Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet Issuing Date 3/13/2013 Revision Number 0 1. PRODUCT AND COMPANY IDENTIFICATION Product Name CHLORINE REAGENT 1 Product Code(s) 4498 Synonyms Recommended Use Company Emergency Telephone Number none Test kit reagent. Laboratory chemicals. Industrial (not for food or food contact use). LaMotte Company, Inc. 802 Washington Avenue P.O. Box 329 Chestertown, MD USA 24 Hour Emergency Number (CHEM-TEL): USA, Canada, Puerto Rico Outside North American Continent (Call collect) HAZARDS IDENTIFICATION Emergency Overview May cause skin and eye irritation Ingestion may cause gastrointestinal irritation, nausea, vomiting, and diarrhea Appearance Clear, colorless Physical State Liquid Odor Odorless OSHA Regulatory Status Potential Health Effects Principle Routes of Exposure Acute Toxicity Eyes Skin Inhalation Ingestion Chronic Effects Aggravated Medical Conditions Safety information is given for exposure to the reagent as sold and considers exposure to the chemical if user has direct eye and skin contact. Skin contact, Ingestion. May cause irritation. May cause irritation. May cause irritation of respiratory tract. Ingestion may cause gastrointestinal irritation, nausea, vomiting, and diarrhea. None known. Page 1 / 7

2 3. COMPOSITION/INFORMATION ON INGREDIENTS CAS-No Weight % < <0.1 KATHON < to 100% 4. FIRST AID MEASURES General Advice Eye Contact Skin Contact Inhalation Ingestion Protection of First-aiders Do not get in eyes, on skin, or on clothing. Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Wash off immediately with soap and plenty of water for at least 15 minutes while removing all contaminated clothing and shoes. If irritation develops or persists, consult physician. Move to fresh air. If breathing is difficult, give oxygen. Rinse mouth. Consult a physician. Never give anything by mouth to an unconscious person. Use personal protective equipment. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. 5. FIRE-FIGHTING MEASURES Flammable Properties Not a fire hazard. Suitable Extinguishing Media Water spray, dry chemical, carbon dioxide (CO 2), or foam. NFPA HMIS Health Hazard 1 Health Hazard 1 Flammability 0 Flammability 0 Stability 0 Stability 0 Physical and Chemical Hazards - Personal Precautions Refer to Section ACCIDENTAL RELEASE MEASURES Methods for Containment Methods for Cleaning Up Soak up with inert absorbent material, containerize, and hold for disposal. Dispose according to federal, state, and local regulations. After cleaning, flush away traces with water. 7. HANDLING AND STORAGE Handling Handle in accordance with good industrial hygiene and safety practice. Prevent contact with skin, eyes, and clothing. Do not ingest. Do not eat, drink, or smoke when using this product. Page 2 / 7

3 Storage Keep containers tightly closed in a dry, cool, and well-ventilated place. To maintain product quality, do not store in heat or direct sunlight. Separate from acids. Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION KATHON Personal Protective Equipment Eye/Face Protection Skin and Body Protection Hygiene Measures ACGIH TLV OSHA PEL NIOSH IDLH TWA: 2 mg/m 3 IDLH: 10 mg/m 3 Ceiling: 2 mg/m 3 TWA: 0.01 ppm Safety glasses with side-shields. Gloves & Lab Coat. Wash hands before breaks and immediately after handling the product. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical State Boiling Point/Range Clear, colorless Liquid Odor Odorless ph 7 >100 C/212 F Vapor Density <1(Air = 1) 10. STABILITY AND REACTIVITY Stability Incompatible Products Conditions to Avoid Stable under normal conditions of use and storage. Strong acids. Strong oxidizing agents. Contact with metals (aluminum, zinc, tin) may release hydrogen gas. Exposure to light. Exposure to air. Incompatible products. Hazardous Decomposition Products Iodine gas. Potassium Oxides. Hazardous Polymerization Hazardous polymerization does not occur. 11. TOXICOLOGICAL INFORMATION Acute Toxicity LD50 Oral LD50 Dermal LC50 Inhalation 1350 mg/kg ( Rabbit ) Page 3 / 7

4 CHLORINE REAGENT 1 Product Code(s) 4498 Chronic Toxicity ACGIH IARC NTP OSHA Endocrine Disruptor Information. EU - Endocrine Disrupters EU - Endocrine Disruptors - Japan - Endocrine Disruptor Candidate List Evaluated Substances Information Group III Chemical 12. ECOLOGICAL INFORMATION Ecotoxicity Toxicity to Algae Toxicity to Fish Microtox Daphnia Magna (Water Flea) LC50= 45.4 mg/l Oncorhynchus mykiss 96 h Log Pow 13. DISPOSAL CONSIDERATIONS Waste Disposal Method Dispose of in accordance with local regulations. This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements RCRA - Halogenated Organic Compounds RCRA - P Series Wastes RCRA - F Series Wastes RCRA - K Series Wastes Page 4 / 7

5 - KATHON TRANSPORT INFORMATION DOT IATA IMDG/IMO Not regulated Not regulated Not regulated 15. REGULATORY INFORMATION International Inventories Component ( <0.05 ) ( <0.1 ) Kathon CG/ICP Preservative KATHON ( <0.1 ) ( 0.3 ) ( 18 ) ( to 100% ) TSCA DSL EINECS/ELIN ENCS IECSC KECL PICCS AICS CS Present X X 1-410; X KE X X Present X X ENCS IECSC KECL X X TSCA DSL EINECS/ELIN CS ENCS IECSC KECL PICCS AICS XU X X ENCS X KE X X Present X X (1)-439 X KECL X X Present X X ENCS X KE X X U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. CAS-No Weight % SARA Threshold Values % < <0.1 KATHON < to 100% SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No Clean Water Act Page 5 / 7

6 CHLORINE REAGENT 1 Product Code(s) 4498 Component CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Quantities Substances ( <0.05 ) ( <0.1 ) KATHON ( <0.1 ) ( 0.3 ) ( 18 ) ( to 100% ) Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any HAPs. CAS-No Weight % HAPS data VOC Chemicals Class 1 Ozone Class 2 Ozone Depletors Depletors < <0.1 Kathon CG/ICP KATHON <0.1 Preservative to 100% CERCLA Hazardous Substances RQs Extremely Hazardous Substances RQs 1000 lb U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals CAS-No California Prop KATHON Massachusetts New Jersey Pennsylvania Illinois Rhode Island X X X X International Regulations Mexico - Grade Page 6 / 7

7 Carcinogen Status Exposure Limits Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR Component ( <0.05 ) ( <0.1 ) KATHON ( <0.1 ) ( 0.3 ) ( 18 ) ( to 100% ) WHMIS Hazard Class 1 % E Not determined Not determined Uncontrolled product according to WHMIS classification criteria 1 % D2A Uncontrolled product according to WHMIS classification criteria 16. OTHER INFORMATION NFPA HMIS PPE Transport Symbol Prepared By Regulatory Affairs Department Issuing Date 3/13/2013 Revision Date - Revision Note Update to Format. Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of MSDS Page 7 / 7