Issue Date: 12-Jul-2005 Revision Date: 06-May-2014 Version 1 1. IDENTIFICATION. Tub, tile, and bowl cleaner. 2. HAZARDS IDENTIFICATION

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1 Safety Data Sheet Issue Date: 12-Jul-2005 Version 1 1. IDENTIFICATION Product Identifier Product Name Shower Patrol Other means of identification SDS # CARROLL-025 Product Code 393 UN/ID No UN3264 Recommended use of the chemical and restrictions on use Recommended Use Tub, tile, and bowl cleaner. Details of the supplier of the safety data sheet Supplier Address Carroll Co W. Kingsley Road Garland, TX Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr) INFOTRAC (International) (North America) 2. HAZARDS IDENTIFICATION Appearance Blue liquid Physical State Liquid Odor Mint Classification Skin corrosion/irritation Category 1 Sub-category C Serious eye damage/eye irritation Category 1 Signal Word Danger Hazard Statements Causes severe skin burns and eye damage Precautionary Statements - Prevention Do not breathe dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Page 1 / 8

2 Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a poison center or doctor/physician IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a poison center or doctor/physician IF SWALLOWED: rinse mouth. Do NOT induce vomiting Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant First Aid Measures 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% FIRST-AID MEASURES Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek immediate medical attention/advice. Skin Contact Take off contaminated clothing. Wash off immediately with plenty of water for at least 15 minutes. If irritation persists, seek medical attention. Wash contaminated clothing before reuse. Inhalation Ingestion Remove to fresh air. Call a physician immediately. Give large quantities of water. Do not induce vomiting. Get medical attention. Most important symptoms and effects Symptoms Burning and/or irritation to eyes and skin. Ingestion may cause severe burns to mouth, throat or stomach. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media. Specific Hazards Arising from the Chemical None known. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Page 2 / 8

3 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Methods and material for containment and cleaning up Methods for Containment Methods for Clean-Up Prevent further leakage or spillage if safe to do so. Flood area with water and then mop up. Product may be neutralized with baking soda. Dispose of in accordance with federal, state and local regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Do not destroy or deface the label. Wash thoroughly after handling. Use personal protection recommended in Section 8. Do not breathe dust/fume/gas/mist/vapors/spray. Conditions for safe storage, including any incompatibilities Storage Conditions Incompatible Materials Keep containers tightly closed in a dry, cool and well-ventilated place. Store containers upright. Store locked up. Oxidizing agents. Bleach. Strong alkalis. Strong acids. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Appropriate engineering controls STEL: 3 mg/m 3 TWA: 1 mg/m 3 TWA: 1 mg/m 3 (vacated) TWA: 1 mg/m 3 (vacated) STEL: 3 mg/m 3 IDLH: 1000 mg/m 3 TWA: 1 mg/m 3 STEL: 3 mg/m 3 Engineering Controls Apply technical measures to comply with the occupational exposure limits. Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Goggles. Rubber gloves. Ensure adequate ventilation, especially in confined areas. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Page 3 / 8

4 Information on basic physical and chemical properties 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Appearance Blue liquid Odor Mint Color Blue Odor Threshold Property Values Remarks Method ph 1.6 Melting Point/Freezing Point Not available Boiling Point/Boiling Range Flash Point None (will not burn) Evaporation Rate Flammability (Solid, Gas) n/a-liquid Upper Flammability Limits Lower Flammability Limit Vapor Pressure Not available Vapor Density Specific Gravity 1.08 (1=Water) Water Solubility Completely soluble Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to Avoid Keep out of reach of children. Incompatible Materials Oxidizing agents. Bleach. Strong alkalis. Strong acids. Hazardous Decomposition Products None known based on information supplied. 10. STABILITY AND REACTIVITY Page 4 / 8

5 Information on likely routes of exposure Product Information 11. TOXICOLOGICAL INFORMATION Eye Contact Skin Contact Inhalation Ingestion Causes severe eye damage. Causes severe skin burns. Avoid breathing vapors or mists. Do not taste or swallow. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 = 1530 mg/kg ( Rat ) = 2730 mg/kg ( Rabbit ) > 850 mg/m 3 ( Rat ) 1 h Trade Secret = 887 mg/kg ( Rat ) = 2500 mg/kg ( Rat ) > 5000 mg/kg ( Rabbit ) - Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. Numerical measures of toxicity 12. ECOLOGICAL INFORMATION Ecotoxicity An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms Trade Secret Crustacea 50: 24 h Daphnia magna mg/l EC50 Persistence/Degradability. Bioaccumulation. Mobility Other Adverse Effects Page 5 / 8

6 Waste Treatment Methods 13. DISPOSAL CONSIDERATIONS Disposal of Wastes Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Status Chemical Name California Hazardous Waste Status Corrosive 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT UN/ID No UN3264 Proper Shipping Name Corrosive liquid, acidic, inorganic, n.o.s. (Phosphoric acid) Hazard Class 8 Packing Group III IATA UN/ID No UN3264 Proper Shipping Name Corrosive liquid, acidic, inorganic, n.o.s. (Phosphoric acid) Hazard Class 8 Packing Group III IMDG UN/ID No UN3264 Proper Shipping Name Corrosive liquid, acidic, inorganic, n.o.s. (Phosphoric acid) Hazard Class 8 Packing Group III Page 6 / 8

7 International Inventories TSCA Listed Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory 15. REGULATORY INFORMATION DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances US Federal Regulations CERCLA Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) Component ( 9.8 ) CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Quantities Substances 5000 lb X US State Regulations U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania X X X Trade Secret X Page 7 / 8

8 16. OTHER INFORMATION NFPA HMIS Health Hazards Health Hazards 3 Flammability Flammability 0 Instability Physical Hazards 1 Special Hazards Personal Protection B = Goggles, gloves Issue Date: Revision Date: Revision Note: 12-Jul May-2014 New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 8 / 8