Polyvinyl Alcohol (PVA) solid

Transcription

1 Page 1 Revised edition: Version: Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Product Name: Polyvinyl Alcohol (PVA) solid Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Industrial application. Additive, adhesive, binder, coatings, protective colloid, dispersion aids, raw material Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Tel./Fax.: Internet: Mon-Droguiste.Com 39 Bis Rue Du Moulin Rouge Charmont Sous Barbuise Tel +33 (0) Fax +33 (0) contact@mon-droguiste.com Importer: Emergency No. Emergency No.: ORFILA : SAMU : 15 - Pompiers : 18 - Médecins de garde : 15 Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 Classification according to EC Regulation No. 67/548 or No. 1999/45 This product is not classified as hazardous according to the CLP/GHS Directive. The material is not subject to classification according to EC lists. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 This product does not require classification and labelling as hazardous according to CLP/GHS. Hazard designation: Signal word: Hazard designation: Safety designation: P281 Use personal protective equipment as required. Store in a closed container in a dry place. 2

2 P402+P404 Page Hazardous components for labelling: Other Hazards Composition/Information on Ingredients Substance Mixture Chemical Characterization: polyvinyl alcohol Hazardous Ingredients: Polyvinyl alcohol, completely saponified Methanol (T,F; R11-39/23/24/25; H ); REACH Reg.-No xxxx > 93% < 3% CAS-Nr: EINECS-Nr: EC-Nr: CAS-Nr: EINECS-Nr: EC-Nr: X Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Seek medical attention in case of complaints. Supply fresh air. Consult physician if symptoms persist. Wash with soap and rinse with plenty of water. If irritation continues consult a physician. Rinse open eye for several minutes under running water. Should irritation continue, seek medical advice After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with plenty of water. After swallowing larger amount of product seek medical aid. Symptoms: Contact with dust: causes irritation of eyes mucous membrane, coughing Effects: Indication of any Immediate Medical Attention and special Treatment needed Treatment: Symptomatic treatment (decontamination, vital functions), no specific antidote known. 5. Fire-Fighting Measures 3

3 5. 1. Extinguishing Media Page 3 Suitable extinguishing media: Water mist, extinguishing powder, foam, carbon dioxide Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture Water with full jet Special hazards: Advice for Firefighters Protective equipment: The product is not flammable. Dust can form explosive mixtures with air. In case of fire: hazardous gases/vapors may be released. Wear self-contained respiratory protective device and full protective gear Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Environmental Precautions Avoid contact with skin and eyes. Do not ingest or inhale. Wear protective clothing Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soils, drains and surface water. Contact local authorities if product pollutes soil or vegetation Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Sweep up, then place into a suitable container for disposal. Avoid generating dust. Collect powder using a special dust vacuum cleaner with particle filter and dispose in a adequate resealable container. Do not use compressed air. Protective clothing, see Section 8. Dispose of contaminated material according to Section 13. Avoid contact with eyes and skin. Do not swallow or inhale. Avoid formation of dust. Hygienic measures: Wash hands at the end of work. Preventive skin protection 4

4 recommended Conditions for Safe Storage, including any Incompatibilities Page 4 Storage conditions: Store in tightly sealed containers in a dry and cool room. Requirements for storage areas and containers: Information on fire and explosion protection: Take measures to prevent static electricity discharge. Storage class (VCI): Further Information: Specific End Use(s) Further information: See Section 1.2.; no other uses provided Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): Parameters to be controlled (EC): TRGS 900 Methanol: 200 ppm; 270 mg/m3; 4(II); skin Polyvinyl alcohol TLV: 3 mg/m3 general dust limit inhalable fraction. TLV: 10 mg/m3 (8h) inhalable dust (average value) Peak limit category II (2) BAT (Methanol): 30 mg/g (urine) Methanol: 200 ppm; 270 mg/m3 Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Use local exhaust ventilation in case of dust and/or fume formation. Provide adequate ventilation. Personal Protection General protective measures: Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Respiratory protection: Wear protective mask, particle filter P2 (for solid and liquid particles DIN 3181) if dust occurs. 5

5 Hand protection: Protective glove material: Page 5 Chemical protective gloves (EN 374 (Europe), F739 (US)). Eye protection: Body protection: Safety glasses with protective shields (EN 166). Protective clothing Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Prevent from getting into the soil, surface water and sewage system. Form: Color: Odor: Odor threshold: granules whitish, transparent odorless ph-value: 5-7 Melting temperature: Boiling temperature: Flash point: > 93 C (200 F) Evaporation rate: Flammability (solid, gas): not available Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: 1.19 g/cm3 Solubility in water: Coefficient of variation (n- Octanol/Water): no information available 6

6 Auto-ignition temperature: Page Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects kg/m3 No further information. Stable if used according to specifications. Stable if used according to specifications. Hazardous polymerisation will not occur. Avoid dusting near sources of ignition. Strong acids and strong oxidizing agents. Carbon oxides Acute Toxicity 7

7 LD50, oral: Methanol: mg/kg (rat) Page 7 LD50, dermal: LC50, inhalation: Methanol: mg/kg (rabbit) Methanol: (4h, rat) Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Longterm contact may cause dry skin. Dust may irritate eyes. Dust can irritate throat and respiratory tract thus causing cough. May cause indisposition. No sensitizing effects known. No mutagenic effects known. No negative effects. Polyvinyl alcohol: IARC (3: not classified with regard to the carcinogenity for humans); NTP (not listed); OSHA (not listed); ACGIH (not listed) No data available. Frequent long-term inhalation of dust increases the risk of asthma, pulmonary diseases and skin irritation. Methanol: LC50: mg/l (96h, Lepomis macrochirus) Methanol: EC50: > mg/l (48h, Daphnia magna) no information available Algae toxicity: 8

8 Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Methanol: EC50: mg/l (96h, Algae) No data available. Page 8 This product is neither a PBT or vpvb substance nor does it contain a PBT or vpvb substance. Water hazard class: 1, slightly hazardous Behaviour in sewage systems: Further ecological effects: No ecological problems expected AOX Value: Disposal Considerations Waste Treatment Methods Product: Dispose of according to official national and local regulations. European Waste Code (EWC): Uncleaned packaging: Packaging may be disposed of in the same manner as the product Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. Tunnel no.: 9

9 IMDG Class (sea): Page 9 Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards None Special Precautions for User Not classified as a dangerous good under transport regulations. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 1, slightly hazardous for water Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment has not been carried out for this product. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.