SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

Transcription

1 Section: 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product identifier Product name : Product code : E Use of the Substance/Mixture : Disinfectant Substance type: : Mixture For professional users only. Product dilution information : No dilution information provided. 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Surface disinfectant. Manual process Recommended restrictions on use : Reserved for industrial and professional use. 1.3 Details of the supplier of the safety data sheet Company : Ecolab Ltd. PO Box 11; Winnington Avenue Northwich, Cheshire, United Kingdom CW8 4DX + 44 (0) ccs@ecolab.com 1.4 Emergency telephone number Emergency telephone number Poison Information Centre telephone number : Food & Beverage, Institutional, Agriculture, Textile Hygiene: Northwich: +44 (0) Healthcare Leeds: +44 (0) Healthcare Swansea: +44 (0) : Not Available Date of Compilation/Revision : Version : 1.0 Section: 2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture Classification (REGULATION (EC) No 1272/2008) Eye irritation, Category 2 Specific target organ toxicity - single exposure, Category 3, Respiratory system Acute aquatic toxicity, Category 1 Chronic aquatic toxicity, Category 1 H319 H335 H400 H410 Classification (67/548/EEC, 1999/45/EC) E 1 / 12

2 Xn; HARMFUL R22 N; DANGEROUS FOR THE ENVIRONMENT R31 R36/37 R50/53 For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section Label elements Labelling (REGULATION (EC) No 1272/2008) Hazard pictograms : Signal Word : Warning Hazard Statements : H319 Causes serious eye irritation. H335 May cause respiratory irritation. H410 Very toxic to aquatic life with long lasting effects. Supplemental Hazard Statements Precautionary Statements : EUH031 Contact with acids liberates toxic gas. : Prevention: P280e Wear eye protection/face protection. P273 Avoid release to the environment. Hazardous components which must be listed on the label: troclosene sodium 2.3 Other hazards Mixing this product with acid or ammonia releases chlorine gas. Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.2 Mixtures Hazardous components Chemical Name CAS-No. EC-No. REACH No. troclosene sodium Classification (67/548/EEC) E-N-O-Xi-Xn; R02-R22-R31- R36/37-R08- R50/53 Classification (REGULATION (EC) No 1272/2008) Note G Oxidizing solids Category 2; H272 Acute toxicity Category 4; H302 Eye irritation Category 2; H319 Specific target organ toxicity - single exposure Category 3; H335 Acute aquatic toxicity Concentration: [%] >= 30 - < E 2 / 12

3 Category 1; H400 Chronic aquatic toxicity Category 1; H410 adipic acid Xi; R36 Eye irritation Category 2; H319 >= 25 - < 30 Sodium Carbonate(soda) Xi; R36 Eye irritation Category 2; H319 >= 3 - < 5 For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section 16. Section: 4. FIRST AID MEASURES 4.1 Description of first aid measures In case of eye contact In case of skin contact If swallowed If inhaled : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention. : Rinse with plenty of water. : Rinse mouth. Get medical attention if symptoms occur. Do NOT induce vomiting. : Remove to fresh air. Treat symptomatically. Get medical attention if symptoms occur. 4.2 Most important symptoms and effects, both acute and delayed See Section 11 for more detailed information on health effects and symptoms. 4.3 Indication of immediate medical attention and special treatment needed Treatment : Treat symptomatically. Section: 5. FIREFIGHTING MEASURES 5.1 Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : None known. 5.2 Special hazards arising from the substance or mixture Specific hazards during firefighting Hazardous combustion products : Exposure to decomposition products may be a hazard to health. : Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Sulphur oxides E 3 / 12

4 5.3 Advice for firefighters Oxides of phosphorus Special protective equipment for firefighters Further information : Use personal protective equipment. : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. Section: 6. ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Advice for non-emergency personnel Advice for emergency responders : Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. 6.2 Environmental precautions Environmental precautions : Do not allow contact with soil, surface or ground water. 6.3 Methods and materials for containment and cleaning up Methods for cleaning up : Sweep up and shovel into suitable containers for disposal. 6.4 Reference to other sections See Section 1 for emergency contact information. For personal protection see section 8. See Section 13 for additional waste treatment information. Section: 7. HANDLING AND STORAGE 7.1 Precautions for safe handling Advice on safe handling Hygiene measures : Avoid contact with skin and eyes. Do not breathe dust/fume/gas/mist/vapours/spray. Use only with adequate ventilation. Wash hands thoroughly after handling. Mixing this product with acid or ammonia releases chlorine gas. : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers : Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers. Storage temperature : 0 C to 25 C E 4 / 12

5 7.3 Specific end uses Specific use(s) : Surface disinfectant. Manual process Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters Occupational Exposure Limits Contains no substances with occupational exposure limit values. 8.2 Exposure controls Appropriate engineering controls Engineering measures : Effective exhaust ventilation system Maintain air concentrations below occupational exposure standards. Individual protection measures Hygiene measures Eye/face protection (EN 166) Hand protection (EN 374) Skin and body protection (EN 14605) Respiratory protection (EN 143, 14387) : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. : Safety glasses with side-shields : Gloves : No special protective equipment required. : None required if airborne concentrations are maintained below the exposure limit listed in Exposure Limit Information. Use certified respiratory protection equipment meeting EU requirements(89/656/eec, 89/686/EEC ), or equivalent, when respiratory risks cannot be avoided or sufficiently limited by technical means of collective protection or by measures, methods or procedures of work organization. Environmental exposure controls General advice : Consider the provision of containment around storage vessels. Section: 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Appearance : tablet Colour : white Odour : Chlorine ph : , 1 % Flash point : Not applicable. Odour Threshold E 5 / 12

6 Melting point/freezing point Initial boiling point and boiling range Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapour pressure Relative vapour density Relative density Water solubility Solubility in other solvents Partition coefficient: n- octanol/water Auto-ignition temperature Thermal decomposition Viscosity, kinematic Explosive properties Oxidizing properties : soluble : The substance or mixture is not classified as oxidizing. 9.2 Other information Not applicable and/or not determined for the mixture Section: 10. STABILITY AND REACTIVITY 10.1 Reactivity No dangerous reaction known under conditions of normal use Chemical stability Stable under normal conditions Possibility of hazardous reactions Mixing this product with acid or ammonia releases chlorine gas Conditions to avoid None known Incompatible materials Acids 10.6 Hazardous decomposition products Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) E 6 / 12

7 Sulphur oxides Oxides of phosphorus Section: 11. TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects Information on likely routes of exposure : Eye contact, Skin contact, Inhalation Toxicity Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Carcinogenicity Reproductive effects Germ cell mutagenicity Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration toxicity : Acute toxicity estimate : > 2,000 mg/kg Components Acute oral toxicity : troclosene sodium LD50 rat: 1,500 mg/kg adipic acid LD50 rat: 5,560 mg/kg Sodium Carbonate(soda) LD50 rat: 2,800 mg/kg Components Acute inhalation toxicity : adipic acid 4 h LC50 rat: > 7.7 mg/l Components E 7 / 12

8 Acute dermal toxicity : troclosene sodium LD50 rabbit: > 10,000 mg/kg adipic acid LD50 rabbit: > 7,940 mg/kg Potential Health Effects Eyes Skin Ingestion Inhalation Chronic Exposure : Causes serious eye irritation. : Health injuries are not known or expected under normal use. : Health injuries are not known or expected under normal use. : May cause respiratory tract irritation. May cause nose, throat, and lung irritation. : Health injuries are not known or expected under normal use. Experience with human exposure Eye contact Skin contact Ingestion Inhalation : Redness, Pain, Irritation : No symptoms known or expected. : No symptoms known or expected. : Respiratory irritation, Cough Section: 12. ECOLOGICAL INFORMATION 12.1 Ecotoxicity Environmental Effects Product Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Components Toxicity to daphnia and other aquatic invertebrates Components Toxicity to algae : Very toxic to aquatic life with long lasting effects. : no data available : no data available : no data available : Sodium Carbonate(soda) 48 h EC50 Daphnia: 200 mg/l : adipic acid 96 h EC50: 26.6 mg/l 12.2 Persistence and degradability no data available 12.3 Bioaccumulative potential no data available E 8 / 12

9 12.4 Mobility in soil no data available 12.5 Results of PBT and vpvb assessment Product Assessment : This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vpvb) at levels of 0.1% or higher Other adverse effects no data available Section: 13. DISPOSAL CONSIDERATIONS Dispose of in accordance with the European Directives on waste and hazardous waste.waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities Waste treatment methods Product Contaminated packaging European Waste Catalogue : The product should not be allowed to enter drains, water courses or the soil. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. : * - detergents containing dangerous substances Section: 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (ADR/ADN/RID) 14.1 UN number : Not dangerous goods 14.2 UN proper shipping : Not dangerous goods name 14.3 Transport hazard : Not dangerous goods class(es) 14.4 Packing group : Not dangerous goods 14.5 Environmental hazards : Not dangerous goods 14.6 Special precautions for : Not dangerous goods user Air transport (IATA) 14.1 UN number : Not dangerous goods 14.2 UN proper shipping : Not dangerous goods E 9 / 12

10 name 14.3 Transport hazard : Not dangerous goods class(es) 14.4 Packing group : Not dangerous goods 14.5 Environmental hazards : Not dangerous goods 14.6 Special precautions for : Not dangerous goods user Sea transport (IMDG/IMO) 14.1 UN number : Not dangerous goods 14.2 UN proper shipping : Not dangerous goods name 14.3 Transport hazard : Not dangerous goods class(es) 14.4 Packing group : Not dangerous goods 14.5 Environmental hazards : Not dangerous goods 14.6 Special precautions for : Not dangerous goods user 14.7 Transport in bulk : Not dangerous goods according to Annex II of MARPOL 73/78 and the IBC Code Section: 15. REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture National Regulations Take note of Dir 94/33/EC on the protection of young people at work. Other regulations : The Chemicals (Hazard Information and Packaging for Supply) Regulations. The Control of Substances Hazardous to Health Regulations. Health and Safety at Work Act Chemical Safety Assessment This product contains substances for which Chemical Safety Assessments are still required. Section: 16. OTHER INFORMATION Full text of R-Phrases R02 Risk of explosion by shock, friction, fire or other sources of ignition. R08 Contact with combustible material may cause fire. R22 Harmful if swallowed. R31 Contact with acids liberates toxic gas. R36 Irritating to eyes. R36/37 Irritating to eyes and respiratory system. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Full text of H-Statements H272 H302 May intensify fire; oxidiser. Harmful if swallowed E 10 / 12

11 H319 H335 H400 H410 Causes serious eye irritation. May cause respiratory irritation. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Full text of other abbreviations Prepared by : Regulatory Affairs Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1 thousand. 0.1 = 1 tenth and = 1 thousandth REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. ANNEX: EXPOSURE SCENARIOS DPD+ Substances: The following substances are the lead substances that contribute to the mixture Exposure Scenario according to the DPD+ Rule: Route Substance CAS-No. EINECS-No. Ingestion troclosene sodium Inhalation troclosene sodium Dermal No lead substance Eyes troclosene sodium aquatic environment troclosene sodium To calculate if your downstream Operating Conditions and Risk management Measures are safe, please calculate your risk factor at the website below: Short title of Exposure Scenario : Surface disinfectant. Manual process Use descriptors Main User Groups : Professional uses: Public domain (administration, education, entertainment, services, craftsmen) Sectors of end-use : SU22: Professional uses: Public domain (administration, education, entertainment, services, craftsmen) E 11 / 12

12 Process categories : PROC10: Roller application or brushing PROC8a: Transfer of substance or preparation (charging/ discharging) from/ to vessels/ large containers at non-dedicated facilities Product categories : PC35: Washing and cleaning products (including solvent based products) Environmental Release Categories : ERC8a: Wide dispersive indoor use of processing aids in open systems E 12 / 12