Safety Data Sheet. according to Regulation (EC) No 1907/2006. MET-L-CHEK Penetrant FP-923

Transcription

1 Page 1 of 8 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Further trade names Article no. (user): (1 L) (10 L) (200 L) 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Fluorescent penetrant for surface crack detection 1.3. Details of the supplier of the safety data sheet Company name: Street: Spoekerdamm 2 Place: D Heidgraben Telephone: Telefax: info@helling.de Internet: Emergency telephone number: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Regulation (EC) No. 1272/2008 Hazard categories: Serious eye damage/eye irritation: Eye Dam. 1 Aspiration hazard: Asp. Tox. 1 Hazard Statements: May be fatal if swallowed and enters airways. Causes serious eye damage Label elements Regulation (EC) No. 1272/2008 Hazard components for labelling white mineral oil (petroleum) Secundary alcohol ethoxylates (3) Signal word: Pictograms: Danger GIZ Nord Göttingen +49-(0) (Information in German and English) Hazard statements H304 May be fatal if swallowed and enters airways. H318 Causes serious eye damage. Precautionary statements P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor. P331 Do NOT induce vomiting. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if

2 Page 2 of 8 P405 P Other hazards present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container to industrial incineration plant. SECTION 3: Composition/information on ingredients 3.2. Mixtures Hazardous components CAS No Chemical name EC No Index No REACH No Classification according to Regulation (EC) No. 1272/2008 [CLP] Quantity white mineral oil (petroleum) % Asp. Tox. 1; H Secundary alcohol ethoxylates (3) % Eye Dam. 1; H318 Full text of H and EUH statements: see section 16. SECTION 4: First aid measures 4.1. Description of first aid measures After inhalation Provide fresh air. In case of trouble call doctor. After contact with skin Wash with plenty of water. Take off contaminated clothing and wash it before reuse. After contact with eyes In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist. After ingestion Rinse mouth immediately and drink plenty of water. In case of trouble call doctor Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Co-ordinate fire-fighting measures to the fire surroundings. Water fog. Foam. ABC powder. Unsuitable extinguishing media High power water jet Special hazards arising from the substance or mixture Heating causes rise in pressure with risk of bursting. In case of fire may be liberated: Carbon dioxide. Carbon monoxide

3 Page 3 of Advice for firefighters In case of fire: Wear self-contained breathing apparatus. Additional information Suppress gases/vapours/mists with water spray jet. Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Provide adequate ventilation. Do not breathe gas/fumes/vapour/spray. Avoid contact with skin, eyes and clothes. Use personal protection equipment Environmental precautions Do not allow to enter into surface water or drains Methods and material for containment and cleaning up Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the recovered material as prescribed in the section on waste disposal Reference to other sections Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section 13 Disposal considerations: see section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling If handled uncovered, arrangements with local exhaust ventilation should be used if possible. Advice on protection against fire and explosion No special measures are necessary Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep container tightly closed in a cool, well-ventilated place. Advice on storage compatibility No special measures are necessary Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters Additional advice on limit values Does not contain substances above concentration limits fixing an occupational exposure limit Exposure controls Appropriate engineering controls If handled uncovered, arrangements with local exhaust ventilation have to be used. Do not breathe gas/fumes/vapour/spray.

4 Page 4 of 8 Protective and hygiene measures Remove contaminated, saturated clothing immediately. Draw up and observe skin protection programme. Wash hands and face before breaks and after work and take a shower if necessary. When using do not eat or drink. Avoid contact with eyes. Eye/face protection Tightly sealed safety glasses. Hand protection Suitable material: NR (Natural rubber (Caoutchouc), Natural latex). The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. Skin protection Wear suitable protective clothing. Respiratory protection In case of inadequate ventilation wear respiratory protection. Filtering device (full mask or mouthpiece) with filter: A SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state: Colour: Odour: ph-value: Changes in the physical state Melting point: Initial boiling point and boiling range: Flash point: Flammability Solid: Gas: Explosive properties not explosive. Lower explosion limits: Upper explosion limits: Ignition temperature: Auto-ignition temperature Solid: Gas: Decomposition temperature: Oxidizing properties Not oxidising. Vapour pressure: liquid yellow fluorescent characteristic > 250 C Test method > 93 C ASTM D 93 1,0 vol. % 10,0 vol. % 200 C Density (at 20 C): 0,916 g/cm³ ASTM D 1298 Water solubility: Immiscible

5 Page 5 of 8 Solubility in other solvents Partition coefficient: Viscosity / dynamic: Viscosity / kinematic: (at 40 C) Vapour density: Evaporation rate: Solvent content: 9.2. Other information Solid content: 9,1 mm²/s 57,0% VOC (1999/13/EU) 0,00% Temperature of decomposition ( C): SECTION 10: Stability and reactivity Reactivity Stable under normal conditions of use Chemical stability Stable under normal conditions of use Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products None known. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Based on available data, the classification criteria are not met. ATEmix calculated ATE (inhalative vapour) 6,67 mg/l

6 Page 6 of 8 CAS No Chemical name Exposure route Dose white mineral oil (petroleum) oral dermal inhalative (4 h) vapour LC Secundary alcohol ethoxylates (3) oral LD50 > 5000 mg/kg LD50 > 2000 mg/kg LD50 > 2000 mg/kg Species Rat Rabbit > 5 mg/l Rat Rat Source Method Irritation and corrosivity Irritant effect on the skin: Not an irritant. Irritant effect on the eye: Causes serious eye damage. Sensitising effects No sensitizing effect known. Carcinogenic/mutagenic/toxic effects for reproduction According to current knowledge not a carcinogen. According to current knowledge not mutagen. According to current knowledge not reproduction toxic. STOT-single exposure Based on available data, the classification criteria are not met. STOT-repeated exposure SECTION 12: Ecological information Toxicity The product is not: Ecotoxic. CAS No Chemical name Aquatic toxicity Dose [h] [d] Species Source white mineral oil (petroleum) Acute fish toxicity LC50 > h Leuciscus idus (golden OECD 203 mg/l orfe) Acute crustacea toxicity EC50 > h Daphnia magna OECD 202 mg/l Algea toxicity NOEC > 100 mg/l Secundary alcohol ethoxylates (3) Acute fish toxicity Acute crustacea toxicity LC mg/l 3 d Pseudokirchneriella subcapitata 96 h EC50 3,1 mg/l 48 h Daphnia magna OECD 201 Method Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment

7 Page 7 of Other adverse effects CAS : This surfactant does not meet the biodegradability criteria according to Regulation (EC) No 648/2004 for detergents. Further information Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. SECTION 13: Disposal considerations Waste treatment methods Advice on disposal Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. Dispose of waste according to applicable legislation. Must not be disposed together with household garbage. Waste disposal number of waste from residues/unused products WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of fine chemicals and chemical products not otherwise specified; other organic solvents, washing liquids and mother liquors Classified as hazardous waste. Contaminated packaging Non-contaminated packages may be recycled. Handle contaminated packages in the same way as the substance itself. SECTION 14: Transport information Land transport (ADR/RID) UN number: UN proper shipping name: Transport hazard class(es): Packing group: Inland waterways transport (ADN) UN number: UN proper shipping name: Transport hazard class(es): Packing group: Marine transport (IMDG) UN number: UN proper shipping name: Transport hazard class(es): Packing group: Air transport (ICAO-TI/IATA-DGR) UN number: UN proper shipping name: Transport hazard class(es): Packing group: Environmental hazards ENVIRONMENTALLY HAZARDOUS: no

8 Page 8 of Special precautions for user Transport in bulk according to Annex II of Marpol and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulatory information 2004/42/EC (VOC): 0,0 Additional information To follow: 850/2004/EC, 79/117/EEC, 689/2008/EC National regulatory information Employment restrictions: Water contaminating class (D): Observe restrictions to employment for juvenils according to the 'juvenile work protection guideline' (94/33/EC). 2 - water contaminating Chemical safety assessment For the following substances of this mixture a chemical safety assessment has been carried out: white mineral oil (petroleum) SECTION 16: Other information Changes section 1, 2, 3, 7, 11, 16 Abbreviations and acronyms ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service LC50: Lethal concentration, 50% LD50: Lethal dose, 50% Relevant H and EUH statements (number and full text) H304 May be fatal if swallowed and enters airways. H318 Causes serious eye damage. Further Information The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)