence and degradability Product: Biodegradability : Biodegradability : 12.3 Bioaccumulative potential Product: Bioaccumulation : Bioaccumulation : 12.4 Mobility in soil Product: Mobility Distribution among environmental compartments The methods for determining biodegradability are not applicable to inorganic substances. The methods for determining the biological degradability are not applicable to inorganic substances. Bioaccumulation is unlikely. Accumulation in aquatic organisms is unlikely. : After release, adsorbs onto soil. : no data available 10/13 Print Date:

11 Distribution among : Medium: Soil, immobile environmental compartments 12.5 Results of PBT and vpvb assessment Product: Assessment Assessment : This substance is not considered to be very persistent nor very bioaccumulating (vpvb)., This substance is not considered to be persistent, bioaccumulating nor toxic (PBT) Other adverse effects Product: Additional ecological information Adsorbed organic bound halogens (AOX) : Do not flush into surface water or sanitary sewer system. : < 2 mg/kg 13. Disposal considerations 13.1 Waste treatment methods Product Contaminated packaging : Fertilizer Do not flush into surface water or sanitary sewer system. Do not dispose of with domestic refuse. In accordance with local and national regulations. : If recycling is not practicable, dispose of in compliance with local regulations. Suitable cleaning agents Water 14. Transport information 14.1 UN number Proper shipping name ADR / GGVS RID ADNR IMDG IATA-DGR : Environmentally hazardous substance, solid, n.o.s. (manganese sulphate, copper sulphate) : Environmentally hazardous substance, solid, n.o.s. (manganese sulphate, copper sulphate) : Environmentally hazardous substance, solid, n.o.s. (manganese sulphate, copper sulphate) : Environmentally hazardous substance, solid, n.o.s. (manganese sulphate, copper sulphate) : Environmentally hazardous substance, solid, n.o.s. (manganese 11/13 Print Date:

12 14.3 Transport hazard class ADR / GGVS : 9 RID : 9 ADNR : 9 IMDG : 9 IATA-DGR : Packing group III 14.5 Environmental hazards sulphate, copper sulphate) IMDG : Marine Pollutant Check Reqd 14.6 Special precautions for user Tunnel restriction code (E) 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Remarks : Not relevant 15. Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Water contaminating class (Germany) : WGK 3 highly water endangering 15.2 Chemical Safety Assessment A Chemical Safety Assessment is not required for this substance. 16. Other information Full text of R-phrases referred to under sections 2 and 3 R22 Harmful if swallowed. R36 Irritating to eyes. R36/38 Irritating to eyes and skin. R41 Risk of serious damage to eyes. R48/20/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. R50 Very toxic to aquatic organisms. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51 Toxic to aquatic organisms. R53 May cause long-term adverse effects in the aquatic environment. Full text of H-Statements referred to under sections 2 and 3. 12/13 Print Date:

13 H302 H315 H318 H319 H373 H400 H410 H411 Harmful if swallowed. Causes skin irritation. Causes serious eye damage. Causes serious eye irritation. May cause damage to organs through prolonged or repeated exposure. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Toxic to aquatic life with long lasting effects. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 13/13 Print Date: