Issue Date: 27-Dec-2011 Revision Date: 24-Feb-2014 Version 1 1. IDENTIFICATION. Symmetry Antimicrobial Lotion Soap

Transcription

1 Safety Data Sheet Issue Date: 27-Dec-2011 Version 1 1. IDENTIFICATION Product Identifier Product Name Symmetry Antimicrobial Lotion Soap Other means of identification SDS # BE-9004 Product Code 9004 Recommended use of the chemical and restrictions on use Recommended Use Hand soap. Details of the supplier of the safety data sheet Supplier Address Buckeye International, Inc Wagner Place Maryland Heights, MO USA Emergency Telephone Number Company Phone Number (Medical) Emergency Telephone (24 hr) (Transportation) (International) (North America) INFOTRAC (International) (North America) 2. HAZARDS IDENTIFICATION Appearance Clear amber liquid Physical State Liquid Odor Fruity Floral Classification Serious eye damage/eye irritation Category 1 Skin sensitization Category 1 Signal Word Danger Hazard Statements Causes serious eye damage May cause an allergic skin reaction Page 1 / 8

2 Precautionary Statements - Prevention Avoid breathing dust/fume/gas/mist/vapors/spray Contaminated work clothing should not be allowed out of the workplace Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a poison center or doctor/physician Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Other Hazards Harmful to aquatic life with long lasting effects 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Water >68.7 Sodium lauryl sulfate <5 Coconut Acid <5 Sodium Sulfate <4 Oleic Acid <4 <2 Ammonium laureth sulfate <2 Chloroxylenol **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** First Aid Measures 4. FIRST-AID MEASURES Eye Contact Skin Contact Inhalation Ingestion Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek immediate medical attention/advice. If skin irritation occurs, rinse affected area with water. Remove to fresh air. Give two glasses of water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Most important symptoms and effects Symptoms Exposed individuals may experience eye tearing, redness, and discomfort. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. Page 2 / 8

3 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media. Specific Hazards Arising from the Chemical Combustion products may be toxic. Hazardous Combustion Products Carbon oxides. Oxides of sulfur. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Spills may be slippery. Use personal protective equipment as required. Methods and material for containment and cleaning up Methods for Containment Methods for Clean-Up Prevent further leakage or spillage if safe to do so. Pick up with mop, wet/dry vac, or absorbent material. Rinse area with clear water and allow floor to dry before allowing traffic. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Avoid breathing vapors or mists. Keep out of the reach of children. Contaminated work clothing should not be allowed out of the workplace. Conditions for safe storage, including any incompatibilities Storage Conditions Incompatible Materials Keep containers tightly closed in a dry, cool and well-ventilated place. Store at room temperature. Chlorine bleach. Page 3 / 8

4 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH STEL: 6 ppm TWA: 3 ppm Appropriate engineering controls TWA: 3 ppm TWA: 6 mg/m 3 (vacated) TWA: 3 ppm (vacated) TWA: 8 mg/m 3 (vacated) STEL: 6 ppm (vacated) STEL: 15 mg/m 3 IDLH: 30 ppm TWA: 3 ppm TWA: 8 mg/m 3 STEL: 6 ppm STEL: 15 mg/m 3 Engineering Controls Apply technical measures to comply with the occupational exposure limits. Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Respiratory Protection When using product, do not rub eyes. No protective equipment is needed under normal use conditions. No protective equipment is needed under normal use conditions. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Information on basic physical and chemical properties 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Appearance Clear amber liquid Odor Fruity Floral Color Amber Odor Threshold Property Values Remarks Method ph 8.7 ± 0.5 (conc and use dilution) Melting Point/Freezing Point Boiling Point/Boiling Range 100 C / 212 F Flash Point None Tag Closed Cup Evaporation Rate 1.0 (Water = 1) Flammability (Solid, Gas) n/a-liquid Upper Flammability Limits Not applicable Lower Flammability Limit Not applicable Vapor Pressure Vapor Density Specific Gravity 1.03 Water Solubility Infinite Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties Page 4 / 8

5 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to Avoid Keep out of reach of children. Incompatible Materials Chlorine bleach. Hazardous Decomposition Products Carbon oxides. Sulfur oxides. Information on likely routes of exposure Product Information 11. TOXICOLOGICAL INFORMATION Eye Contact Skin Contact Inhalation Ingestion Causes serious eye damage. May cause an allergic skin reaction. Under normal conditions of intended use, this material is not expected to be an inhalation hazard. Do not taste or swallow. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Sodium lauryl sulfate = 1288 mg/kg ( Rat ) = 580 mg/kg ( Rabbit ) > 3900 mg/m 3 ( Rat ) 1 h Oleic Acid = 25 g/kg ( Rat ) Sodium Sulfate > mg/kg ( Rat ) = 1720 mg/kg ( Rat ) = 1 ml/kg ( Rabbit ) = 1025 mg/kg - ( Rabbit ) Ammonium laureth sulfate = 630 mg/kg ( Rat ) Chloroxylenol = 3830 mg/kg ( Rat ) - - Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Page 5 / 8

6 Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization Carcinogenicity May cause an allergic skin reaction. This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. Numerical measures of toxicity Ecotoxicity Harmful to aquatic life with long lasting effects. 12. ECOLOGICAL INFORMATION Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms Sodium lauryl sulfate Oleic Acid Sodium Sulfate : 72 h Desmodesmus subspicatus mg/l EC : 96 h Desmodesmus subspicatus mg/l EC50 117: 96 h Pseudokirchneriella subcapitata mg/l EC : 96 h Pseudokirchneriella subcapitata mg/l EC50 static : 96 h Pimephales : 96 h Pimephales : 96 h Pimephales : 96 h Oncorhynchus mykiss mg/l LC50 static 4.62: 96 h Oncorhynchus mykiss mg/l LC50 flow-through 4.2: 96 h Oncorhynchus mykiss mg/l LC : 96 h Brachydanio rerio mg/l LC50 flow-through : 96 h Brachydanio rerio mg/l LC50 semi-static : 96 h Lepomis macrochirus mg/l LC50 static : 96 h Lepomis macrochirus mg/l LC50 flow-through 4.5: 96 h Lepomis macrochirus mg/l LC : 96 h Pimephales promelas mg/l LC50 static : 96 h Pimephales promelas mg/l LC50 semi-static : 96 h Pimephales promelas mg/l LC : 96 h Poecilia reticulata mg/l LC50 semi-static : 96 h Poecilia reticulata mg/l LC50 static 1.31: 96 h Cyprinus carpio mg/l LC50 semi-static 205: 96 h Pimephales : 96 h Pimephales promelas mg/l LC : 96 h Pimephales : 96 h Lepomis macrochirus mg/l LC50 static 13500: 96 h Lepomis macrochirus mg/l LC50 Crustacea 1.8: 48 h Daphnia magna mg/l EC : 48 h Daphnia magna mg/l EC50 Page 6 / 8

7 Chloroxylenol Persistence/Degradability. Bioaccumulation. Mobility 15: 72 h Desmodesmus subspicatus mg/l EC50 227: 96 h Pimephales promelas mg/l LC50 flow-through 3684: 96 h Brachydanio rerio mg/l LC50 static : 96 h Lepomis macrochirus mg/l LC50 static : 96 h Oncorhynchus mykiss mg/l LC50 static 200: 96 h Oncorhynchus mykiss mg/l LC50 flow-through : 96 h Oncorhynchus mykiss mg/l LC50 static : 96 h Lepomis macrochirus mg/l LC50 static EC50 = 1.6 mg/l 5 min 65: 48 h Daphnia magna mg/l EC : 48 h Daphnia magna mg/l EC50 Static Chemical Name Sodium lauryl sulfate Partition Coefficient Other Adverse Effects 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Disposal should be in accordance with applicable regional, national and local laws and regulations. 14. TRANSPORT INFORMATION Note DOT IATA IMDG Marine Pollutant Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. Not regulated Not regulated This material may meet the definition of a marine pollutant Page 7 / 8

8 15. REGULATORY INFORMATION International Inventories TSCA Listed Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances US Federal Regulations CERCLA Does not apply SARA 311/312 Hazard Categories This material, as supplied, does not contain any substances subject to the requirements of SARA Sections 311/312 (40 CFR 370) SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 US State Regulations U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania Oleic Acid X Sodium Sulfate X X X X X 16. OTHER INFORMATION NFPA HMIS Health Hazards Health Hazards Flammability Flammability Instability Physical Hazards Special Hazards Personal Protection Issue Date: Revision Date: Revision Note: 27-Dec Feb-2014 New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 8 / 8