SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier

Transcription

1 JOSTCOTE Microencapsulated Ferrous Sulfate 60% Date of issue: 7/23/2018 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : EC-No. : CAS-No. : Formula : FeSO 4 xh 2O 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture Uses advised against 1.3. Details of the supplier of the safety data sheet Manufacturer Jost Chemical Co Lackland Rd Saint Louis, Missouri T F sds@jostchemical.com Emergency telephone number Emergency number : Nutrient; Dietary Supplement Distributor JOST CHEMICAL EUROPE SPRL rue du Bois Portal n 30/1-3 B Andenne - BELGIQUE T F info@jostchemical.com : For Hazardous Materials [or Dangerous Goods] Incident Spill, Leak, Fire, Exposure, or Accident Call CHEMTREC Day or Night United States and Canada: / Global: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Directive 67/548/EEC or 1999/45/EC No labelling applicable 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to Directive 67/548/EEC JOSTCOTE Microencapsulated Ferrous Sulfate 60% (CAS-No.) (EC-No.) Ferrous Sulfate RM (CAS-No.) (EC-No.) (EC Index-No.) Full text of R- and H-statements: see section 16 Classification according to Regulation (EC) No. 1272/2008 [CLP] 100 Not classified Not classified 60 Not classified Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Eye Irrit. 2, H319 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Call a poison center or a doctor if you feel unwell. EN (English) 1/6

2 First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention. : Rinse eyes with water as a precaution. : Rinse mouth. Call a poison center or a doctor if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms/effects : Not expected to present a significant hazard under anticipated conditions of normal use. Symptoms/effects after skin contact Symptoms/effects after eye contact Symptoms/effects after ingestion : May cause skin irritation. : Irritation. : Diarrhea Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam Special hazards arising from the substance or mixture Fire hazard : Carbon oxides (CO, CO2). Toxic fumes. Explosion hazard Hazardous decomposition products in case of fire 5.3. Advice for firefighters Protection during firefighting : No direct explosion hazard. : Toxic fumes may be released. : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures : Ventilate spillage area. Avoid contact with skin and eyes For emergency responders Protective equipment 6.2. Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up : Mechanically recover the product. Other information 6.4. Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". : Dispose of materials or solid residues at an authorized site. : Ensure good ventilation of the work station. Avoid contact with skin and eyes. Wear personal protective equipment. : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Technical measures : Does not require any specific or particular technical measures. Storage conditions 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls: Ensure good ventilation of the work station. Personal protective equipment: Dust production: dust mask with filter type P2. Gloves. Safety glasses. Hand protection: Protective gloves : Store in a well-ventilated place. Keep cool. 7/23/2018 (Version: 1.0) EN (English) 2/6

3 Eye protection: Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment Personal protective equipment symbol(s): Environmental exposure controls: Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance Molecular mass Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) : Powder. : g/mol : white. Melting point : 60 C Freezing point Boiling point : 280 C Flash point : Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information : Non flammable. : Insoluble in water. SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. 7/23/2018 (Version: 1.0) EN (English) 3/6

4 SECTION 11: Toxicological information Information on toxicological effects Acute toxicity ( ) LD50 oral rat 500 mg/kg bodyweight (OECD 423: Acute Oral Toxicity Acute Toxic Class Method, Rat, Female, Read-across) LD50 oral rat 500 mg/kg bodyweight (OECD 423: Acute Oral Toxicity Acute Toxic Class Method, Rat, Female, Read-across) Irritation Corrosivity Sensitisation Repeated dose toxicity Carcinogenicity Mutagenicity Toxicity for reproduction SECTION 12: Ecological information Toxicity Ecology - general Dangerous for the environment Chronic aquatic toxicity : The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment. ( ) LC50 fish 1 EC50 Daphnia 1 ErC50 (algae) > 100 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Oryzias latipes, Semi-static 91 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Semistatic 130 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata, Static LC50 fish 1 EC50 Daphnia 1 ErC50 (algae) Persistence and degradability > 100 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Oryzias latipes, Semi-static 91 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Semistatic 130 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata, Static Persistence and degradability Biodegradability in water: no data available Bioaccumulative potential ( ) BCF fish (OECD 305: Bioconcentration: Flow-Through Fish Test, 28 day(s), Cyprinus carpio, Flow-through system, Fresh water, Experimental value, Heptahydrate) BCF fish (OECD 305: Bioconcentration: Flow-Through Fish Test, 28 day(s), Cyprinus carpio, Flow-through system, Fresh water, Experimental value, Heptahydrate) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500) Mobility in soil Ecology - soil No (test)data on mobility of the substance available. 7/23/2018 (Version: 1.0) EN (English) 4/6

5 12.5. Results of PBT and vpvb assessment Component Other adverse effects This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII SECTION 13: Disposal considerations Waste treatment methods Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) UN-No. (IMDG) UN-No. (IATA) UN-No. (ADN) UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information Special precautions for user Overland transport Transport by sea Air transport Inland waterway transport Rail transport : Not regulated for transport : Not regulated for transport : No : No : No supplementary information available 7/23/2018 (Version: 1.0) EN (English) 5/6

6 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances Directive 2012/18/EU (SEVESO III) National regulations Listed on the United States TSCA (Toxic Substances Control Act) inventory Not subject to reporting requirements of the United States SARA Section 313 Listed on the Canadian DSL (Domestic Substances List) Chemical safety assessment SECTION 16: Other information Indication of changes: Initial SDS. Full text of R-, H- and EUH-statements: Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 H302 H315 H319 Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 7/23/2018 (Version: 1.0) EN (English) 6/6