: ERADICOAT. Safety Data Sheet Date of issue: 01/12/2016 Revision date: 01/12/2016 : Version: 3.0

Transcription

1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name. Product code Type of formulation Active ingredient : : CE 00 C0056 : Soluble concentrate (SL) : Maltodextrin 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Use of the substance/mixture : Plant protection product for professional use. Agriculture. : Insecticide Uses advised against 1.3. Details of the supplier of the safety data sheet CERTIS UK Suite 5, 3 Riverside Granta Park Great Abington Cambridgeshire CB21 6AD United Kingdom Tel: +44 (0) Fax: +44 (0) certis@certiseurope.co.uk Website: Emergency telephone number Emergency number : Certis Carechem24 multilingual 24 hours emergency number: +44 (0) For advice on medical emergencies, fires, spillages or chemical hazards only phone: For further advice for medical professionals - The National Poisons Information Service: Tel: (UK only) or Dublin Tel: / For further advice for veterinary surgeons: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Eye Irrit. 2 H319 Aquatic Chronic 3 H412 Full text of H-phrases: see section 16 01/12/2016 EN (English) 1/7

2 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : GHS07 Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) : Warning : H319 - Causes serious eye irritation. H412 - Harmful to aquatic life with long lasting effects. : P264 - Wash hands thoroughly after handling P280 - Wear protective gloves, protective clothing, eye protection/face protection P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 - If eye irritation persists: Get medical advice/attention. P501 - Dispose of contents/container to a licensed hazardous-waste disposal contractor or collection site except for empty clean containers which can be disposed of as non-hazardous waste. EUH phrases : EUH401 - To avoid risks to human health and the environment, comply with the instructions for use Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances Mixture Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Maltodextrin (CAS No.) <50 Not classified. Surfactant CDG (CAS No) mixture <3 Skin Irrit. 2, H315 Eye Dam. 1, H318 Aquatic Chronic 2, H411 BH30 (CAS No) <2 Eye Irrit. 2, H319 Full text of H- and EUH-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact : IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. : IF ON SKIN: Wash with plenty of soap and water. : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. First-aid measures after ingestion : Wash out mouth with plenty of water Most important symptoms and effects, both acute and delayed 01/12/2016 EN (English) 2/7

3 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Dry chemical powder. Alcohol resistant foam. Carbon dioxide (CO 2) Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions : Exercise caution when fighting any chemical fire. Fight fire from safe distance and protected location. Cool closed containers exposed to fire with water spray. If possible, take the containers out of dangerous zone. Contain fire-fighting water with dikes or absorbents to prevent migration and entry into sewers or streams. Protection during firefighting : Wear suitable protective clothing, gloves, eye/face protection and respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Protective equipment Emergency procedures : Wear suitable protective clothing, gloves and eye or face protection. : Evacuate area. Ensure adequate ventilation. Avoid direct contact with the substance. Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams Environmental precautions 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Clean up any spills as soon as possible, using an absorbent material to collect it. Once absorbed collect spilled material with shovels, buckets and place in closed containers and label properly. Remove as chemical waste, according to national or local legislation. In the event of major spillage: Contact an expert Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Read label before use. Wear personal protective equipment. Wear eye/face protection. 01/12/2016 EN (English) 3/7

4 Hygiene measures : Always wash your hands immediately after handling this product, and once again before leaving the workplace. Do no eat, drink or smoke when using this product Conditions for safe storage, including any incompatibilities Storage conditions : Keep locked up and out of the reach of children. Keep away from food, drink and animal feeding stuffs. Keep in original containers, tightly closed Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Personal protective equipment : Protective clothing. Gloves. Protective goggles. Materials for protective clothing : Chemical resistant protective clothing. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid. Colour : Gold. Odour Odour threshold ph : 6,0 10 Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point : Not flash to boiling. Auto-ignition temperature : 437 C Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density : 1.23 ±0.01 (20 C ± 0.5 C) Density Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic : to Pa.s Explosive properties Oxidising properties : No oxidising properties. Explosive limits 01/12/2016 EN (English) 4/7

5 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Maltodextrin LD 50 oral rat LD 50 dermal rat LC 50 inhalation rat Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard > 2000 mg/kg > 2000 mg/kg > 5.16 mg/l/4h (Non irritant to skin - maltodextrin) : Causes serious eye irritation. : May produce an allergic reaction (maltodextrin) SECTION 12: Ecological information Toxicity Persistence and degradability Bioaccumulative potential Bioaccumulative potential Biodegradable Mobility in soil 01/12/2016 EN (English) 5/7

6 12.5. Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods SECTION 14: Transport information In accordance with ADR / RID / ADNR / IMDG / ICAO / IATA UN number No dangerous good in sense of transport regulations UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Other information : No supplementary information available Special precautions for user Overland transport Transport by sea Air transport Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions Contains no REACH candidate substance National regulations Chemical safety assessment SECTION 16: Other information Change date Previous Version Section Changed Item Change Comments 12/03/ ph, Flash point, Self ignition temperature, Relative density, Viscocity, Oxidising properties, Modified. 14/10/ DSD label elements Added 04/12/ H317 Added UK RA proposal 05/03/ P305 + P351 + P338 Added UK RA (MG) proposal. 01/12/2016 EN (English) 6/7

7 P337 + P Coconut Diethanolamide, Dietalonamine, Sodium Alkylamine dicaroxylate Specified UK RA (MG) proposal. 17/03/ P501 Added Ireland request 12/01/ H317 Removed EU was accepted in UK. According to EU version H412 Added /12/ ph: Modified According to new data production. Full text of H- and EUH-phrases: Aquatic Chronic 2 Hazardous to the aquatic environment Chronic Hazard, Category 2 Aquatic Chronic 3 Hazardous to the aquatic environment Chronic Hazard, Category 3 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 H315 H318 H319 H411 H412 Causes skin irritation Causes serious eye damage Causes serious eye irritation Toxic to aquatic life with long lasting effects Harmful to aquatic life with long lasting effects This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. 01/12/2016 EN (English) 7/7