: VIM Power & Shine Antibacterial Spray

Transcription

1 Date of issue: 10/18/2017 SECTION 1: Identification 1.1. Product identifier Product form : Mixture Trade name : Product code : Recommended use and restrictions on use Recommended use : Commercial,Industrial 1.3. Supplier Unilever Canada Inc. Address 160 Bloor Street East, Suite 1400, Toronto, Ont. CANADA M4W 3R Emergency telephone number Emergency number : PROSAR or call local Poison Information Centre. SECTION 2: Hazard identification 2.1. Classification of the substance or mixture Classification (GHS-CA) Not classified 2.2. GHS Label elements, including precautionary statements GHS-CA labeling No labeling applicable 2.3. Other hazards 2.4. Unknown acute toxicity (GHS-CA) No data available SECTION 3: Composition/Information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification (GHS-CA) Water (CAS-No.) Acute Tox. 3 (Oral), H301 Alcohols, C12-15, ethoxylated (CAS-No.) Acute Tox. 4 (Oral), H302 Ethanolamine (CAS-No.) Flam. Liq. 4, H227 Met. Corr. 1, H290 Acute Tox. 4 (Oral), H302 Acute Tox. 3 (Dermal), H311 Skin Corr. 1A, H314 Eye Dam. 1, H318 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion First-aid measures general : If affected person is experiencing breathing difficulty, allow affected person to breathe fresh air. Allow affected person to rest. : If adverse skin reaction occurs, remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. : Never give anything by mouth to an unconscious person. If affected person feels unwell, seek medical advice (show the label where possible) Most important symptoms and effects (acute and delayed) Symptoms/effects : Not expected to present a significant hazard under anticipated conditions of normal use. Potential Adverse human health effects and : Based on available data, the classification criteria are not met. symptoms 10/18/2017 EN (English US) Page 1

2 4.3. Immediate medical attention and special treatment, if necessary SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand Unsuitable extinguishing media 5.3. Specific hazards arising from the hazardous product Fire hazard : Not flammable. Explosion hazard : Product is not explosive Special protective equipment and precautions for fire-fighters Firefighting instructions : Fight fire with normal precautions from a reasonable distance. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not attempt to take action without suitable protective equipment. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.2. Methods and materials for containment and cleaning up Methods for cleaning up : Clear up spills immediately and dispose of waste safely Reference to other sections For further information refer to section 8: "Exposure controls/personal protection" SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Keep container closed to avoid product contamination Conditions for safe storage, including any incompatibilities Storage conditions : Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Ethanolamine ( ) OEL STEL (ppm) OEL TWA (ppm) OEL STEL (mg/m³) OEL TWA (mg/m³) 6 ppm 3 ppm 12 mg/m³ 6 mg/m³ 8.2. Appropriate engineering controls Environmental exposure controls : Avoid release to the environment Individual protection measures/personal protective equipment Personal protective equipment:. Hand protection: Eye protection: Skin and body protection: Respiratory protection: SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear Color : Light green Odor : Fragranced Odor threshold 10/18/2017 EN (English US) 2/6

3 ph : Relative evaporation rate (butyl acetate=1) Relative evaporation rate (ether=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapor pressure Vapor pressure at 50 C Relative density Specific gravity / density Solubility Viscosity, kinematic Explosion limits 9.2. Other information : kg/m³ SECTION 10: Stability and reactivity Reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : None. : Product is stable. : Stable. : Extremely high or low temperatures. : Strong acids. Strong bases. : Smokes. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity (oral). Acute toxicity (dermal) Acute toxicity (inhalation) Water ( ) (Information taken from scientific literature; not specific to this product or its raw materials) > 90 ml/kg Alcohols, C12-15, ethoxylated ( ) (Information taken from scientific literature; not specific to this product or its raw materials) LD50 dermal rabbit 1600 mg/kg 2500 mg/kg 1720 mg/kg LD50 dermal rabbit 1000 mg/kg Polypropylene glycol monobutyl ether ( ) (Information taken from scientific literature; not specific to this product or its raw materials) LD50 dermal rabbit 5840 mg/kg mg/kg Sodium cumenesulfonate ( ) (Information taken from scientific literature; not specific to this product or its raw materials) > 7000 mg/kg 1,2-Benzisothiazol-3(2H)-one ( ) (Information taken from scientific literature; not specific to this product or its raw materials) 1020 mg/kg Poly(dimethylsiloxane) ( ) (Information taken from scientific literature; not specific to this product or its raw materials) > 24 g/kg Skin corrosion/irritation. ph: Serious eye damage/irritation. ph: Respiratory or skin sensitization Germ cell mutagenicity 10/18/2017 EN (English US) 3/6

4 Carcinogenicity Reproductive toxicity Specific target organ toxicity single exposure Specific target organ toxicity repeated exposure Aspiration hazard Potential Adverse human health effects and symptoms Symptoms/effects : Based on available data, the classification criteria are not met. : Not expected to present a significant hazard under anticipated conditions of normal use. SECTION 12: Ecological information Toxicity LC50 fish 1 LC50 fish 2 EC50 Daphnia mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) 3684 mg/l (Exposure time: 96 h - Species: Brachydanio rerio [static]) 65 mg/l (Exposure time: 48 h - Species: Daphnia magna) Persistence and degradability Not established Bioaccumulative potential (at 25 C) 1,2-Benzisothiazol-3(2H)-one ( ) (Information taken from scientific literature; not specific to this product or its raw materials) Mobility in soil 1.3 (at 25 C) (at 25 C) 1,2-Benzisothiazol-3(2H)-one ( ) (Information taken from scientific literature; not specific to this product or its raw materials) 1.3 (at 25 C) Other adverse effects GWPmix comment Other information : No known effects from this product. : Avoid release to the environment. SECTION 13: Disposal considerations Disposal methods Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information Basic shipping description In accordance with TDG - Not regulated for transport Transport information/dot Not regulated for transport Air and sea transport IMDG Not regulated for transport IATA Not regulated for transport SECTION 15: Regulatory information National regulations All ingredients are listed on the Domestic Substances List or are exempt from listing International regulations. SECTION 16: Other information Date of issue : 10/18/ /18/2017 EN (English US) 4/6

5 Data sources : DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This SDS was prepared and is to be used only for this product. If the product is used as a component in another product, this SDS information may not be applicable. Full text of H-phrases listed in Sections 2-15: H227 Combustible liquid H290 May be corrosive to metals H301 Toxic if swallowed H302 Harmful if swallowed H311 Toxic in contact with skin H314 Causes severe skin burns and eye damage H318 Causes serious eye damage 10/18/2017 EN (English US) 5/6

6 SDS Canada (GHS) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 10/18/2017 EN (English US) 6/6