Safety data sheet. Lubricant Lubricating grease

Transcription

1 Safety data sheet Revision: Replaces: Version:0300/GBR SECTION 1: Identification of the substance/mixture and of the company/undertaking 11 Product identifier Trade name: LGAF 3E 12 Relevant identified uses of the substance or mixture and uses advised against Recommended uses: Lubricant Lubricating grease 13 Details of the supplier of the safety data sheet Supplier: SKF MAINTENANCE PRODUCTS Postbus 1008 NL-3430 BA Nieuwegein The Netherlands Tel: WWW: wwwskfcom 14 Emergency telephone number (UK only) Only available to health professionals SECTION 2: Hazards identification 21 Classification of the substance or mixture CLP-classification (Regulation (EC) No 1272/2008): Most serious harmful effects: The product shall not be classified as hazardous according to the classification and labelling rules for substances and mixtures According to tests, the product need not be classified May cause slight irritation to the skin and eyes 22 Label elements Supplemental information: 23 Other hazards The product shall not be classified as hazardous according to the classification and labelling rules for substances and mixtures Safety data sheet available on request The product does not contain any PBT or vpvb substances SECTION 3: Composition/information on ingredients 32 Mixtures Registration number CAS/ EC Number Substance CLP-classification (Regulation (EC) No 1272/2008) w/w% Note A Calcium hydroxide Eye Dam 1;H318 Skin Irrit 2;H315 STOT SE 3;H < T White mineral oil (petroleum) Asp Tox 1;H < D Distillates (petroleum), hydrotreated heavy naphthenic Asp Tox 1;H <10 4

2 I Distillates (petroleum), solvent-dewaxed heavy paraffinic Asp Tox 1;H <10 4) H304 is not applicable due to the high viscosity of the product Please see section 16 for the full text of H-phrases Other information: Any letters after the CAS number refer to individual data sets The mineral oils in the product contain <3% DMSO extract(ip 346) 4 SECTION 4: First aid measures 41 Description of first aid measures Inhalation: Seek fresh air Seek medical advice in case of persistent discomfort Ingestion: Skin: Eyes: Wash out mouth thoroughly and drink 1-2 glasses of water in small sips Seek medical advice in case of discomfort Remove contaminated clothing Wash skin with soap and water Seek medical advice in case of persistent discomfort Flush with water (preferably using eye wash equipment) until irritation subsides Seek medical advice if symptoms persist Other information: When obtaining medical advice, show the safety data sheet or label 42 Most important symptoms and effects, both acute and delayed May cause slight irritation to the skin and eyes 43 Indication of any immediate medical attention and special treatment needed Treat symptoms No special immediate treatment required SECTION 5: Firefighting measures 51 Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Extinguish with powder, foam, carbon dioxide or water mist Use water or water mist to cool non-ignited stock Do not use water stream, as it may spread the fire 52 Special hazards arising from the substance or mixture Not flammable, but combustible The product decomposes when combusted and the following toxic gases can be formed: Carbon monoxide and carbon dioxide/ Phosphorous oxides 53 Advice for firefighters Move containers from danger area if it can be done without risk Avoid inhalation of vapour and flue gases seek fresh air Wear Self-Contained Breathing Apparatus (SCBA) with chemical resistant gloves SECTION 6: Accidental release measures 61 Personal precautions, protective equipment and emergency procedures For non-emergency personnel: Stop leak if this can be done without risk Wear gloves Wear safety goggles if there is a risk of eye splash In case of insufficient ventilation, wear respiratory protective equipment For emergency responders: In addition to the above: Normal protective clothing equivalent to EN 469 is recommended 62 Environmental precautions Avoid unnecessary release to the environment 63 Methods and material for containment and cleaning up Contain and absorb spill with sand or other absorbent material and transfer to suitable waste containers Wipe up minor spills with a cloth 64 Reference to other sections See section 8 for type of protective equipment See section 13 for instructions on disposal SECTION 7: Handling and storage 71 Precautions for safe handling Use the product under well-ventilated conditions Running water and eye wash equipment should be available Wash hands before breaks, before using restroom facilities, and at the end of work 72 Conditions for safe storage, including any incompatibilities The product should be stored safely, out of reach of children and away from food, animal

3 feeding stuffs, medicines, etc Keep in tightly closed original packaging Do not store with the following: Strong oxidisers 73 Specific end use(s) None SECTION 8: Exposure controls/personal protection 81 Control parameters Occupational exposure limits: Ingredient: Exposure limit Comments Calcium hydroxide - (8h), - (15m) ppm 5 (8h), - (15m) mg/m3 - Legal basis: EH40/2005 Workplace exposure limits Last amended December 2011 Measuring methods: DNEL values: Compliance with the stated occupational exposure limits may be checked by occupational hygiene measurements Workers: Inhalation DNEL (acute/short-term exposure - local effects), 4 mg/m³, Inhalation DNEL (long-term exposure - local effects), 1 mg/m³, General population: Inhalation DNEL (acute/short-term exposure - local effects), 4 mg/m³, Inhalation DNEL (long-term exposure - local effects), 1 mg/m³, PNEC values: PNEC aqua (freshwater) 0,49 mg/l, PNEC aqua (marine water) 0,32 mg/l, PNEC aqua (intermittent releases) 0,49 mg/l, PNEC STP (wastewater-treatment facilities) 3 mg/l, PNEC soil 1080 mg/kg, D: PNEC oral (foodstuffs) 9,33 mg/kg food, I: PNEC oral (foodstuffs) 9,33 mg/kg food, 82 Exposure controls Appropriate engineering controls: Personal protective equipment, eye/face protection: Personal protective equipment, skin protection: Personal protective equipment, respiratory protection: Environmental exposure controls: Wear the personal protective equipment specified below Wear safety goggles if there is a risk of eye splash Eye protection must conform to EN 166 Plastic or rubber gloves recommended In case of insufficient ventilation, wear respiratory protective equipment Filter type: A P Respiratory protection must conform to one of the following standards: EN 136/140/145 Ensure compliance with local regulations for emissions SECTION 9: Physical and chemical properties 91 Information on basic physical and chemical properties State: Paste Colour: White Odour: Almost odourless Odour threshold: ph (solution for use): ph (concentrate): Melting point/freezing point: Initial boiling point and boiling range: Flash point: 160 C (closed cup)

4 Evaporation rate: Flammability (solid, gas): Upper/lower flammability limits: Upper/lower explosive limits: Vapour pressure: Vapour density: Relative density: 1,1 Solubility: Partition coefficient n-octanol/water: Auto-ignition temperature: Decomposition temperature: Viscosity: Explosive properties: Non-explosive Oxidising properties: Non-oxidising 92 Other information None SECTION 10: Stability and reactivity 101 Reactivity Reacts with the following: Strong oxidisers 102 Chemical stability The product is stable when used in accordance with the supplier s directions 103 Possibility of hazardous reactions None known 104 Conditions to avoid None known 105 Incompatible materials Strong oxidisers 106 Hazardous decomposition products Carbon monoxide and carbon dioxide/ Phosphorous oxides SECTION 11: Toxicological information 111 Information on toxicological effects Acute toxicity - oral: Ingestion of large quantities may cause discomfort The product does not have to be classified Based on existing data, the classification criteria are deemed not to have been met Rat: LD50 = >2000 mg/kg (OECD 425) T: Rat: LD50 = >5000 mg/kg D: Rat: LD50 = >5000 mg/kg (OECD 401) I: Rat: LD50 = >5000 mg/kg (OECD 401) Acute toxicity - dermal: Acute toxicity - inhalation: Skin corrosion/irritation: The product does not have to be classified Based on existing data, the classification criteria are deemed not to have been met Rabbit: LD50 = >2500 mg/kg (OECD 402) T: Rabbit: LD50 = >2000 mg/kg D: Rabbit: LD50 = >5000 mg/kg (OECD 402) I: Rabbit: LD50 = >5000 mg/kg (OECD 402) The product does not have to be classified Based on existing data, the classification criteria are deemed not to have been met T: Rat, Mist, 4h: LC50 = >5 mg/l D: Rat, Mist, 4h: LC50 = >5,53 mg/l (OECD 403) I: Rat, Mist, 4h: LC50 = >5,53 mg/l (OECD 403) May irritate the skin may cause reddening According to tests, the product need not be classified Rabbit,, : Irritating (OECD 404) T: Rabbit,, : Non-irritating D: Rabbit,, : Non-irritating I: Rabbit,, : Non-irritating

5 Serious eye damage/eye irritation: Respiratory sensitisation or skin sensitisation: May cause eye irritation According to tests, the product need not be classified Rabbit,, : Corrosive: (OECD 405) T: Rabbit,, : Non-irritating: D: Rabbit,, : Non-irritating: I: Rabbit,, : Non-irritating: (OECD 405) The product does not have to be classified Based on existing data, the classification criteria are deemed not to have been met T: Guinea pig,, : Non-sensitising D: Guinea pig,, : Non-sensitising I: Guinea pig,, : Non-sensitising (OECD 406) Germ cell mutagenicity: Carcinogenic properties: Reproductive toxicity: Single STOT exposure: Repeated STOT exposure: Aspiration hazard: Other toxicological effects: The product does not have to be classified Based on existing data, the classification criteria are deemed not to have been met Bacteria,, : negative (OECD 471) T: Mouse,, : negative (OECD 474) D: Mouse,, : negative (OECD 474) I: Mouse,, : negative (OECD 474) The product does not have to be classified Based on existing data, the classification criteria are deemed not to have been met Rat,, 104w: negative T: Mouse,, 24m: negative D: Mouse,, 78w: negative I: Mouse,, 78w: negative (OECD 451) The product does not have to be classified Based on existing data, the classification criteria are deemed not to have been met Rat,, : negative T: Rat,, : negative D: Rat,, : negative (OECD 421) I: Rat,, : negative (OECD 414) The product does not have to be classified Test data are not available The ingredients are chemically bound which means they cannot be absorbed in the body The product does not have to be classified Based on existing data, the classification criteria are deemed not to have been met T: Rat, 1mg/l, 4w: D: Rat, >0,98mg/l, 28d: I: Rat, >980mg/m³, 4w: The product does not have to be classified Test data are not available None known SECTION 12: Ecological information 121 Toxicity The product does not have to be classified Based on existing data, the classification criteria are deemed not to have been met Acute toxicity: Fish: Gasterosteus aculeatus: 96hLC50 = 457 mg/l Crustacea: Daphnia magna: 48hEC50 = 49,1 mg/l Algae: Pseudokirchneriella subcapitata: 72hEC50 = 184,57 mg/l T: Fish: Oncorhynchus mykiss: 96hLC50 = >100 mg/l Crustacea: Daphnia magna: 48hEC50 = >100 mg/l Algae: Pseudokirchneriella subcapitata: 72hNOEC = 100 mg/l

6 D: Fish: Pimephales promelas: 96hLL50 = >100 mg/l Crustacea: Daphnia magna: 48hEL50 = >10000 mg/l Algae: Pseudokirchneriella subcapitata: 72hEL50 = >100 mg/l Chronic toxicity: I: Fish: Pimephales promelas: 96hLC50 = >100 mg/l Crustacea: Daphnia magna: 48hEC50 = >10000 mg/l Algae: Pseudokirchneriella subcapitata: 72hEC50 = >100 mg/l Crustacea: Name of species not specified: 14dNOEC = 32 mg/l T: Fish: Oncorhynchus mykiss: 28dNOEC = 1000 mg/l Crustacea: Daphnia magna: 21dNOEC = 1000 mg/l D: Crustacea: Daphnia magna: 21dNOEC = 10 mg/l I: Crustacea: Daphnia magna: 21dNOEC = 10 mg/l 122 Persistence and degradability Not expected to be biodegradable Test data are not available for all substances 123 Bioaccumulative potential 124 Mobility in soil T: Not readily biodegradable D: Not readily biodegradable I: Not readily biodegradable Test data are not available Test data are not available 125 Results of PBT and vpvb assessment The product does not contain any PBT or vpvb substances 126 Other adverse effects Oil products may cause soil and water pollution German water pollution classification (WGK): 1 SECTION 13: Disposal considerations 131 Waste treatment methods Avoid discharge to drain or surface water Contact the local authorities EWC code: Depends on line of business and use, for instance *spent waxes and fats Absorbent/cloth contaminated with the product: EWC code: Absorbents, filter materials, wiping cloths and protective clothing other than those mentioned in Uncleansed packaging is to be disposed of via the local waste-removal scheme Empty, cleansed packaging should be disposed of for recycling SECTION 14: Transport information The product is not covered by the rules for transport of dangerous goods 141 UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards -

7 146 Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code - SECTION 15: Regulatory information 151 Safety, health and environmental regulations/legislation specific for the substance or mixture Special provisions: None 152 Chemical safety assessment Chemical safety assessment has not been performed SECTION 16: Other information Changes have been made in the following sections: Abbreviation explanations: Classification method: H-phrases: Training: 2, 3, 5, 6, 7, 8, 9, 10, 11, 12 DNEL: Derived No Effect Level PBT: Persistent, Bioaccumulative and Toxic PNEC: Predicted No Effect Concentration STOT: Specific Target Organ Toxicity vpvb: Very Persistent and Very Bioaccumulative Test data Calculation based on the hazards of the known components H304 May be fatal if swallowed and enters airways H315 Causes skin irritation H318 Causes serious eye damage H335 May cause respiratory irritation A thorough knowledge of this safety data sheet should be a prerequisite condition Other information: This safety data sheet has been prepared for and applies to this product only It is based on our current knowledge and the information that the supplier was able to provide about the product at the time of preparation The safety data sheet complies with applicable law on preparation of safety data sheets in accordance with 1907/2006/EC (REACH) as subsequently changed!"###$ %&'()"" ###!'*+,- -%!/ ' &345 6