: Diesel CRDI Cleaner

Transcription

1 SECTION 1: Identification 1.1. Identification Product form Trade name Date of issue: 09/30/2016 Revision date: 08/30/2018 Supersedes: 05/10/2017 Version: 1.4 : Mixture Product code : Recommended use and restrictions on use Use of the substance/mixture 1.3. Supplier Protex By Bardahl 1400 NW 52nd Street P.O. Box Seattle, WA T F jackie.leung@bardahl.com Emergency telephone number : : Diesel additive Emergency number : SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Flammable liquids, Category 4 Acute toxicity (inhalation:dust,mist) Category 4 Skin corrosion/irritation, Category 2 Carcinogenicity, Category 2 Aspiration hazard, Category 1 Hazardous to the aquatic environment Chronic Hazard, Category 2 Combustible liquid Harmful if inhaled. Causes skin irritation. Suspected of causing cancer. May be fatal if swallowed and enters airways. Toxic to aquatic life with long lasting effects GHS Label elements, including precautionary statements GHS-US labelling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) : Danger : Combustible liquid May be fatal if swallowed and enters airways. Causes skin irritation. Harmful if inhaled. Suspected of causing cancer. Toxic to aquatic life with long lasting effects. : Do not handle until all safety precautions have been read and understood. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Avoid breathing mist, vapours. Wash hands thoroughly after handling. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear eye protection, protective gloves. If swallowed: Immediately call a POISON CENTER If on skin: Wash with plenty of water If inhaled: Remove person to fresh air and keep comfortable for breathing Call a doctor if you feel unwell Do NOT induce vomiting. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. In case of fire: Use alcohol resistant foam, carbon dioxide (CO2), BC-powder to extinguish. Collect spillage. 08/30/2018 EN (English) Page 1

2 Store in a well-ventilated place. Keep cool. Store locked up. Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation 2.3. Other hazards which do not result in classification 2.4. Unknown acute toxicity (GHS US) SECTION 3: Composition/information on ingredients 3.1. Substances 3.2. Mixtures Name Product identifier % GHS-US classification Petroleum Distillates (CAS-No.) >= 80 Flam. Liq. 4, H227 Acute Tox. 4 (Inhalation), H332 Skin Irrit. 2, H315 Carc. 2, H351 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 Naptha (petroleum), hydrotreated heavy (CAS-No.) Asp. Tox. 1, H304 2-Ethylhexan-1-ol (CAS-No.) Flam. Liq. 4, H227 Acute Tox. 4 (Inhalation), H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 STOT SE 3, H335 Aquatic Acute 3, H402 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Call a physician immediately. : Remove person to fresh air and keep comfortable for breathing. Call a poison center or a doctor if you feel unwell. : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation occurs: Get medical advice/attention. : Rinse eyes with water as a precaution. : Do not induce vomiting. Call a physician immediately Most important symptoms and effects (acute and delayed) Symptoms/effects after skin contact Symptoms/effects after ingestion : Irritation. : Risk of lung oedema Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media 5.2. Specific hazards arising from the chemical Fire hazard Reactivity : Water spray. Dry powder. Foam. Carbon dioxide. : Combustible liquid Special protective equipment and precautions for fire-fighters Protection during firefighting : The product is non-reactive under normal conditions of use, storage and transport. : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. 08/30/2018 EN (English) 2/8

3 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Ventilate spillage area. No open flames, no sparks, and no smoking. Avoid breathing mist, vapours. Avoid contact with skin and eyes. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up For containment Methods for cleaning up Other information : Collect spillage. : Take up liquid spill into absorbent material. Notify authorities if product enters sewers or public waters. : Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Wear personal protective equipment. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use only outdoors or in a well-ventilated area. Avoid breathing mist, vapours. Avoid contact with skin and eyes. : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Store in a well-ventilated place. Keep cool. Store locked up. ACGIH ACGIH TWA (mg/m³) 1200 mg/m³ ACGIH ACGIH TWA (ppm) 184 ppm Petroleum Distillates ( ) ACGIH ACGIH TWA (mg/m³) 100 mg/m³ 8 hrs 8.2. Appropriate engineering controls Appropriate engineering controls Environmental exposure controls : Ensure good ventilation of the work station. : Avoid release to the environment Individual protection measures/personal protective equipment Hand protection: Protective gloves Eye protection: Safety glasses Skin and body protection: Wear suitable protective clothing 08/30/2018 EN (English) 3/8

4 Respiratory protection: [In case of inadequate ventilation] wear respiratory protection. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : amber Dark Odour : characteristic Odour threshold ph Melting point : Freezing point Boiling point Flash point : 63.3 C PMCC typical Relative evaporation rate (butylacetate=1) Flammability (solid, gas) :. Vapour pressure Relative vapour density at 20 C Relative density Density : g/cm³ typical Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic : C typical Viscosity, dynamic Explosive limits Explosive properties Oxidising properties 9.2. Other information SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition Incompatible materials Oxidizing agent Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) : Inhalation:dust,mist: Harmful if inhaled. 08/30/2018 EN (English) 4/8

5 ATE US (dust,mist) mg/l/4h LD50 oral rat > 5000 mg/kg LD50 dermal rat > 5000 mg/kg LC50 inhalation rat (mg/l) > 4.9 g/m³ (4 hr) Petroleum Distillates ( ) LD50 oral rat LD50 dermal rabbit LC50 inhalation rat (mg/l) ATE US (oral) ATE US (gases) ATE US (vapours) ATE US (dust,mist) LD50 oral rat LD50 dermal rat LC50 inhalation rat (mg/l) ATE US (oral) ATE US (gases) ATE US (vapours) ATE US (dust,mist) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity 7600 mg/kg > 4300 mg/kg 4.1 mg/l/4h 7600 mg/kg bodyweight 4500 ppmv/4h 4.1 mg/l/4h 4.1 mg/l/4h 3290 mg/kg bodyweight (Equivalent or similar to OECD 401, Rat, Male, Experimental value, Oral) > 3000 mg/kg bodyweight (OECD 402: Acute Dermal Toxicity, Rat, Male/female, Experimental value, Dermal) mg/l air (OECD 403: Acute Inhalation Toxicity, 4 h, Rat, Male/female, Experimental value, Inhalation (mixture of vapour and aerosol)) 3290 mg/kg bodyweight 4500 ppmv/4h 11 mg/l/4h 1.5 mg/l/4h : Causes skin irritation. : Suspected of causing cancer. Reproductive toxicity STOT-single exposure STOT-single exposure STOT-repeated exposure May cause respiratory irritation. Aspiration hazard Viscosity, kinematic Symptoms/effects after skin contact Symptoms/effects after ingestion SECTION 12: Ecological information Toxicity Ecology - general : May be fatal if swallowed and enters airways. : C typical : Irritation. : Risk of lung oedema. : Toxic to aquatic life with long lasting effects. LC50 fish 2 > 100 mg/l (LC50) EC50 Daphnia 2 > 100 mg/l (EC50) Threshold limit algae 2 > 100 mg/l (EC50) LC50 fish 1 EC50 Daphnia mg/l (EU Method C.1, 96 h, Leuciscus idus, Flow-through system, Fresh water, Experimental value, GLP) 39 mg/l (EU Method C.2, 48 h, Daphnia magna, Static system, Fresh water, Experimental value, GLP) 08/30/2018 EN (English) 5/8

6 12.2. Persistence and degradability Persistence and degradability Readily biodegradable in water. Biodegradability in soil: no data available. Adsorbs into the soil. Low potential for mobility in soil. Photooxidation in the air. Persistence and degradability Biodegradable in the soil. Readily biodegradable in water Bioaccumulative potential Bioaccumulative potential Bioaccumable. BCF other aquatic organisms (BCFWIN, Calculated value) Log Pow 2.9 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method, 25 C) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4) Mobility in soil Surface tension N/m (20 C) Surface tension Ecology - soil N/m (20 C, 0.81 g/l) Highly mobile in soil Other adverse effects SECTION 13: Disposal considerations Disposal methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Transportation of Dangerous Goods Transport by sea Transport document description (IMDG) UN-No. (IMDG) : 3082 Proper Shipping Name (IMDG) Class (IMDG) Packing group (IMDG) Limited quantities (IMDG) Air transport : UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III, MARINE POLLUTANT : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. : 9 - Miscellaneous dangerous substances and articles : III - substances presenting low danger : 5 L 08/30/2018 EN (English) 6/8

7 SECTION 15: Regulatory information US Federal regulations Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States TSCA (Toxic Substances Control Act) inventory International regulations CANADA EU-Regulations National regulations US State regulations Component State or local regulations 2-Ethylhexan-1-ol( ) Naptha (petroleum), hydrotreated heavy( ) Petroleum Distillates( ) SECTION 16: Other information Revision date : 08/30/2018 Full text of H-statements: H227 H304 H315 H319 H332 H335 H351 H402 H411 NFPA health hazard NFPA fire hazard NFPA reactivity Combustible liquid May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation. Suspected of causing cancer. Harmful to aquatic life Toxic to aquatic life with long lasting effects. : 2 - Materials that, under emergency conditions, can cause temporary incapacitation or residual injury. : 2 - Materials that must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. : 0 - Material that in themselves are normally stable, even under fire conditions. 08/30/2018 EN (English) 7/8

8 Hazard Rating Health Flammability Physical Personal protection : 2 Moderate Hazard - Temporary or minor injury may occur : 2 Moderate Hazard - Materials which must be moderately heated or exposed to high ambient temperatures before ignition will occur. Includes liquids having a flash point at or above 100 F but below 200 F. (Classes II & IIIA) : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives. : B B - Safety glasses, Gloves SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 08/30/2018 EN (English) 8/8