MATERIAL SAFETY DATA SHEET

Transcription

1 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Other means of identification : Not applicable. Recommended use : Laundry product Restrictions on use : Reserved for industrial and professional use. Product dilution information : 0.1 % % Company : ECOLAB PTY LTD (A.B.N ) 2 Drake Avenue Macquarie Park, NSW Australia Emergency telephone number : Issuing date : SECTION 2. HAZARDS IDENTIFICATION Classified as hazardous according to the criteria of Safe Work Australia and classified as dangerous goods according to the ADG Code. Hazard classification R-phrase(s) S-phrase(s) : Xi - IRRITANT : R10 - Flammable. R38 - Irritating to skin. R43 - May cause sensitization by skin contact. : S24 - Avoid contact with skin. S37 - Wear suitable gloves. S43 - In case of fire, use water spray. Not classified as hazardous according to the criteria of Safe Work Australia nor classified as dangerous goods according to the ADG Code. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Chemical Name CAS-No. Concentration: (%) d-limonene No hazardous ingredients SECTION 4. FIRST AID MEASURES / 9

2 In case of eye contact In case of skin contact If swallowed : Rinse with plenty of water. : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. : Rinse mouth. Get medical attention if symptoms occur. Contact the Poison's Information Centre (eg Australia ; New Zealand ). If inhaled Protection of first-aiders Notes to physician In case of eye contact In case of skin contact If swallowed : Get medical attention if symptoms occur. : If potential for exposure exists refer to Section 8 for specific personal protective equipment. : Treat symptomatically. : Rinse with plenty of water. : Rinse with plenty of water. : Rinse mouth. Get medical attention if symptoms occur. Contact the Poison's Information Centre (eg Australia ; New Zealand ). If inhaled : Get medical attention if symptoms occur. See toxicological information (Section 11) SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during firefighting Hazardous combustion products Special protective equipment for firefighters Specific extinguishing methods Hazchem Code : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : High volume water jet : Fire Hazard Keep away from heat and sources of ignition. Flash back possible over considerable distance. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. : Carbon oxides : Use personal protective equipment. : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. : 3Y / 9

3 SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Remove all sources of ignition. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. : Do not allow contact with soil, surface or ground water. : Eliminate all ignition sources if safe to do so. Stop leak if safe to do so. Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. : Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. : Do not allow contact with soil, surface or ground water. : Stop leak if safe to do so. Contain spillage, and then collect with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. SECTION 7. HANDLING AND STORAGE Advice on safe handling Conditions for safe storage : Avoid contact with skin and eyes. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Keep away from fire, sparks and heated surfaces. Do not get in eyes, on skin, or on clothing. Wash hands thoroughly after handling. Use only with adequate ventilation. : Keep away from heat and sources of ignition. Keep away from oxidizing agents. Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers. Storage temperature : 0 C to 35 C Advice on safe handling Conditions for safe storage : Wash hands thoroughly after handling. Use only with adequate ventilation. : Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters / 9

4 Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection Hygiene measures Engineering measures : Wear the following personal protective equipment: Standard glove type. : No personal respiratory protective equipment normally required. : Remove and wash contaminated clothing before re-use. Wash hands before breaks and immediately after handling the product. Wash face, hands and any exposed skin thoroughly after handling. : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection : No personal respiratory protective equipment normally required. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid liquid Colour : clear, light yellow colourless Odour : citrus citrus ph : , 100 % Flash point Odour Threshold Melting point/freezing point Initial boiling point and boiling range Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapour pressure Relative vapour density : 48 C closed cup, Sustains combustion : > 100 C / 9

5 Relative density : Water solubility Solubility in other solvents Partition coefficient: n- octanol/water Auto-ignition temperature Thermal decomposition Viscosity, kinematic Explosive properties Oxidizing properties Molecular weight VOC : practically insoluble SECTION 10. STABILITY AND REACTIVITY Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Stable under normal conditions. : No dangerous reaction known under conditions of normal use. : Heat, flames and sparks. : None known. : Carbon oxides SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Eyes Skin Ingestion Inhalation Chronic Exposure Eyes Skin Ingestion Inhalation : Causes skin irritation. May cause allergic skin reaction / 9

6 Chronic Exposure Experience with human exposure Eye contact Skin contact Ingestion Inhalation Eye contact Skin contact Ingestion Inhalation : Redness, Irritation, Allergic reactions Toxicity Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Carcinogenicity Reproductive effects Germ cell mutagenicity Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration toxicity Components Acute oral toxicity Components Acute dermal toxicity : d-limonene LD50 rat: 4,400 mg/kg : d-limonene LD50 rabbit: > 5,000 mg/kg SECTION 12. ECOLOGICAL INFORMATION / 9

7 Ecotoxicity Environmental Effects : This product has no known ecotoxicological effects. Product Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Other adverse effects no data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Disposal considerations Disposal methods Disposal considerations : The product should not be allowed to enter drains, water courses or the soil. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not reuse empty containers. : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not reuse empty containers. SECTION 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (ADG) UN number : 2319 Description of the goods : TERPENE HYDROCARBONS, N.O.S. (Limonene) / 9

8 Class : 3 Packing group : III Hazchem Code : 3Y Environmentally hazardous : No Sea Transport (IMDG/IMO) UN number : 2319 Description of the goods : TERPENE HYDROCARBONS, N.O.S. (Limonene) Class : 3 Packing group : III Marine pollutant : No Not intended for transport. SECTION 15. REGULATORY INFORMATION National regulatory information Standard for the Uniform Scheduling of Medicines and Poisons : No poison schedule number allocated The components of this product are reported in the following inventories: 1907/2006 (EU) : Switzerland. New notified substances and declared preparations : Switzerland. Federal Health Agency, Giftliste 1 (Stoffe) United States TSCA Inventory : On TSCA Inventory Canadian Domestic Substances List (DSL) : This product contains the following components that are not on the Canadian DSL nor NDSL. Australia. Industrial Chemical (Notification and Assessment) Act : On the inventory, or in compliance with the inventory New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand : Japan. ENCS - Existing and New Chemical Substances Inventory : Japan. ISHL - Inventory of Chemical Substances (METI) : Korea. Korean Existing Chemicals Inventory (KECI) : Philippines Inventory of Chemicals and Chemical Substances (PICCS) : China Inventory of Existing Chemical Substances : / 9

9 SECTION 16. OTHER INFORMATION Sources of key data used to compile the Material Safety Data Sheet Globally Harmonized System of Classification and Labelling of Chemicals (GHS) IARC: (International Agency for Research on Cancer) US. National Toxicology Program (NTP) Report on Carcinogens ECHA List of Publishable Substances Registered EU HPVCs (High Production Volume Chemicals) Issuing date : Date of first issue : version : 1.1 Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the MSDS. The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text / 9