GHS SAFETY DATA SHEET

Transcription

1 GHS SAFETY DATA SHEET 1 - Identification Product identifier Other means of identification Synonym(s) Recommended use Recommended restrictions Issue date Company identification AnJET TM 2050N Food grade ink Inkjet Printing None Known. 22-March-2017 MYLAN GROUP Long Duc Industrial Park Tra Vinh City, Tra Vinh Province, Vietnam Tel Fax Hazard(s) identification Physical hazards Flammable liquids. Category 3 Health hazards OSHA hazard(s) Not classified. Not classified. Label elements Signal word Hazard statement Warning H226- Flammable liquid and vapor. Precautionary statement Prevention Response Storage P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P233 - Keep container tightly closed. P240 - Ground/Bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting/equipment. P242 - Use only non-sparking tools. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P370+P378- In case of fire: for small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam to extinguish. For large fires, use water spray, fog, or alcohol-resistant foam to extinguish. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P403 + P235 - Store in a well-ventilated place. Keep cool. Version #: 01 Issue date: 22-Mar-2017 Revision - Page 1 of 8

2 Disposal P501- Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) Environmental hazards Not classified. Not classified. 3 - Composition/information on ingredients Mixtures Chemical name CAS Number % Water >60 Ethanol <20 Glycerol <5 Food grade dye mixture Proprietary <10 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/ effects, acute and delayed 5. Fire-fighting measures FLASH POINT: Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Move person to fresh air immediately. If symptoms persist, get immediate medical attention. In case of contact, immediately remove contaminated clothing and flush skin with copious amounts of water. Wash clothing separately before reuse. Get medical attention, if needed. In case of eye contact, remove contact lens and rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention immediately. Rinse mouth out with water. If the material is swallowed, get immediate medical attention or advice -- Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention immediately. See section o C Suitable extinguishing media: sand, carbon dioxide (CO2) or dry chemical. Not applicable. Firefighters should wear full protective clothing including self-contained breathing apparatus. Avoid run off into storm sewers and ditches which lead to waterways. Move containers from fire area if you can do it without risk. Version #: 01 Issue date: 22-Mar-2017 Revision - Page 2 of 8

3 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat, sparks and flame. Components Type Value Ethanol (CAS ) PEL 1900 mg/m 3 US. ACGIH Threshold Limit Values 1000 ppm Components Type Value Ethanol (CAS ) STEL 1000 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Ethanol (CAS ) TWA 1900 mg/m ppm Biological limit values Appropriate engineering controls Individual protection measures, such as personal protective equipment Eye/face protection Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations No biological exposure limits noted for the ingredient(s). When using, do not eat, drink or smoke. Wash hands after handling the product. Version #: 01 Issue date: 22-Mar-2017 Revision - Page 3 of 8

4 9. Physical and chemical properties Appearance Odor Odor threshold ph Melting point/freezing point; Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Brown liquid. >70 o C 35 o C Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies) Partition coefficient: n- octanol/water Auto-ignition temperature Decomposition temperature Viscosity at 25 o C (cps) Specific Gravity Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Stable at normal conditions. None known. Version #: 01 Issue date: 22-Mar-2017 Revision - Page 4 of 8

5 Incompatible materials Hazardous decomposition products 11. Toxicological information Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity value Components Species Test results Ethanol (CAS ) Acute Inhalation LC50 Oral LD50 Other LD50 Skin corrosion/irritation Mouse Rat Dog Guinea pig Mouse Rat Mouse Rat 39 mg/l, 4 Hours mg/l, 10 Hours 5.5 g/kg 5.6 g/kg Mouse 3450 mg/kg Rat 7060 mg/kg 6.2 g/kg 933 mg/kg 1440 mg/kg Serious eye damage/eye irritation Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Specific target organ toxicity - single exposure Eye Contact: Inhalation: Ingestion: Specific target organ toxicity - repeated exposure Aspiration hazard 12. Ecological information Aquatic toxicity Eco toxicity Version #: 01 Issue date: 22-Mar-2017 Revision - Page 5 of 8

6 Components Species Test Results Ethanol (CAS ) Aquatic Crustacea EC50 Water flea (Daphnia magna) mg/l, 48 hours Fish LC50 Fathead minnow (Pimephales promelas) > 100 mg/l, 96 hours Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) Ethanol (CAS ) Mobility in soil Other adverse effects 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information Not regulated. DOT UN number UN proper shipping name UN1210 Printing ink, flammable (Ethanol) Transport hazard class(es) 3 Subsidiary class(es) Packing group Special precautions for user Labels required III IATA UN number UN proper shipping name UN1210 Printing ink, flammable (Ethanol) Version #: 01 Issue date: 22-Mar-2017 Revision - Page 6 of 8

7 Transport hazard class(es) 3 Subsidiary class(es) Packaging group Environmental hazards Labels required ERG Code Special precautions for user III IMDG UN number UN proper shipping name UN1210 Printing ink, flammable (Ethanol) Transport hazard class(es) 3 Subsidary class(es) Packaging group Environmental hazards Marine pollutant Labels required EmS Special precautions for user III Section 15 - Regulatory Information US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) US. OSHA Specifically Regulated Substances (29 CFR ) CERCLA Hazardous Substance List (40 CFR 302.4) US EPA TSCA Inventory: All chemical substances in this product comply with all rules or orders under TSCA. Not regulated. Not on regulatory list. Not on regulatory list. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard No. Delayed Hazard No. Fire Hazard Yes. Pressure Hazard No. Version #: 01 Issue date: 22-Mar-2017 Revision - Page 7 of 8

8 Reactivity Hazard No. SARA 302 Extremely hazardous substance No. SARA 311/312 Hazardous chemical No. US state regulations US. Massachusetts RTK - Substance List US. New Jersey Worker and Community Right-to-Know Act US. Pennsylvania RTK - Hazardous Substances Ethanol (CAS ) Not on regulatory list. Ethanol (CAS ) US. Rhode Island RTK Ethanol (CAS ) US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Not on regulatory list. Section 16 - Other Information Issue date 22-March-207 Revision date - Version # 01 Disclaimer This Safety Data Sheet document is provided without charge to customers of Mylan Group. Data is the most current known to Mylan Group at the time of preparation of this document and is believed to be accurate. My Company makes no warranty of any kind, express or implied, concerning the safe use of this material in your process or in combination with other substances. This document was prepared to the requirements of the jurisdiction specified in Section 1 above and may not meet regulatory requirements in other countries. Version #: 01 Issue date: 22-Mar-2017 Revision - Page 8 of 8