MATERIAL SAFETY DATA SHEET. 1. Product and Company Identification

Transcription

1 MATERIAL SAFETY DATA SHEET Product Name CAS # 1 Product and Company Identification FINISH Dishwashing Booster Mixture This MSDS is designed for workplace employees, emergency personnel and for other conditions and situations where there is a greater potential for large-scale or prolonged exposure, in accordance with requirements of the Canadian Workplace Hazardous Materials Information System (WHMIS) This MSDS is not applicable for consumer use of our products For consumer use, all precautionary and first aid language is provided on the product label in accordance with the applicable government regulation Distributed by LEGEND HMIS/NFPA Severe Serious Moderate Slight Minimal Product Use Rinse additive Reckitt Benckiser (Canada) Inc 168 Tech Avenue Unit #2 Mississauga, ON L4W 5S9 In Case of Emergency: Transportation Emergencies: 24 Hour Number: North America: CHEMTREC: Outside North America: Health Flammability Physical Hazard Personal Protection / 2 B 2 Hazards Identification 2 Emergency Overview CAUTION IRRITANT MAY IRRITATE EYES AND SKIN DO NOT mix with other products DO NOT get in eyes, skin or clothing Potential short term health effects Routes of exposure Eyes Keep out of reach of children Eye, Skin contact, Ingestion Eye irritation Skin Irritating to skin Not expected to be a skin sensitizer Inhalation None expected during normal conditions of use Ingestion None expected during normal conditions of use Target organs Eyes Respiratory system Skin Chronic effects The finished product is not expected to have chronic health effects Signs and symptoms May cause irritation Potential environmental effects See section 12 3 Composition/Information on Ingredients CAS # Percent 6-1 #2341 Page 1 of 6 4-Jan-213

2 First aid procedures Eye contact Skin contact Inhalation Ingestion Notes to physician General advice 4 First Aid Measures If in eyes, rinse with water for 15 minutes Remove any contact lenses and continue to rinse with water Get medical attention immediately If on skin, rinse well with water Move to fresh air If swallowed, call a Poison Control Centre or doctor immediately DO NOT induce vomiting Rinse mouth with water Treat patient symptomatically If you feel unwell, seek medical advice (show the label where possible) Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Show this safety data sheet to the doctor in attendance Avoid contact with eyes and skin Keep out of reach of children 5 Fire-fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighers Hazardous combustion products Not flammable by WHMIS criteria Treat for surrounding material Firefighters should wear full protective clothing including self contained breathing apparatus May include and are not limited to: Oxides of carbon Explosion data Sensitivity to mechanical impact Sensitivity to static discharge 6 Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Handling Storage Keep unnecessary personnel away Do not touch or walk through spilled material Do not touch damaged containers or spilled material unless wearing appropriate protective clothing Keep people away from and upwind of spill/leak Do not discharge into lakes, streams, ponds or public waters Advise authorities if product has penetrated drains, sewers or water pipes Prevent entry into waterways, sewers, basements or confined areas Before attempting clean up, refer to hazard data given above Use broom or dry vacuum to collect material for proper disposal without raising dust Rinse area with water Prevent large spills from entering sewers or waterways Contact emergency services and supplier for advice 7 Handling and Storage Ensure adequate ventilation Avoid contact with eyes, skin and clothing Use good industrial hygiene practices in handling this material Wash hands after handling and before eating Not recommended for painted glassware, painted mugs, aluminium, enamel coated silverware or fine china Do not use with non stick coated cookware or removeable stove top components Separate stainless steel from silver, do not use for silver Keep container upright and tightly closed to prevent leakage Keep at temperatures below 5 C/122 F Keep out of reach of children #2341 Page 2 of 6 4-Jan-213

3 Exposure limit values 8 Exposure Controls / Personal Protection Exposure limit values Engineering controls Personal protective equipment ACGIH-TLV TWA: 1 mg/m3 Ensure adequate ventilation, especially in confined areas Consult the product label for special protection or precautions that have been identified for using this product under directed consumer use conditions The following recommendations are given for workplace employees, emergency personnel and for other conditions and situations where there is a greater potential for large-scale or prolonged exposure Hand protection Skin and body protection Respiratory protection General hygiene considerations Eye / face protection Not normally required under normal use conditions If splashing is likely to occur or for occupational exposures, wear appropriate eye protection Emergency responders should wear full eye and face protection Avoid contact with the skin Impervious gloves Emergency responders should wear impermeable gloves Usual safety precautions while handling the product will provide adequate protection against injury or irritation Follow label directions carefully Where exposure guideline levels may be exceeded, use an approved NIOSH respirator Emergency responders should wear self-contained breathing apparatus (SCBA) to avoid inhalation of airborne particles (dust) generated by this product during a spill or other clean-up operations Handle in accordance with good industrial hygiene and safety practice When using do not eat or drink Wash hands before breaks and immediately after handling the product to prevent possible eye irritation from hand contact 9 Physical and Chemical Properties Appearance Free-flowing granular powder Colour White Form Solid Odour Odourless Odour threshold Physical state Solid ph 2 ± 4 (5%) Freezing point Boiling point Pour point Evaporation Rate Flash point Auto-ignition temperature Flammability limits in air, lower, % by volume Flammability Limits in Air, Upper, % by Volume Vapour pressure Vapour density Specific gravity 6-1 Octanol/water coefficient Reactivity 1 Stability and Reactivity This product may react with strong oxidizing agents #2341 Page 3 of 6 4-Jan-213

4 Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Component analysis - LC5 Component analysis - Oral LD5 Effects of acute exposure Eye Skin Inhalation Ingestion Sensitisation Chronic effects Carcinogenicity Mutagenicity Reproductive effects Teratogenicity Name of Toxicologically Synergistic Products Hazardous polymerisation does not occur Stable under recommended storage conditions DO NOT MIX WITH BLEACH or use in conjunction with other household products Avoid temperatures above 5 C / 122 F Avoid exposure to strong sunlight for prolonged periods Acids Caustics Oxidizers May include and are not limited to: Oxides of carbon 11 Toxicological Information Eye irritation LC5 LD5 54 mg/kg mouse; 3 mg/kg rat Irritating to skin Not expected to be a skin sensitizer None expected during normal conditions of use None expected during normal conditions of use Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects 12 Ecological Information Ecotoxicity Components of this product have been identified as having potential environmental concerns Ecotoxicity - Freshwater Fish - Acute Toxicity Data Hr LC5 Lepomis macrochirus: 1516 mg/l [static] Ecotoxicity - Water Flea - Acute Toxicity Data Hr EC5 Daphnia magna: 12 mg/l Persistence and degradability Bioaccumulation/accumulation Mobility in environmental media Environmental effects Aquatic toxicity Partition coefficient Chemical fate information Other adverse effects 13 Disposal Considerations Disposal instructions Waste from residues / unused products Contaminated packaging Dispose in accordance with all applicable regulations Do not dispose of large quantities down the drain Dispose of empty packaging with normal household trash Do not re-use empty containers #2341 Page 4 of 6 4-Jan-213

5 14 Transport Information US Department of Transportation (DOT) Proper shipping name () UN number Severe marine pollutant Packaging exceptions Transportation of Dangerous Goods (TDG - Canada) Proper shipping name () Severe marine pollutant Packaging exceptions IMDG (Marine Transport) Proper shipping name Marine pollutant Severe marine pollutant Special provisions Packaging exceptions IATA/ICAO (Air) Proper shipping name UN number Maximum net quantity packaging Maximum net quantity packaging cargo only () #2341 Page 5 of 6 4-Jan-213

6 15 Regulatory Information Canadian federal regulations Canada - WHMIS - Ingredient Disclosure List % WHMIS classification Exempt - Consumer product Inventory Status Country(s) or region Canada Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations Inventory Name Domestic Substances List (DSL) Non-Domestic Substances List (NDSL) On Inventory (Yes/No)* A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16 Other Information Disclaimer This product should only be used as directed on the label and for the purpose intended To the best of our knowledge, the information contained herein is accurate However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein Final determination of suitability of any material is the sole responsibility of the user All materials may present unknown hazards and should be used with caution Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist Further information FINISH Dishwashing Booster - Lemon Sparkle, 34 g v4 Effective Date Expiry Date 4-Jan Jan Jan-216 Prepared by Reckitt Benckiser Regulatory Department Other Information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document Yes No #2341 Page 6 of 6 4-Jan-213