Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet NFPA HMIS PPE Symbol(s) Preparation Date 7/7/2010 Revision Number: 1 1. PRODUCT AND COMPANY IDENTIFICATION Product Description: NDFX 242 Item#: ND0242 Recommended Use Viscosifier, Shale Inhibition, Filtration Control, Drilling Process Contact Manufacturer Newpark Drilling Fluids, LLC : Park Ten Place, Suite 150 Houston, TX Emergency Telephone Number 24-Hour Health/Environmental Emergency Phone: , HAZARDS IDENTIFICATION Emergency Overview Spills may produce extremely slippery surfaces Appearance Viscous, Milky, White, Liquid Physical State Liquid. Odor Aliphatic. Potential Health Effects Principle Routes of Exposure Acute Effects Eyes Skin Inhalation Ingestion Inhalation, Skin contact, Eye contact, Ingestion May cause redness and irritation of the eye. May be irritating to skin. Repeated or prolonged contact can cause defatting of skin and/ or dermatitis. May cause irritation of respiratory tract. Inhalation may cause headaches, nausea, dizziness and other symptoms of central nervous depression. May cause nausea and vomiting. Chronic Effects Prolonged or repeated contact tends to remove skin oils possibly leading to irritation and dermatitis. See Section 11 for additional Toxicological information. Page 1 / 7

2 Aggravated Medical Conditions Potential Environmental Effects Target Organ Effects See Section 12 for additional Ecological information. Skin. Respiratory system 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical characterization Anionic water-soluble polymer 4. FIRST AID MEASURES Eye Contact Skin Contact Inhalation Ingestion tes to Physician Immediately flush with large quantities of water for at least 15 minutes. If eye irritation persists, seek medical attention. Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes. If skin irritation persists, seek medical attention. Remove to fresh air. If breathing is difficult, give oxygen. If symptoms persist, call a physician. first aid should be required if small amount is ingested. If large amoung is ingested, or symptoms occur, obtain medical attention.. Treat symptomatically. 5. FIRE-FIGHTING MEASURES Flammable Properties Does not flash.. Suitable Extinguishing Media Water spray. Water. Foam. Dry powder. Carbon dioxide (CO2). Unsuitable Extinguishing Media Explosion Limits Hazardous Combustion Products Impact sensitivity Sensitivity to static discharge Carbon oxides Specific Hazards Arising from the Chemical Aqueous solutions or powders that become wet render surfaces extremely slippery. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health 1 Flammability 1 Reactivity 0 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Environmental Precautions Use personal protective equipment. Do not allow to enter drains or waterways. Page 2 / 7

3 Methods for Containment Methods for Cleaning Up Other Information In case of spillage, collect and contain material. Place in a suitable container for reuse and disposal. Do not flush with water. Dam up. Soak up with inert absorbent material (e.g. sand, earth etc.). If liquid has been spilt in large quantities clean up promptly by scoop or vacuum. Place into approved waste containers. After cleaning, flush away traces with water. t applicable 7. HANDLING AND STORAGE Handling Storage Avoid contact with skin, eyes and clothing. Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Wash hands before breaks and at the end of the workday. Keep containers tightly closed in a dry, cool and well-ventilated place. Store at temperatures from 0 to 30 degrees Celsius. Freezing will affect the physical condition and damage the material. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. NIOSH IDLH: t Determined Engineering Measures Personal Protective Equipment Eye/face Protection Skin Protection Respiratory Protection General Hygiene Considerations Local exhaust and adequate ventilation recommended. Safety glasses with side-shields. Do not wear contact lenses. Chemical resistant apron. Protective suit if splashing or contact with product is likely. Protective gloves. Wear a NIOSH approved organic respirator in mist conditions. Wash hands before breaks and at the end of workday. Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Viscous Milky White Liquid Color Milky Odor Aliphatic Odor Threshold Physical State Liquid ph 6-8 at 5 g / l Flash Point Does not flash Autoignition Temperature Boiling Point/Range Melting Point/Range t Applicable Flammability Limits in Air Explosive Properties Oxidizing Properties Evaporation Rate t Applicable Vapour Pressure at 68 degrees Fahrenheit ( 20 degrees Celsius) Vapour Density Specific Gravity Page 3 / 7

4 Oil Solubility Partition Coefficient (n-octanol/water) Viscosity Water Solubility Dispersable in water 10. STABILITY AND REACTIVITY Chemical Stability Conditions to Avoid Incompatible Products Hazardous Decomposition Products Possibility of Hazardous Reactions Stable. Heat, flames and sparks. Oxidizing agents. Carbon oxides. Nitrogen oxides (NOx). Hazardous polymerization will not occur 11. TOXICOLOGICAL INFORMATION Acute Toxicity LD50 Oral: > LD50 Oral VALUE 5000 mg/kg rat LC50 Inhalation: This product is not expected to be toxic on inhalation Component Information Irritation Corrosivity Sensitization Irritating to eyes and skin This product is not expected to be a sensitizer. Chronic Toxicity Carcinogenicity There are no known carcinogenic chemicals in this product. Mutagenic Effects Reproductive Effects Developmental Effects Teratogenicity Target Organ Effects Skin., Respiratory system Endocrine Disruptor Information 12. ECOLOGICAL INFORMATION Ecotoxicity Page 4 / 7

5 Contains no substances known to be hazardous to the environment or not degradable in waste water treatment plants. Persistence and Degradability Bioaccumulation Mobility in Environmental Media The material is believed not to bioaccumulate. 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods Contaminated Packaging US EPA Waste Number Dispose of contents/container in accordance with federal, state and local regulations. Rinse empty containers with water and use the rinse water to prepare the working solution. Can be landfilled or incinerated, when in compliance with local regulations. 14. TRANSPORT INFORMATION DOT TDG MEX ICAO IATA IMDG/IMO 15. REGULATORY INFORMATION International Inventories TSCA DSL NDSL EINECS/ELINCS ENCS CHINA KECL PICCS AICS U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part 372. Page 5 / 7

6 SARA 311/312 Hazardous Categorization Chronic Health Hazard Acute Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Clean Water Act CERCLA U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. State Right-to-Know Other International Regulations Mexico - Grade Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class t determined Preparation Date 7/7/ OTHER INFORMATION Revision Date Revision Summary 12-Jul-2010 Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of MSDS Page 6 / 7

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