ACCLAIM SUPER EC MSDS Version 1.1

Transcription

1 SECTION 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product Name ACCLAIM SUPER EC Chemical Name Synonym MSDS Number 263 Chemical Family Chemical Formulation EPA Registration No. Canadian Registrat. No Bayer CropScience Inc # th Avenue SE Calgary, AB T2Z 3X2 Canada Emergency Number (24 Hours/Day): Product Information: Product Use Description Herbicide. SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS Component Name CAS No. Concentration % by Weight Minimum Maximum Fenoxaprop-p-ethyl >= Inert ingredients >= <= SECTION 3. HAZARDS IDENTIFICATION NOTE: Please refer to Section 11 for detailed toxicological information. Emergency Overview May cause irritation to eyes, nose, throat and skin. Do not allow product to contaminate water because it is toxic to fish. Odor Appearance Routes of Exposure Immediate Effects Chronic or Delayed Long-Term Aromatic Pale yellow Liquid Inhalation, ingestion and may be absorbed through skin contact. CARCINOGENIC: This product is not considered to be carcinogenic and the ingredients are not listed by OSHA, IARC or NTP. Page 1 of 6 Bayer CropScience Inc

2 SECTION 4. FIRST AID MEASURES Eye Immediately wash eye with water for at least 15 minutes. Get medical attention immediately. Skin Remove soiled clothes and wash skin with soap and water for at least 15 minutes. Wash soiled clothes separately from other articles before wearing again. Ingestion Inhalation Note to Physician If swallowed, DO NOT INDUCE VOMITING. Get immediate medical attention. Take this MSDS and the original container well closed with you (if possible). In cases of difficult breathing, remove to fresh air. If not breathing, give artificial respiration and get medical attention immediately. In the event of large amounts being ingested, the following measures should be considered: Monitor function of kidney, liver and red blood count. Gastric lavage, charcoal administration and elimination by dialysis. SECTION 5. FIRE FIGHTING MEASURES Flash Point CLOSED CUP: 72± 2 C Suitable Extinguishing Media Fire Fighting Instructions Water, water mist, foam or dry chemical. Use water spray to cool off fire exposed surfaces and to protect personnel. Firefighters should wear self-contained breathing apparatus. Prevent fire run-off from entering streams or lakes. SECTION 6. ACCIDENTAL RELEASE MEASURES Land Spill or Leaks Wear appropriate protective equipment for spill clean-up. SMALL SPILL: Absorb with sand or other non-combustible material like clay or kitty litter. LARGE SPILL: Dike up and contain the spill in appropriate recovery containers. Absorb rest with sand, earth or clay. Decontaminate the area and used equipment with laundry bleach (Javex) or hydrated lime. SECTION 7. HANDLING AND STORAGE Handling Procedures Wear suitable protective clothing, rubber gloves, pesticide approved respirator and eye protection when handling this product. Page 2 of 6

3 Storing Procedures Store in a cool (10-27 C), well ventilated area. Keep containers tightly closed when not in use. Do not handle or store near flame, heat or strong oxidants. Do not store or transport with food, feed, seed, or fertilizer. Do not use polyethylene plastic containers for storage. Keep out of reach of children. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION General Protection When spraying, wear clean, well fitted goggles, pesticide approved respirator, protective clothing and gloves. Do not eat, drink or smoke when handling this product. Wash your hands, before eating, drinking, smoking or before touching anything or anyone. See handling and Work Practices, section 7. Exposure Limits ACGIH TLV FENOXAPROP-P-ETHYL TWA: N/E STEL: N/E SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Odor Pale yellow Liquid Aromatic ph at 3.0 TO 5.0 at 110 g/l water Density Solubility (in water) 1.01 ± 0.05 Kg/L Miscible in water SECTION 10. STABILITY AND REACTIVITY Chemical Stability Incompatibility Hazardous Products of Decomposition Stable. Avoid strong oxidizing agents, acids and bases. Thermal decomposition may produce toxic smoke, including carbon monoxide and carbon dioxide. Page 3 of 6

4 Hazardous Polymerization (Conditions to avoid) Will not occur. SECTION 11. TOXICOLOGICAL INFORMATION Acute Oral Toxicity Acute Dermal Toxicity Acute Inhalation Toxicity Skin Irritation Eye Irritation LD50 : 3355 mg/kg (rat) formulated product LD50 :>2000 mg/kg (rat) formulated product LC50 : 3920 mg/kg (rat) formulated product slightly irritant (rabbit) moderately irritant (rabbit) Assessment Carcinogenicity ACGIH NTP IARC OSHA SECTION 12. ECOLOGICAL INFORMATION Ecological Information The product is toxic to fish. As with all crop protection products it should not be allowed to enter any body of water. Do not feed treated plants (crop of underseeded legumes) to live stock SECTION 13. DISPOSAL CONSIDERATIONS General Disposal Guidance Dispose in accordance with local regulations (eg. Government approved incinerator). Mixing with strong alkali like lime or caustic soda speeds up degradation. Empty containers should be TRIPLE RINSED and destroyed in a manner approved by the Provincial Ministry of Environment. DO NOT RE-USE empty containers. RCRA Classification SECTION 14. TRANSPORT INFORMATION DOT/TDG : Not regulated for transport. Page 4 of 6

5 SECTION 15. REGULATORY INFORMATION This is a registered Canadian Pest Control product. PCP# US Federal EPA Registration No. TSCA list TSCA 12b export notification SARA Title III - section notification and information SARA Title III - section toxic chemical release reporting US States Regulatory CA Prop65 This product does not contain any substances known to the State of California to cause cancer. This product does not contain any substances known to the State of California to cause reproductive harm. US State right-to-know ingredients Canadian Regulations Canadian Registrat. No Canadian Domestic Substance List Environmental CERCLA Clean Water Section 307 Priority Pollutants Safe Drinking Water Act Maximum Contaminant Levels International Regulations EU Classification European Inventory of Existing Commercial Substances (EINECS) Page 5 of 6

6 SECTION 16. OTHER INFORMATION Prepared by : The HSE Department of Bayer CropScience Inc. Phone : (306) Approval Date: This information is provided in good faith but without express or implied warranty. Buyer assumes all responsibility for safety and use not in accordance with label instructions. The product names are registered trademarks of Bayer AG. Bayer CropScience Inc Page 6 of 6