SAFETY DATA SHEET. None. None. The mixture does not meet the criteria for classification.

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1 SAFETY DATA SHEET 1. Identification Product identifier Other means of identification Product code Synonyms KAS_DURATIONNPK_US_EN 90 Day * DURATION AG ST NPK * DURATION AG LT NPK * 120 Day * DURATION AG XLT NPK * 120 Day * 180 Day * DURATION CR NPK 270 Day * 360 Day * 270 Day Recommended use Fertilizer. Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufacturer/Supplier Koch Agronomic Services, LLC 4111 E 37th St N Wichita, KS US kochmsds@kochind.com Emergency For Chemical Emergency Call CHEMTREC day or night USA/Canada Mexico Outside USA/Canada (collect calls accepted) 2. Hazard(s) identification Physical hazards Health hazards OSHA defined hazards Label elements Hazard symbol Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information Not applicable. Not classified. Not classified. Not classified. None. None. The mixture does not meet the criteria for classification. Observe good industrial hygiene practices. Wash hands after handling. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. None known. 3. Composition/information on ingredients Mixtures Chemical name Ammonium nitrate CAS number % Version #: 01 Revision date: - Issue date: 27-May / 7

2 Potassium sulphate Polymer coating Ammonium Dihydrogenorthophosphate Diammonium phosphate Non-hazardous ingredients Composition comments Mixture Proprietary < 4 All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. This Safety Data Sheet is not a guarantee of product specification or NPK value(s). NPK content is on specified sales orders, customer invoices, or product specification sheets obtained from supplier. 4. First-aid measures Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire fighting equipment/instructions General fire hazards Move to fresh air. Get medical attention if any discomfort continues. Wash with soap and water. Get medical attention if irritation develops or persists. Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation develops or persists. Rinse mouth. Get medical attention if any discomfort continues. Eye contact: Symptoms can include irritation, redness, scratching of the cornea, and tearing. Skin contact: Mild skin irritation. Dust may irritate throat and respiratory system and cause coughing. Treat symptomatically. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Water fog. Water spray. Carbon dioxide (CO2). Foam. Do not use water jet as an extinguisher, as this will spread the fire. Fire may produce irritating, corrosive and/or toxic gases. Heating may cause the release of ammonia vapors. Selection of respiratory protection for firefighting: follow the general fire precautions indicated in the workplace. Self-contained breathing apparatus and full protective clothing should be worn when fighting chemical fires. Use standard firefighting procedures and consider the hazards of other involved materials. Cool material exposed to heat with water spray and remove it if no risk is involved. The product is not flammable. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Avoid inhalation of dust and contact with skin and eyes. Ensure adequate ventilation. Wear suitable protective clothing. For personal protection, see section 8 of the SDS. Stop the flow of material, if this is without risk. Prevent entry into waterways, sewer, basements or confined areas. Avoid dust formation. Sweep up or vacuum up spillage and collect in suitable container for disposal. If sweeping of a contaminated area is necessary use a dust suppressant agent which does not react with the product. After removal flush contaminated area thoroughly with water. Environmental precautions 7. Handling and storage Precautions for safe handling Never return spills to original containers for re-use. Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Do not allow to enter drains, sewers or watercourses. Avoid generation and spreading of dust. Avoid inhalation of dust and contact with skin and eyes. Use only with adequate ventilation. Observe good industrial hygiene practices Version #: 01 Revision date: - Issue date: 27-May / 7

3 Conditions for safe storage, including any incompatibilities Keep container tightly closed. Store in a cool, dry, well-ventilated place. Store away from incompatible materials. 8. Exposure controls/personal protection Occupational exposure limits US. ACGIH Threshold Limit Values Dust Biological limit values Appropriate engineering controls Type Value Form TWA 3 mg/m3 Respirable particles. 10 mg/m3 Inhalable particles. No biological exposure limits noted for the ingredient(s). Provide adequate general and local exhaust ventilation. Individual protection measures, such as personal protective equipment Eye/face protection Wear dust-resistant safety goggles where there is danger of eye contact. Skin protection Hand protection For prolonged or repeated skin contact use suitable protective gloves. Suitable gloves can be recommended by the glove supplier. Other Normal work clothing (long sleeved shirts and long pants) is recommended. Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Wear air supplied respiratory protection if exposure concentrations are unknown. In the United States of America, if respirators are used, a program should be instituted to assure compliance with OSHA 29 CFR and ANSI Z88.2. Thermal hazards General hygiene considerations 9. Physical and chemical properties Appearance Physical state Solid. Form Solid. Color Brownish-gray. Odor Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies) Solubility (water) Partition coefficient Not applicable. (n-octanol/water) Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Handle in accordance with good industrial hygiene and safety practice Version #: 01 Revision date: - Issue date: 27-May / 7

4 Auto-ignition temperature Decomposition temperature Viscosity Other information Explosive properties Oxidizing properties 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products Not explosive. Not oxidizing. The product is stable and non-reactive under normal conditions of use, storage and transport. The product is stable under normal conditions of use, storage and transport. Hazardous polymerization does not occur. Elevated temperatures. Strong acids. Strong oxidizing agents. Reducing agents. Combustible material. Ammonia. Nitrogen oxides (NOx). Potassium oxides. Sulfur oxides (SOx.). 11. Toxicological information Information on likely routes of exposure Dust may irritate respiratory system. Skin contact May cause irritation through mechanical abrasion. Eye contact May cause irritation through mechanical abrasion. Ingestion Ingestion may cause irritation and malaise. Symptoms related to the physical, chemical and toxicological characteristics Eye contact: Symptoms can include irritation, redness, scratching of the cornea, and tearing. Skin contact: Mild skin irritation. Dust may irritate throat and respiratory system and cause coughing. Information on toxicological effects toxicity May cause discomfort if swallowed. Species Ammonium Dihydrogenorthophosphate (CAS ) Dermal Diammonium phosphate (CAS ) Dermal Test Results > 5000 mg/kg > 5000 mg/m³ > 2000 mg/kg > 88.8 mg/l, 4 Hours 4500 mg/kg > 5000 mg/kg > 5000 mg/m³, 4 hours > 2000 mg/kg Version #: 01 Revision date: - Issue date: 27-May / 7

5 Species Potassium sulphate (CAS ) Dermal Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization May cause irritation through mechanical abrasion. Dust may irritate the eyes. Test Results > 2000 mg/day, 24 hours 3.6 mg/m3, 4 hours > 2000 mg/kg Based on available data, the classification criteria are not met. Skin sensitization Not a skin sensitizer. Germ cell mutagenicity Based on available data, the classification criteria are not met. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. OSHA Specifically Regulated Substances (29 CFR ) Reproductive toxicity Based on available data, the classification criteria are not met. Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects Further information 12. Ecological information Ecotoxicity of dusts may cause respiratory irritation. Based on available data, the classification criteria are not met. Not applicable. Diammonium phosphate (CAS ) Aquatic Algae EC50 Crustacea Fish Potassium sulphate (CAS ) Aquatic Algae EC50 Crustacea Fish Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects 13. Disposal considerations Disposal instructions Frequent inhalation of dust over a long period of time increases the risk of developing lung diseases. Prolonged exposure may cause chronic effects. No other specific acute or chronic health impact noted. The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Species Selenastrum capricornutum Daphnia Carp, hawk fish (Cirrhinus mrigala) Chlorella vulgaris Daphnia magna Lepomis macrochirus Pimephales promelas No data is available on the degradability of this product. Not expected to bioconcentrate or bioaccumulate. This product is water soluble and may disperse in soil. No data available. Test Results > 97.1 mg/l, 72 hours 1790 mg/l, 96 hours 1700 mg/l, 96 hours 2700 mg/l, 18 days 720 mg/l, 48 hours 2550 mg/l, 96 hours 680 mg/l, 96 hours Do not allow this material to drain into sewers/water supplies. Dispose in accordance with all applicable regulations Version #: 01 Revision date: - Issue date: 27-May / 7

6 Hazardous waste code Waste from residues / unused products Contaminated packaging The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Disposal recommendations are based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information Not applicable. This product is a solid. Therefore, bulk transport is governed by IMSBC code. US federal regulations This product is hazardous according to OSHA 29 CFR All components are listed on or exempt from the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR ) CERCLA Hazardous Substance List (40 CFR 302.4) Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance SARA 311/312 Hazardous Yes chemical SARA 313 (TRI reporting) Chemical name CAS number % by wt. Ammonium nitrate Ammonium Dihydrogenorthophosphate Diammonium phosphate Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) Not regulated. Safe Drinking Water Act Not regulated. (SDWA) US state regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US. Massachusetts RTK - Substance List US. New Jersey Worker and Community Right-to-Know Act US. Pennsylvania Worker and Community Right-to-Know Law Version #: 01 Revision date: - Issue date: 27-May / 7

7 US. Rhode Island RTK US. California Proposition 65 Not Listed. International Inventories Country(s) or region Inventory name On inventory (yes/no)* United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 27-May-2015 Revision date - Version # 01 Further information HMIS is a registered trade and service mark of the NPCA. HMIS ratings Health: 2 Flammability: 1 Physical hazard: 0 NFPA ratings List of abbreviations References Disclaimer IARC Monographs. Overall Evaluation of Carcinogenicity HSDB - Hazardous Substances Data Bank NOTICE: The information presented herein is based on data considered to be accurate as of the date of preparation of this Safety Data Sheet (SDS) and was prepared pursuant to Government regulation(s) that identify specific types of information to be provided. This SDS may not be used as a commercial specification sheet of manufacturer or seller, and no warranty or representation, expressed or implied, is made as to the accuracy or comprehensiveness of the foregoing data and safety information, nor is any authorization given or implied to practice any patented invention without a license. Additional information may be needed to evaluate other uses of the product, including use of the product in combination with any materials or in any processes other than those specifically referenced. Information provided herein with respect to any hazards that may be associated with the product is not meant to suggest that use of the product in a given application will necessarily result in any exposure or risk to workers or the general public. No responsibility can be assumed by vendor for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices, or from any hazards inherent in the nature of the product. Purchasers and users assume all risk of use, storage and handling of the product in compliance with applicable federal, state and local laws and regulations. Purchasers and users of the product specifically should advise all of their employees, agents, contractors and customers who will use the product of this (M)SDS Version #: 01 Revision date: - Issue date: 27-May / 7