MATERIAL SAFETY DATA SHEET

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1 1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product identifier Product: Synonyms: CELMITRON 70% WDG (UK: MAPP 14408) Type: Formulated product 1.2 Relevant identified uses of the substance or mixture and uses advised against herbicide 1.3 Details of the supplier of the safety data sheet Name: AgriChem B.V. Address: Koopvaardijweg 9 Postal code: 4906 CV Residence: Oosterhout Country: the Netherlands Telephone no: (++ 31) (0) Fax no: (++ 31) (0) info@agrichem.com 1.4 Emergency telephone number In case of poisoning contact national or local poison information centre (London telephone no ) 2 HAZARDS IDENTIFICATION 3 COMPOSITION/INFORMATION ON INGREDIENTS Name 1: METAMITRON 2: SURFACTANT S10-01 CAS no EINECS no REACH Reg. No Percentage Labeling R phrases (1) H phrases (1) Xn;N Xn H302-H400 (1) Complete text of R/H phrases: see chapter 16 Date of conversion: 13-nov /5 Print date: 13-Nov-12

2 4 FIRST AID MEASURES 4.1 Description of first aid measures CONTACT WITH SKIN Wash with water and soap. In case of symptoms, contact a doctor and show the label or packaging. CONTACT WITH EYES Rinse with plenty of water for at least 10 minutes. Flush away from the non-contaminated eye. In case of contact lenses: if these can be removed easily, remove lenses first and rinse afterwards. Consult an eye doctor immediately and show the label or the packaging. INHALATION Fresh air, rest. Take victim to a doctor if irritation persists. INGESTION Half-upright sitting position. Consult a doctor immediately. Doctor: gastric lavage. 4.2 Most important symptoms and effects, both acute and delayed 4.3 Indication of any immediate medical attention and special treatment needed Contact the Poisons information centre for further treatment in the hospital. 5 FIREFIGHTING MEASURES Non flammable. 5.1 Extinguishing media 5.2 Special hazards arising from the substance or mixture 5.3 Advice for firefighters 6 ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Protective clothing. Face-shield/safety glasses. Gloves. 6.2 Environmental precautions Prevent soil and water pollution. 6.3 Methods and material for containment and cleaning up Scoop spill into closing containers. Date of conversion: 13-nov /5 Print date: 13-Nov-12

3 7 HANDLING AND STORAGE 7.1 Precautions for safe handling Do not discharge the waste into the drain. 7.2 Conditions for safe storage, including any incompatibilities Store in original packaging. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters Legal limit value TWA 8 h: comp. ppm comp. mg/m3 8.2 Exposure controls Face shield. Gloves. Protective clothing. 9 PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Form: Odour: Colour: Solid aromatic odour On exposure to air: light brown 9.2 Other information (EN L 133/22 Official Journal of the European Union ) ph value: % dilution Flash point/flammability: Not applicable Relative density: 0.73 g/ml Solubility: Water miscible Viscosity: Not applicable Surface tension: 10 STABILITY AND REACTIVITY 10.1 Reactivity 10.2 Chemical stability 10.3 Possibility of hazardous reactions 10.4 Conditions to avoid Stable under normal conditions Incompatible materials oxidizing agents. Date of conversion: 13-nov /5 Print date: 13-Nov-12

4 10.6 Hazardous decomposition products Can decompose at high temperatures forming toxic gases. 11 TOXICOLOGICAL INFORMATION LD50 oral rat: LD50 dermal rat: LD50 dermal rabbit: LC50 inhalation rat: >2000 mg/kg b.w. > 2000 mg/kg bw > mg/l air 12 ECOLOGICAL INFORMATION Toxicity LC50 (for fish): EC50 (for crustacea): ErC50 (for algae): Acute aquatic hazard: 1 Chronic aquatic hazard: Oral toxicity bees: Dermal toxicity bees: LD50 birds: Not toxic to bees 12.2 Persistence and degradability 12.3 Bioaccumulative potential 12.4 Mobility in soil 12.5 Results of PBT and vpvb assessment 12.6 Other adverse effects 13 DISPOSAL CONSIDERATIONS Dispose of in accordance with local regulations.. Use appropriate containment to avoid environmental. Do not discharge into surface water Waste treatment methods Date of conversion: 13-nov /5 Print date: 13-Nov-12

5 14 TRANSPORT INFORMATION Hazard identification: UN no: 3077 UN name: Road Environmentally hazardous substance, solid, n.o.s.metamitron Class: 9 Group: III Marine pollutant: Y EMS number: Label : 15 REGULATORY INFORMATION Dangerous for the environment Risk phrases: Safety phrases: S(1/2) (Keep locked up and out of the reach of children) S13 Keep away from food, drink and animal feeding stuffs S20/21 When using do not eat, drink or smoke S35 This material and its container must be disposed of in a safe way S57 Use appropriate containment to avoid environmental contamination 16 OTHER INFORMATION The complete text of the R phrases mentioned in chapter 3: R22 R36 Harmful if swallowed Irritating to eyes The complete text of the H phrases mentioned in chapter 3: H302 H400 Harmful if swallowed. Very toxic to aquatic life. The information in this MSDS is to the best of our knowledge true and accurate, but all instructions, recommendations and suggestions are made without guarantee. We can accept no liability for loss or damage suffered from use of this information. Furthermore no liability is accepted if use of any product in accordance with these instructions, recommendations and suggestions infringes any patent. Date of conversion: 13-nov /5 Print date: 13-Nov-12