Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Printed revision (GB) Version 1.

Transcription

1 ! SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Name of product 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses! Sector of uses [SU] SU22 - Professional uses: Public domain (administration, education, entertainment, services, craftsmen) SU3 - Industrial uses: Uses of substances as such or in preparations at industrial sites Recommended intended purpose(s) Usable as defoaming additon for aqueous cleaning solutions in the range ph < Details of the supplier of the safety data sheet Manufacturer/distributor Advice 1.4. Emergency telephone number Emergency advice Elma Schmidbauer GmbH Gottlieb-Daimler-Str. 17, D Singen (Htwl.) Phone , Fax info@elma-ultrasonic.com Internet Chemie/Labor: chemlab@elma-ultrasonic.com Vergiftungs-Informations-Zentrale Freiburg (Sprache/Language: D, GB) Phone SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to 67/548/EEC or 1999/45/EC Additional hints The product is not classified as dangerous according to Directives 67/548/EEC or 1999/45/EC. Classification according to Regulation (EC) No 1272/2008 [CLP/GHS] Additional hints The product is not classified as dangerous according to Regulation (EC) 1272/2008 [GHS] Label elements Labelling according to Regulation (EC) No 1272/2008 [CLP/GHS] Additional information Remark The product does not require a hazard warning label according to Regulation (EC) No 1272/2008 [GHS] Other hazards Acute Tox. 5 (oral + inhalation) H303 + H333: May be harmful if swallowed or if inhaled. Aquatic Acute 2 H401: Toxic to aquatic life. Page 1/8

2 Results of PBT and vpvb assessment The product does not contain any vpvb-substances according to the recipe. SECTION 3: Composition/ information on ingredients Description Nonfoaming nonionic surfactant. SECTION 4: First aid measures 4.1. Description of first aid measures In case of inhalation In case of inhalation of mist seek medical advice. In the event of symptoms refer for medical treatment. In case of skin contact In case of contact with skin wash off with water. In case of eye contact In the event of persistent symptoms seek medical treatment. In case of contact with eyes rinse thoroughly with water. In case of ingestion If swallowed seek medical advice immediately and show the doctor packing or label. Rinse out mouth and give plenty of water to drink Most important symptoms and effects, both acute and delayed Physician's information / possible symptoms No further informations available Indication of any immediate medical attention and special treatment needed Treatment (Advice to doctor) No further informations available. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Foam Dry powder Carbon dioxide Water spray jet 5.2. Special hazards arising from the substance or mixture In case of fire formation of dangerous gases possible. In the event of fire the following can be released: Carbon monoxide (CO) 5.3. Advice for firefighters Special protective equipment for fire-fighters Do not inhale explosion and/or combustion gases. Page 2/8

3 ! SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel High risk of slipping due to leakage/spillage of product.! For emergency responders Forms slippery surfaces with water. High risk of slipping due to leakage/spillage of product Environmental precautions Do not discharge into the drains or bodies of water Methods and material for containment and cleaning up Take up with absorbent material (e.g. sand, sawdust, general-purpose binder). Flush away residues with water. After taking up the material dispose according to regulation Reference to other sections Informations for safe handling see chapter 7. Informations for personal protective equipment see chapter 8. Informations for disposal see chapter 13.! SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling No special measures necessary if used correctly. General protective measures Avoid contact with eyes and skin Do not inhale aerosols Hygiene measures Provide washing facilities at place of work. Keep away from food and drink. Advice on protection against fire and explosion The product is combustible Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep in closed original container. Further information on storage conditions Keep locked up, out of reach of children Protect from heat and direct solar radiation. Do not keep at temperatures below 5 C. Information on storage stability Storage time: 3 years Specific end use(s) Recommendation(s) for intended use no further Page 3/8

4 SECTION 8: Exposure controls/personal protection 8.1. Control parameters Additional advice Occupational exposure limits: Exposure controls Eye protection safety goggles Limitation and surveillance of the environment Avoid penetration into the subsoil/soil. Do not discharge into surface waters. Appropriate engineering controls Technical exhaustion in case of longtermed exposition in sprayed aerosols.! SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Colour liquid yellowish Odour threshold Important health, safety and environmental information Odour hardly noticeable Value Temperature at Method Remark ph value 7 20 C 10 g/l boiling temperature solidifying range -10 C DIN/ISO 3016 Flash point ca. 200 C DIN/ISO 2592 Flammable (solid) Flammability (gas) Ignition temperature not applicable not applicable Self ignition temperature not spontaneously flammable Lower explosion limit Upper explosion limit Vapour pressure < 0,1 hpa 20 C Relative density 0,97 g/cm3 20 C DIN Vapour density not available Page 4/8

5 Value Temperature at Method Remark Solubility in water 20 C cloudly soluble Solubility/other Partition coefficient n- octanol/water (log P O/W) Decomposition temperature 3,26 > 100 C Viscosity dynamic 50 mpa*s 20 C DIN Solvent content 0 % Vapourisation rate Oxidising properties no Explosive properties no 9.2. Other information No further relevant informations available. SECTION 10: Stability and reactivity Reactivity No hazardous reactions known if used as directed Chemical stability Stable at ambient temperature Possibility of hazardous reactions Reactions with oxidising agents Conditions to avoid Heat and direct solar radiation Incompatible materials Substances to avoid Reactions with oxidising agents Hazardous decomposition products No decomposition if used as directed.! SECTION 11: Toxicological information Information on toxicological effects Acute toxicity/irritation/sensitization Page 5/8

6 Value/Validation Species Method Remark LD50 acute oral > 3930 mg/kg rat OECD 401 LD50 acute dermal No informations available. Skin irritation non-irritant rabbit CESIO Eye irritation non-irritant rabbit eye CESIO Skin sensitization Based on available data, the classification criteria are not met. Subacute Toxicity - Carcinogenicity Value Species Method Validation Mutagenicity Reproduction- Toxicity Carcinogenicity No experimental information on genotoxicity in vitro available. No informations available. No informations available.! Specific target organ toxicity (single exposure) Based on available data, the classification criteria are not met.! Specific target organ toxicity (repeated exposure) No informations available.! Aspiration hazard Based on available data, the classification criteria are not met. Experiences made from practice Has a degreasing effect on the skin.! SECTION 12: Ecological information Toxicity Ecotoxicological effects Value Species Method Validation Fish LC mg/l (96 h) Golden orfe Daphnia EC mg/l (48 h) Daphnia magna Algae EC mg/l (72 h) Desmodesmus subspicatus Bacteria EC50 > 1000 mg/l Pseudomonas putida DIN T Persistence and degradability Biological 75 % (28 d) OECD 301 B degradability The product is readily biodegradable to OECD criteria Bioaccumulative potential not available Page 6/8

7 12.4. Mobility in soil not available Results of PBT and vpvb assessment The product does not contain any vpvb-substances according to the recipe Other adverse effects No further relevant informations available. Additional ecological information Value Method Remark COD 2234 mgo2/g DIN ISO AOX The product does not contain any organically bound halogens according to the recipe.! General regulation Acute aquatic environmental hazards: Aquatic Acute 2 H401: Toxic to aquatic life. Do not allow uncontrolled leakage of product into the environment. This surfactant complies with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. SECTION 13: Disposal considerations Waste treatment methods Waste code No. Name of waste detergents other than those mentioned in Recommendations for the product Remove in accordance with local official regulations. Incinerate in suitable incineration plant, but care for official regulations. Recommendations for packaging Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be taken for reuse. Recommended cleansing agent Water SECTION 14: Transport information ADR/RID IMDG IATA-DGR UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Special precautions for user no Page 7/8

8 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Land and inland navigation transport ADR/RID No dangerous goods as defined by these transport regulations. Marine transport IMDG No hazardous material as defined by the prescriptions. Air transport ICAO/IATA-DGR No hazardous material as defined by the prescriptions.! SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture! Authorizations! Application restrictions! Other regulations (EU) Regulation (EC) No 648/2004 (Detergents regulation). Directive 2012/18/EU, Annex I: not mentioned. VOC standard VOC content 0 % Chemical Safety Assessment For this product a chemical safety assessment has not been carried out.! SECTION 16: Other information! Recommended uses and restrictions National and local regulations concerning chemicals shall be observed. Further information These data are given according to our actual knowledge about this product.this data sheet does not correspond to an assurance by virtue of a contract for properties of the product. Indication of changes: "!" = Data changed compared with the previous version. Previous version: 1.8 Page 8/8