DFF+IPU SC G U-EU 1/6 Version 1 / EU Revision Date: Print Date:

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1 DFF+IPU SC G U-EU 1/6 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product information Trade name DFF+IPU SC G U-EU Product code (UVP) Usage herbicide Company AG Alfred-Nobel-Straße Monheim am Rhein Germany Telefax +49(0) Responsible Department Product Safety and Specification Mgnt +49(0) /3189 (during business hours only) Emergency telephone number +1 (760) (Company 3E for ) 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature Suspension concentrate (=flowable concentrate)(sc) Hazardous components Chemical Name CAS-No. / Symbol(s) R-phrase(s) Concentration [%] EINECS-No. Isoproturon Xn, N R40, R50/53 46, Diflufenican R52/53 5,00 3. HAZARDS IDENTIFICATION Risk advice to man and the environment Limited evidence of a carcinogenic effect. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 4. FIRST AID MEASURES Skin contact Take off contaminated clothing and shoes immediately. Wash off immediately with soap and plenty of water. If symptoms persist, call a physician. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Get medical attention if irritation develops and persists. Ingestion Do NOT induce vomiting. Rinse mouth. If symptoms persist, call a physician. Notes to Physician

2 DFF+IPU SC G U-EU 2/6 Symptoms Systemic:, The absorption of this product into the body may lead to the formation of methaemoglobine that, in sufficient concentration, causes cyanosis., headache, daze Risks Danger of formation of methaemoglobin. Treatment Initial treatment should be symptomatic and supportive. In the event of a mouthful or more being ingested, the following measures should be considered: Monitoring of: cardiac, kidney and red blood cell count. If ingested, irrigate the stomach using activated charcoal in addition. Antidote: Administer 100% oxygen. If methaemoglobin level is greater than 20%, additionally give 1% Methylene Blue/Toluidine Blue solution intravenously at 1-2 ml/kg. Contraindications: alcohol. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media water spray foam carbon dioxide (CO2) dry powder Specific hazards during fire fighting In the event of fire the following can be released: carbon monoxide (CO) hydrogen fluoride nitrogen oxides (NOx) Special protective equipment for fire-fighters Use breathing apparatus. Further information Do not allow run-off from fire fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Environmental Precautions Contain contaminated water and fire fighting water. Do not allow to get into surface water, drains and ground water. Methods for Cleaning Up Recover the product by pumping, suction or absorption using a dry and inert absorbent clay. Collect and transfer the product into a properly labelled and tightly closed container. When picked up, treat material as prescribed in Ch. 13. "Disposal considerations". 7. HANDLING AND STORAGE Handling Advice on safe handling Smoking, eating and drinking should be prohibited in the application area. Storage

3 DFF+IPU SC G U-EU 3/6 Requirements for storage areas and containers Keep container tightly closed in a dry and well-ventilated place. Protect against frost. Advice on common storage Keep away from food, drink and animal feedingstuffs. Storage stability Other data Suitable materials High density polyethylene Do not store at temperature exceeding 50 C. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Personal protective equipment In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the following recommendations would apply. Respiratory Protection No personal respiratory protective equipment normally required. Respiratory protection should only be used to control residual risk of short duration activities, when all reasonably practicable steps have been taken to reduce exposure at source e.g. containment and/or local extract ventilation. Always follow respirator manufacturer's instructions regarding wearing and maintenance. Hand Protection Eye protection Skin and body protection Wear CE Marked (or equivalent) nitrile rubber gloves (minimum thickness 0,40 mm). Wash when contaminated. Dispose of when contaminated inside, when perforated or when contamination outside cannot be removed. Wash hands always before eating, drinking, smoking or using the toilet. Wear goggles conforming to EN166 (Field of Use 5 or equivalent). Wear standard coverall and type 6 suit. Wear two layers of clothing wherever possible. Polyester/cotton or cotton overalls should be worn under chemical protection suit and should be professionally laundered frequently. Protective measures Avoid contact with skin and eyes. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Colour Safety data ph liquid, opaque white 9,1-9,3 at 1 % (24-26 C) suspension in water

4 DFF+IPU SC G U-EU 4/6 ph 8-10 at 1 % Freezing temperature -3 C Flash point Not relevant; aqueous solution Autoignition Temperature 470 C Density approx. 1,1 g/cm³ at 20 C Water solubility Explosivity dispersible Not explosive 92/69/EEC, A.14 / OECD STABILITY AND REACTIVITY Hazardous Reactions No hazardous reactions when stored and handled according to prescribed instructions. Stable under normal conditions. 11. TOXICOLOGICAL INFORMATION Acute Oral Toxicity LD50 (rat) > mg/kg Acute Dermal Toxicity Skin Irritation Eye Irritation Sensitization LD50 (rat) > mg/kg No skin irritation. (rabbit) No eye irritation. (rabbit) Non-sensitizing. (guinea pig) OECD Test Guideline 406, Buehler test Assessment Carcinogenicity A possible carcinogenic effect is indicated at high doses in animal studies on the active substance isoproturon. Further information No data is available on the product itself. Information given is based on data obtained from similar substances. 12. ECOLOGICAL INFORMATION Ecotoxicity effects Toxicity to Fish Toxicity to daphnia LC50 (Rainbow trout (Oncorhynchus mykiss)) 74,8 mg/l Exposure time: 96 h LC50 (Daphnia) 378 mg/l Exposure time: 48 h

5 DFF+IPU SC G U-EU 5/6 Toxicity to algae EC50 (Pseudokirchneriella subcapitata) 22,7 µg/l Exposure time: 72 h Further information on ecology Additional ecological information Information given is based on data obtained from similar substances. 13. DISPOSAL CONSIDERATIONS Product Must not be disposed of together with household garbage. Do not allow product to reach sewage system. In accordance with current regulations and, if necessary, after consultation with the site operator and/or with the responsible authority, the product may be taken to a waste disposal site or incineration plant. Contaminated packaging Clean container with water. Puncture container to avoid re-use. Not completely emptied packagings should be disposed of as hazardous waste. Waste key for the unused product agrochemical waste containing dangerous substances 14. TRANSPORT INFORMATION ADR/RID/ADNR UN-No 3082 Labels 9 Packaging group III Hazard no. 90 Description of the goods IMDG UN-No 3082 Labels 9 Packaging group III EmS F-A, S-F Marine pollutant Description of the goods IATA UN-No 3082 Labels 9 Packaging group Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ISOPROTURON SOLUTION) Marine pollutant ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ISOPROTURON SOLUTION) III ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ISOPROTURON SOLUTION )

6 DFF+IPU SC G U-EU 6/6 15. REGULATORY INFORMATION Classification and labelling in accordance with the EC Directive on dangerous preparations 1999/45/EC as amended. Classification: Hazard warning labelling compulsory Hazardous components which must be listed on the label: Isoproturon Symbol(s) Xn N Harmful Dangerous for the environment R-phrase(s) R40 Limited evidence of a carcinogenic effect. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s) S35 This material and its container must be disposed of in a safe way. S36/37 Wear suitable protective clothing and gloves. S57 Use appropriate container to avoid environmental contamination. Exceptional labelling To avoid risks to man and the environment, comply with the instructions for use. 16. OTHER INFORMATION Further information Text of R phrases mentioned in Section 2: R40 Limited evidence of a carcinogenic effect. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The information given in this Data Sheet has been included in accordance with the guidelines established by EC Directive 1991/155/EC as amended. This data sheet complements the user's instructions, but does not replace them. The information it contains is based on the knowledge available about the product concerned at the time it was compiled. Users are further reminded of the possible risks of using a product for purposes other than those for which it was intended. The required information complies with current EEC legislation. Addressees are requested to observe any additional national requirements. Changes since the last version are highlighted in the margin. This version replaces all previous versions.