According to 1907/2006/EC, Article 31 Version: 2 Printing date: 7/30/2013 Revision: 7/30/2013

Transcription

1 Page 1/8 SECTION 1: Identification of the Substance/Mixture and of the Company/Undertaking 1.1 Product identifier CAS Number: EC Number: Relevant identified uses of the substance or mixture and uses advised against: No further relevant information available. Application of the substance/ the preparation: Cosmetic raw material 1.3 Details of the supplier of the safety data sheet Supplier/Manufacturer: Peter Cremer North America 3117 Southside Avenue Cincinnati, OH USA Tel: (513) Toll: (877) Fax: (513) Information department: See supplier/manufacturer 1.4 Emergency telephone number: CHEMTREC: (US and Canada) (For calls originating elsewhere) SECTION 2: Hazards Identification 2.1 Classification of the substance or mixture Classification according to Directive 67/548/EEC or Directive 1999/45/EC: Not applicable Information concerning particular hazards for human and environment: Based on the calculation method of Directive 1999/45/EC, the mixture is not subject to labeling. Classification system: The classification complies with current legislature, but is supplemented with information from technical literature and company information. 2.2 Label Elements Labeling according to EU guidelines: Observe the general safety regulations when handling chemicals. The mixture is not subject to labeling according to Directive 1999/43/EC and the Hazardous Substances Ordinance. 2.3 Other Hazards Results of PBT and vpvb assessment: o PBT: Not applicable o vpvb: Not applicable

2 Page 2/8 SECTION 3: Composition/Information on Ingredients 3.1 Chemical characterization: Mixtures Description: Mixture of the substances listed below with nonhazardous additions. Dangerous components: o CAS: glycerol o EINECS: substance with a Community workplace exposure limit Additional information: For the wording of the listed risk phrases refer to section 16. SECTION 4: First-Aid Measures 4.1 Description of first aid measures General information: If symptoms persist or in case of doubt, seek medical advice. Change soiled clothing. After inhalation: Supply fresh air; consult a doctor in case of pain. After skin contact: Rinse with plenty of water. Generally the product does not irritate the skin. After eye contact: Rinse opened eyes for several minutes under running water. If symptoms persist, consult a doctor. After swallowing: Drink water or milk. If symptoms persist, consult a doctor. 4.2 Most important symptoms and effects, both acute and delayed: After the uptake of large quantities: gastric or intestinal disorders. 4.3 Indication of any immediate medical attention and special treatment needed: Symptomatic treatment SECTION 5: Firefighting Measures 5.1 Extinguishing media Suitable extinguishing agents: o The product is not combustible and does not support any combustion. o Carbon dioxide (CO 2). o Fire-extinguishing powder. o Foam. o Use fire fighting measures that suit the environment. For safety reasons unsuitable extinguishing agents: High volume water jet. 5.2 Special hazards arising from the substance or mixture: In case of fire, the following can be released: o Carbon monoxide and carbon dioxide 5.3 Advice for firefighters Protective equipment: Wear self-contained respiratory protective device. Additional Information: Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Collect contaminated fire fighting water separately. It must not enter the sewage system.

3 Page 3/8 SECTION 6: Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures: o Keep away from water and humidity. o Product forms slippery surface when combines with water. o Avoid contact with eyes. 6.2 Environmental precautions: o Do not allow product to reach sewage system or any water course. o Do not allow to penetrate the ground/soil. 6.3 Methods and material for containment and cleaning up: o Pick up mechanically. o Make sure to recycle or dispose of in suitable receptacles. o Dispose contaminated material as waste according to item Reference to other sections: No dangerous substances are released. SECTION 7: Handling and Storage 7.1 Precautions for safe handling: Avoid contact with eyes. Information about protection against explosions and fires: Observe the general rules of industrial fire protection. 7.2 Conditions for safe storage, including any incompatibilities Requirements to be met by storerooms and receptacles: Store at ambient temperatures and under dry conditions. Information about storage in one common storage facility: o Store away from foodstuffs. o Store away from feed. o Store away from oxidizing agents. Further information about storage conditions: None. Storage Class: other combustible and non-combustible substances. 7.3 Specific end use(s): No further relevant information available.

4 Page 4/8 SECTION 8: Exposure Controls and Personal Protection 8.1 Control parameters Additional information about design of technical systems: No further data; see item 7. Components with limit values that require monitoring at the workplace: glycerol WEL (Great Britain) Long-term value: 10mg/m 3 Additional information: The lists that were valid during the creation were used as basis. 8.2 Personal protection General protective and hygienic measures: o The usual precautionary measures should be adhered to when handling chemicals. o Avoid contact with eyes. Breathing equipment: not required. Protection of hands: o At longer contact: protective gloves. o The glove material has to be impermeable and resistant to the product/substance/preparation. o Due to missing tests no recommendation to the glove material can be given for the product/preparation/chemical mixture. o Selection of the glove material in consideration of the penetration times, rates of diffusion and the degradation. Material of gloves: o For un-dissolved solid substances the following materials may be suitable: Nitrate rubber (NBR), butyl o rubber (BR), fluorocarbon rubber (FKM) and polychloroprene rubber (CR). The selection of suitable gloves depends upon the material and quality of the gloves. The degree of protection will vary from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material cannot be calculated in advance and therefore has to be checked prior to the application. Penetration time of glove material: The exact penetration time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Safety glasses. Body protection: Protective work clothing.

5 Page 5/8 SECTION 9: Physical and Chemical Properties 9.1 Information on basic physical and chemical properties General Information: Appearance: o Form: Pellets o Color: White o Odor: Fat-like ph-value: Not applicable Change in condition: Melting point/melting range: Boiling point/boiling range: Not determined 343 C Flash point: 300 C Decomposition temperature: Not determined Self ignition temperature: Product is not self-igniting. Danger of explosion: Product does not present an explosion hazard. Vapor pressure: Not applicable Density: g/cm 3 Solubility in/miscibility with water: Soluble Viscosity: o Dynamic: Not applicable o Kinematic: Not applicable 9.2 Other information: No further relevant information available SECTION 10: Stability and Reactivity 10.1 Reactivity No further relevant information available Chemical Stability Thermal decomposition / conditions to be avoided: o To avoid thermal decomposition do not overheat. o No decomposition if used and stored according to specifications Possibility of hazardous reactions: No dangerous reactions known Conditions to avoid: No further relevant information available Incompatible materials: Strong oxidants Hazardous decomposition products: No hazardous decomposition products if instructions for storage and handling are followed.

6 Page 6/8 SECTION 11: Toxicological Information 11.1 Information on toxicological effects LD/LC50 values that are relevant for classification: No toxicity data are available for the product itself. On the skin: No irritating effect. On the eye: Light irritation possible. On respiratory tract: No data available. Sensitization: No sensitizing effects known. Carcinogenic, mutagenic effects and adverse effects on reproduction: No data available. Additional toxicological information: o The product is not subject to classification according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version. o When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us. SECTION 12: Ecological Information 12.1 Toxicity Aquatic toxicity: Presently there are no ecotoxicological values available Persistence and degradability: No further relevant information available. Other information: o The product is easily biodegradable Bio-accumulative potential: No product has not been tested Mobility in soil: No further relevant information available. General notes: o Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. o Danger to drinking water is possible if large quantities leak into the ground or into water course Results of PBT and vpvb assessment: PBT: Not applicable vpvb: Not applicable 12.6 Other adverse effects: No further relevant information available. SECTION 13: Disposal Considerations 13.1 Waste treatment methods Recommendation: Disposal according to instructions of local authorities Un-cleaned packaging Recommendation: Disposal must be made according to official regulations.

7 Page 7/8 SECTION 14: Transport Information 14.1 UN-Number o ADR, ADN, IMDG, IATA: Void 14.2 UN proper shipping name o ADR, ADN, IMDG, IATA: Void 14.3 Transport hazard class(es) o ADR, ADN, IMDG, IATA o Class: Void 14.4 Packaging group o ADR, ADN, IMDG, IATA: Void 14.5 Environmental hazards: o Marine pollutant: No 14.6 Special precautions for user: Not applicable 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: SECTION 15: Regulatory Information Not applicable 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

8 Page 8/8 SECTION 16: Other Information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Reasons for amendments: o Layout o Information Section 1, 5, 9, 10 o Storage class o Information on toxicity Replaces version dated: 12/7/2011 Department issuing MSDS: Peter Cremer North America 3117 Southside Avenue Cincinnati, OH USA Tel: (513) Toll: (877) Fax: (513) Contact: Sarah Keyes Abbreviations and acronyms: o ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road. o RID: Regulations Concerning the International Transport of Dangerous Goods by Rail. o IMDG: International Maritime Code for Dangerous Goods. o IATA: International Air Transport Association. o GHS: Globally Harmonized System of Classification and Labeling of Chemicals. o CAS: Chemical Abstracts Service (Division of the American Chemical Society). o LC50: Lethal concentration, 50 percent. o LD50: Lethal dose, 50 percent. Sources: MSDS of the supplier