SECTION 1: Identification of the substance/mixture and of the company/undertaking

Transcription

1 Date of issue: 05/07/2017 Revision date: 05/07/2017 Supersedes: 31/10/2014 Version: 2.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Mixture Name Product code BU Fire Protection 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec For professional use only Industrial Uses advised against 1.3. Details of the supplier of the safety data sheet Hilti France S.A. Rond Point Mérantais Magny-les-Hameaux - France T F fr-contactez-nous@hilti.com Supplier Hilti France S.A. Rond Point Mérantais Magny-les-Hameaux - France T F fr-contactez-nous@hilti.com Department issuing data specification sheet Hilti AG Feldkircherstraße Schaan - Liechtenstein T chemicals.hse@hilti.com 1.4. Emergency telephone number Emergency number Schweizerisches Toxikologisches Informationszentrum 24h Service (international) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC). 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) 05/07/2017 FR - en 1/8

2 2.2. Label elements Labelling according to Regulation (EC). 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display 2.3. Other hazards Adverse physicochemical, human health and environmental effects To our knowledge, this product does not present any particular risk, provided it is handled in accordance with good occupational hygiene and safety practice. SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture Name Product identifier % Classification according to Regulation (EC). 1272/2008 [CLP] calcium sulfate substance with national workplace exposure limit(s) (FR) Full text of H-statements: see section 16 (CAS ) (EC ) (REACH-no) >= 80 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). Remove person to fresh air and keep comfortable for breathing. Assure fresh air breathing. Allow the victim to rest. Wash skin with plenty of water. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Rinse cautiously with water for several minutes. Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. Call a poison center or a doctor if you feel unwell. Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/effects t expected to present a significant hazard under anticipated conditions of normal use Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Water spray. Dry powder. Foam. Carbon dioxide. Sand. Do not use a heavy water stream. 05/07/2017 FR - en 2/8

3 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment. Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures Avoid dust formation For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures Ventilate spillage area. Evacuate unnecessary personnel. Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". Equip cleanup crew with proper protection. Ventilate area Environmental precautions Prevent entry to sewers and public waters. tify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections Mechanically recover the product. On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials. For further information refer to section 13. See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures Provide good ventilation in process area to prevent formation of vapour. Ensure good ventilation of the work station. Wear personal protective equipment. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions Keep container closed when not in use. Protect from moisture. Incompatible products Strong acids. Strong bases. Incompatible materials Moisture. Storage temperature 5-30 C 7.3. Specific end use(s) 05/07/2017 FR - en 3/8

4 SECTION 8: Exposure controls/personal protection 8.1. Control parameters France Local name Calcium (sulfate de) France VME (mg/m³) 10 mg/m³ 8.2. Exposure controls Appropriate engineering controls Personal protective equipment Hand protection Ensure good ventilation of the work station. Avoid all unnecessary exposure. Protective gloves. Wear protective gloves Type Material Permeation Thickness (mm) Standard Disposable gloves Nitrile rubber (NBR) 3 (> 60 minutes) >0.4 EN 374 Eye protection Safety glasses. Chemical goggles or safety glasses Type Use Characteristics Standard Safety glasses EN 166, EN 170 Skin and body protection Respiratory protection Wear suitable protective clothing In case of insufficient ventilation, wear suitable respiratory equipment. Wear appropriate mask Device Filter type Condition Standard Dust mask Type P2 Environmental exposure controls Other information Avoid release to the environment. Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Solid Appearance Powder. Colour white. Odour odourless. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point t determined Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) t flammable,n flammable Vapour pressure Relative vapour density at 20 C Relative density 05/07/2017 FR - en 4/8

5 Density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits t determined Soluble in water. Product is not explosive Other information SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions dangerous reactions known under normal conditions of use Conditions to avoid ne under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Reproductive toxicity Specific target organ toxicity (single exposure) > 1584 mg/kg bodyweight (Rat; OECD 420: Acute Oral toxicity Acute Toxic Class Method; Experimental value) 05/07/2017 FR - en 5/8

6 Specific target organ toxicity (repeated exposure) Aspiration hazard Potential adverse human health effects and symptoms. SECTION 12: Ecological information Toxicity Ecology - general LC50 fish 1 LC50 fish 2 The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment mg/l (96 h; Lepomis macrochirus) > mg/l (96 h; Gambusia affinis) Persistence and degradability Persistence and degradability Persistence and degradability Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD BOD (% of ThOD) Bioaccumulative potential Bioaccumulative potential Bioaccumulative potential t established. Biodegradability: not applicable. t established. bioaccumulation data available Mobility in soil Results of PBT and vpvb assessment Other adverse effects Avoid release to the environment SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods Dispose of contents/container in accordance with licensed collector s sorting instructions. Waste disposal recommendations Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials Avoid release to the environment. European List of Waste (LoW) code gypsum-based construction materials other than those mentioned in SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN Other information supplementary information available 05/07/2017 FR - en 6/8

7 ADR IMDG IATA RID UN number t regulated for transport UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Dangerous for the environment : Dangerous for the environment : Marine pollutant : Dangerous for the environment : supplementary information available Dangerous for the environment : Special precautions for user - Overland transport - Transport by sea - Air transport - Rail transport Carriage prohibited (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Chemical safety assessment chemical safety assessment has been carried out SECTION 16: Other information 05/07/2017 FR - en 7/8

8 Data sources Other information REGULATION (EC) 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) 1907/2006. ne. SDS_EU_Hilti This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 05/07/2017 FR - en 8/8