GPS Safety Summary. 1. NAME OF SUBSTANCE Normal technical butyl alcohol.

Transcription

1 Nevinnomysskiy Azot 1 Nizyaeva St., Nevinnomysk-7, Stavropol Territory, , Russia GPS Safety Summary This Product Safety Summary is intended to provide a brief overview of the information on the risk assessment results of the chemical product that we manufacture based on the chemical industry s Global Product Strategy (GPS) to the general public as a social responsibility of a company that manufacture chemical substances. This summary is not intended to provide technical information in case of emergency situations, medical information or information on treatment in case of influence. In addition, it is not intended to be prepared as a document to replace a Safety Data Sheet (SDS) or a risk assessment report like a Chemical Safety Report under the REACH (Registration, Evaluation, Authorization and Restriction of Chemicals) (REACH CSR). 1. NAME OF SUBSTANCE Normal technical butyl alcohol. 2. GENERAL INFORMATION Producer: Nevinnomysskiy Azot. Address: 1 Nizyaeva St., Nevinnomysk-7, Stavropol Territory, , Russia. Tel.: +7 (495) Fax: +7 (86554) nevinazot@eurochem.ru

2 3. CHEMICAL IDENTIFICATION Chemical name Butan-1-ol Public name Butan-1-ol Brand name Normal technical butyl alcohol Customary name n-butanol IUPAC name Butan-1-ol CAS number EC number Synonyms n-butanol, 1-butanol, butanol Molecular formula C 4 H 9 OН Structural formula 4. PRODUCT USES AND CHARACTERISTICS Butan-1-ol used as a solvent in the processes of chemical synthesis and fiber production or as a raw material for producing other chemical products. Butan-1-ol is also used as a vehicle for paint or as a base for brake fluid or fragrances. 5. PHYSICAL/CHEMICAL PROPERTIES Physical state at 20 C and 1013 hpa liquid Melting point/freezing point at 1013 hpa C Boiling point at 1013 hpa 119 C Flash point (in closed crucible) 35 C Vapour pressure at 20 C 10 hpa Partition coefficient at 25 C (LogPow) 1 Water solubility at 25 C 66 g/l Surface tension at 20 C and concentration 1 g/l 69.9 mn/m Auto flammability at 1013 hpa 35 С Flammability Flammable upon ignition Lower flammability limit 1.7% Upper flammability limit 12% Self-ignition temperature at 1013 hpa 355 С Explosiveness Non-explosive Molecular weight g/mol Density at 20 C 0.81 g/cm 3 Viscosity at 20 C mpa s (dynamic) page 2 from 8

3 6. HEALTH INFORMATION Human Health Safety Assessment DNEL (Derived No Effect Level) Acute Toxicity Irritation Sensitization Mutagenicity Carcinogenicity Toxicity after repeated exposure Toxicity for reproduction Workes (long-term local effects, inhalation): 310 mg/m³ General Population (long-term local effects, oral): mg/kg bw/day General Population (long-term local effects, inhalation): 55 mg/m³ Of moderate toxicity after single ingestion. Of low toxicity after short-term skin contact. Practically non-toxic after short-term inhalation. May cause drowsiness or dizziness after shortterm inhalation. Causes skin irritation. May cause serious eye damage. May cause irritation of the respiratory tract. Skin sensitizing effects were not observed. Not considered to be mutagenic. Not considered to be carcinogenic. Not considered to be toxic after repeated exposure. Not considered to be toxic for reproduction. Note: For more information on the health hazards of this substance and recommended protective equipment, please refer to the relevant (M)SDS. 7. ENVIRONMENTAL INFORMATION Environment Safety Assessment Predicted No-Effect Concentration (PNEC) Aquatic Toxicity Persistence and degradability Bioaccumulation potential PNEC aqua (freshwater): mg/l PNEC aqua (marine water): mg/l PNEC aqua (intermittent releases): 2.25 mg/l PNEC sediment (freshwater): mg/kg sediment dw PNEC sediment (marine water): mg/kg sediment dw PNEC soil: mg/kg soil dw PNEC STP: 2476 mg/l With high probability acutely not harmful to aquatic organisms. Readily biodegradable. Significant accumulation in organi sms is not to be expected. page 3 from 8

4 Note: For more information on the environmental hazards of this substance and recommended measures, please refer to the (M)SDS. 8. RECOMMENDATIONS ON RISK MANAGEMENT Closed manufacturing processes, high performance forced-air or local exhaust ventilation at the work zone, use of personal protection equipment. Minimization of quantity of exposed workers. Use of special dispensers and pumps designed to prevent splashes / spills. Effective removal of contaminants. Minimization of manual phases. Avoidance of contact with contaminated tools and objects. Regular cleaning of equipment and work area. Verification of the appropriate use of risk management measures. Ensure high levels of personal hygiene. Inform consumers through labeling. 9. REGULATORY INFORMATION / CLASSIFICATION AND LABELLING 9.1 Classification according to REGULATION (EC) No 1272/2008 Oxidizing liquid: category 3 H226 Skin corrosion / irritation Serious eye damage / eye irritation Specific target organ toxicity - single Specific target organ toxicity - single H315 H318 H335 H Labeling according to REGULATION (EC) No 1272/2008 Hazard pictogramm : GHS02: flame GHS05: corrosion GHS07: exclamation mark Signal word : Danger. page 4 from 8

5 Hazard steatment : H226 : Flammable liquid and vapour. H302 : Harmful if swallowed. H315 : Causes skin irritation. H318 : Causes serious eye damage. H335 : May cause respiratory irritation. H336 : May cause drowsiness or dizziness. Hazard statement P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 : Keep container tightly closed. P240 : Ground/bond container and receiving equipment. P241 : Use explosion-proof P242 : Use only non-sparking tools. P280 : Wear protective gloves/protective clothing/eye protection/face protection. P303+P361+P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P370+P378 : In case of fire: Use to extinguish P403+P235 : Store in a well-ventilated place. Keep cool. P501 : Dispose of contents/container to PBT assessment The substance is not PBT / vpvb. 10. REGISTRATION INFORMATION Normal technical butyl alcohol. Registration number : CONCLUSIONS In the Product Safety Summary for risk calculations used following Exposure scenarios and Process Categories: Identifiers ES1 - M1 Market Sector Titles of exposure scenarios and the related contributing scenarios Manufacture - Manufacture - Manufacture (ERC 1) - Environmental contributing scenario (ERC 1) page 5 from 8

6 Identifiers Market Sector ES2 - C1 PC 1; PC 4; PC 9a; PC 9b; PC 15; PC 18; PC 23; PC 24; PC 31 ES3 - C2 PC 1; PC 4; PC 9a; PC 9b; PC 15; PC 18; PC 23; PC 24; PC 31 ES4 - F1 ES5 - IW1 ES6 - PW1 Titles of exposure scenarios and the related contributing scenarios - Worker contributing scenario (PROC 15) Consumer Use - Consumer Use - Consumer Use (ERC 8d) - Consumer contributing scenario (PC 1) - Consumer contributing scenario (PC 9a) - Consumer contributing scenario (PC 9b) - Consumer contributing scenario (PC 9c) - Consumer contributing scenario (PC 24) - Consumer contributing scenario (PC 31) Consumer Use - Consumer Use - Consumer Use (ERC 8f) - Consumer contributing scenario (PC 1) - Consumer contributing scenario (PC 9a) - Consumer contributing scenario (PC 9b) - Consumer contributing scenario (PC 9c) - Consumer contributing scenario (PC 24) - Consumer contributing scenario (PC 31) Formulation - Formulation - Formulation (ERC 2) - Environmental contributing scenario (ERC 2) - Worker contributing scenario (PROC 5) - Worker contributing scenario (PROC 9) - Worker contributing scenario (PROC 15) Use at industrial site - Use at industrial site - Use at industrial site (ERC 6a) - Environmental contributing scenario (ERC 6a) - Worker contributing scenario (PROC 9) Use by professional worker - Use by professional worker - Use by professional worker (ERC 8f) - Environmental contributing scenario (ERC 8f) page 6 from 8

7 Identifiers ES7 - PW2 ES8 - C3 ES9 - C4 Market Sector Titles of exposure scenarios and the related contributing scenarios - Worker contributing scenario (PROC 5) - Worker contributing scenario (PROC 9) - Worker contributing scenario (PROC 10) - Worker contributing scenario (PROC 11) - Worker contributing scenario (PROC 13) - Worker contributing scenario (PROC 15) - Worker contributing scenario (PROC 19) Use by professional worker - Use by professional worker - Use by professional worker (ERC 8d) - Environmental contributing scenario (ERC 8d) - Worker contributing scenario (PROC 5) - Worker contributing scenario (PROC 9) - Worker contributing scenario (PROC 10) - Worker contributing scenario (PROC 11) - Worker contributing scenario (PROC 13) - Worker contributing scenario (PROC 15) - Worker contributing scenario (PROC 19) Consumer Use - Consumer Use - Consumer Use (ERC 8d) - Consumer contributing scenario (PC 1) - Consumer contributing scenario (PC 24) - Consumer contributing scenario (PC 31) - Consumer contributing scenario (PC 35) Consumer Use - Consumer Use - Consumer Use (ERC 8f) - Consumer contributing scenario PC 1) - Consumer contributing scenario (PC 24) - Consumer contributing scenario (PC 31) - Consumer contributing scenario (PC 35) The risk of normal technical butyl alcohol release to the environment during the performing processes of production, processing and use is hardly probable. Descriptors doses to assess the impact of normal technical butyl alcohol per employee identified for inhalation exposure only. page 7 from 8

8 Thus, GPS safety risk calculations performed only for production, processing, use and disposal of chemicals (in accordance with the ECHA Guidelines on Safety Assessment). The analysis shows that risks could be adequately controlled through the use of standardized technical, organizational measures, which are designed and operated by Nevinnomysskiy Azot. 12. CONTACT DATA For more information on the matter, please contact at: or visit: DATE OF ISSUE Notes: For more information on first aid measures, fire fighting, prevention and elimination of accidents and emergency situations and their consequences, recycling, safe use and transportation and storage rules, refer to the Safety Data Sheet (SDS) for this chemical or chemical products. While the data and information contained herein are presented in good faith and believed to be accurate at the date of printing, it is provided for your guidance only and may be revised in the future. No warranties of any kind, either express or implied, of merchantability, fitness for a particular purpose or of any other nature are made regarding the data or information provided. Further, it is expressly understood that the data and information furnished by EuroChem hereunder are given gratis and EuroChem assumes no obligation or liability whatsoever resulting from use of or reliance on the data and information given. EuroChem makes no commitment to update or correct any information that appears on the Internet. page 8 from 8