SAFETY DATA SHEET TECGRIP CAS CARTRIDGE

Transcription

1 SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name Product number TGR Relevant identified uses of the substance or mixture and uses advised against Identified uses A chemical anchoring application Details of the supplier of the safety data sheet Supplier PAREX Ltd Holly Lane Industrial Estate Atherstone Warwickshire CV9 2QZ Tel: +44 (0) (Mon-Fri 08:30-16:30) Fax: +44 (0) sds@parex.co.uk 1.4. Emergency telephone number Emergency telephone + 44 (0) (Mon-Fri 08:30-16:30) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Not Classified Health hazards Environmental hazards Eye Irrit. 2 - H319 Skin Sens. 1 - H317 Repr. 2 - H361d STOT RE 2 - H373 Not Classified 2.2. Label elements Pictogram Signal word Hazard statements Warning H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H361d Suspected of damaging the unborn child. H373 May cause damage to organs (Ears, Respiratory system, lungs) through prolonged or repeated exposure. 1/8

2 Precautionary statements Contains P202 Do not handle until all safety precautions have been read and understood. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P302+P352 IF ON SKIN: Wash with plenty of water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/ attention. P314 Get medical advice/ attention if you feel unwell. P501 Dispose of contents/ container in accordance with national regulations. STYRENE, DIBENZOYL PEROXIDE 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.2. Mixtures STYRENE 3-10% CAS number: EC number: REACH registration number: Classification Flam. Liq. 3 - H226 Acute Tox. 4 - H332 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Repr. 2 - H361d STOT RE 1 - H372 2-ETHYLHEXYL BENZOATE 1-3% CAS number: Classification Aquatic Chronic 4 - H413 DIBENZOYL PEROXIDE 1-3% CAS number: REACH registration number: Classification Org. Perox. B - H241 Eye Irrit. 2 - H319 Skin Sens. 1 - H317 The full text for all hazard statements is displayed in Section 16. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Ingestion Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Get medical attention. Do not induce vomiting. Promptly get affected person to drink large volumes of water to dilute the swallowed chemical. Get medical attention. 2/8

3 Skin contact Eye contact Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention. Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyelids widely. If irritation persists: Seek medical attention and bring along these instructions Most important symptoms and effects, both acute and delayed Inhalation Skin contact Eye contact Harmful by inhalation. May cause irritation. Irritating and may cause redness and pain Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Use fire-extinguishing media suitable for the surrounding fire. Use alcohol-resistant foam, carbon dioxide or dry powder to extinguish. Do not use halons Special hazards arising from the substance or mixture Specific hazards Hazardous combustion products Risk of explosion if heated under confinement. Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours Advice for firefighters Special protective equipment for firefighters Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions For personal protection, see Section Environmental precautions Environmental precautions Do not discharge into drains, water courses or onto the ground. Contain spillage with sand, earth or other suitable non-combustible material. Contain spillage with sand, earth or other suitable non-combustible material Methods and material for containment and cleaning up Methods for cleaning up Absorb spillage with non-combustible, absorbent material. Containers with collected spillage must be properly labelled with correct contents and hazard symbol Reference to other sections Reference to other sections For waste disposal, see Section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Usage precautions Use only outdoors or in a well-ventilated area. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. 3/8

4 Advice on general occupational hygiene Wash at the end of each work shift and before eating, smoking and using the toilet Conditions for safe storage, including any incompatibilities Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking Specific end use(s) Specific end use(s) Building and construction work (SU19). SECTION 8: Exposure Controls/personal protection 8.1. Control parameters Occupational exposure limits STYRENE Long-term exposure limit (8-hour TWA): WEL 100 ppm 430 mg/m³ Short-term exposure limit (15-minute): WEL 250 ppm 1080 mg/m³ Long-term exposure limit (8-hour TWA): WEL 20ppm 85mg/m3 (Ireland) Short-term exposure limit (15-minute): 40ppm 170mg/m3 (Ireland) DIBENZOYL PEROXIDE Long-term exposure limit (8-hour TWA): 5 mg/m³ Long-term exposure limit (8-hour TWA): WEL 5mg/m3 (Ireland) WEL = Workplace Exposure Limit 8.2. Exposure controls Protective equipment Appropriate engineering controls Eye/face protection Hand protection Other skin and body protection Hygiene measures Respiratory protection Environmental exposure controls As this product contains ingredients with exposure limits, process enclosures, local exhaust ventilation or other engineering controls should be used to keep worker exposure below any statutory or recommended limits, if use generates dust, fumes, gas, vapour or mist. Wear eye protection. Wear protective gloves. To protect hands from chemicals, gloves should comply with European Standard EN374. Viton rubber (fluoro rubber). Be aware that the liquid may penetrate the gloves. Frequent change is advisable. The selected gloves should have a breakthrough time of at least 8 hours. Wear protective clothing. Wash at the end of each work shift and before eating, smoking and using the toilet. Respiratory protection must be used if the airborne contamination exceeds the recommended occupational exposure limit. Organic vapour filter. Gas/vapour filter, type A. EN141. Keep container tightly sealed when not in use. SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Appearance Paste. 4/8

5 Colour Odour Various colours. Characteristic. Relative density 1.71 Solubility(ies) Insoluble in water at 20C. Oxidising properties Oxidising (by EC criteria) Other information Volatile organic compound This product contains a maximum VOC content of 2.74 g/l. SECTION 10: Stability and reactivity Reactivity Reactivity Stable under recommended transport or storage conditions Chemical stability Stability Stable under the prescribed storage conditions. May polymerise on heating Possibility of hazardous reactions Possibility of hazardous reactions May polymerise on heating Conditions to avoid Conditions to avoid Heat. Air. Sources of ignition. Direct sunlight Incompatible materials Materials to avoid Acids. Alkalis. Heavy metals. Reducing agents. Avoid contact with peroxides Hazardous decomposition products Hazardous decomposition products Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. Pressure rise and possible bursting of containers may follow. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity - inhalation ATE inhalation (gases ppm) 30,000.0 ATE inhalation (vapours mg/l) ATE inhalation (dusts/mists mg/l) Skin corrosion/irritation Skin corrosion/irritation Serious eye damage/irritation Serious eye damage/irritation Aspiration hazard Aspiration hazard 10.0 May cause skin irritation. Irritation of eyes is assumed. Harmful by inhalation. SECTION 12: Ecological Information Ecotoxicity No information available Toxicity 5/8

6 12.2. Persistence and degradability Persistence and degradability No data available Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation Mobility in soil Mobility The product is insoluble in water. The product is immiscible with water and will sediment in water systems Results of PBT and vpvb assessment Results of PBT and vpvb assessment This product does not contain any substances classified as PBT or vpvb Other adverse effects Other adverse effects Not available. SECTION 13: Disposal considerations Waste treatment methods General information Disposal methods Waste, residues, empty containers, discarded work clothes and contaminated cleaning materials should be collected in designated containers, labelled with their contents. Residues and empty containers should be taken care of as hazardous waste according to local and national provisions. Dispose of contents/container in accordance with national regulations. Small quantities of the product can be mixed and allowed to cure. It can then be disposed of as solid waste. Waste class Waste code number SECTION 14: Transport information UN number UN No. (ADR/RID) 3269 UN No. (IMDG) 3269 UN No. (ICAO) 3269 UN No. (ADN) UN proper shipping name Proper shipping name (ADR/RID) POLYESTER RESIN KIT (STYRENE) Proper shipping name (IMDG) POLYESTER RESIN KIT (STYRENE) Proper shipping name (ICAO) Proper shipping name (ADN) POLYESTER RESIN KIT (STYRENE) POLYESTER RESIN KIT (STYRENE) Transport hazard class(es) ADR/RID class 3 ADR/RID classification code F3 ADR/RID label 3 IMDG class 3 6/8

7 ICAO class/division 3 ADN class 3 Transport labels Packing group ADR/RID packing group IMDG packing group ADN packing group ICAO packing group III III III III Environmental hazards Environmentally hazardous substance/marine pollutant No Special precautions for user ADR transport category 3 Tunnel restriction code (E) Transport in bulk according to Annex II of MARPOL and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (as amended). Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (as amended) Chemical safety assessment No chemical safety assessment has been carried out. SECTION 16: Other information Issued by QSHE Manager Revision date 19/10/2018 Supersedes date 14/01/2016 SDS number /8

8 Hazard statements in full H226 Flammable liquid and vapour. H241 Heating may cause a fire or explosion. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H361d Suspected of damaging the unborn child. H372 Causes damage to organs through prolonged or repeated exposure. H373 May cause damage to organs (Ears, Respiratory system, lungs) through prolonged or repeated exposure. H413 May cause long lasting harmful effects to aquatic life. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 8/8