Material Safety Data Sheet

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1 Material Safety Data Sheet 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Identification of the preparation Product use Version # 04 Revision date Company identification 2. HAZARDS IDENTIFICATION Emergency Overview Acute health effects Skin contact Eye contact Inhalation Ingestion Potential health effects Routes of exposure CN633Series Inkjet printing 09-Aug-2011 Hewlett-Packard Australia Pty Ltd Joseph Street Blackburn Victoria 3130 Australia Telephone Hewlett-Packard health effects line (Toll-free within the US) (Direct) HP Customer Care Line (Toll-free within the US) (Direct) hpcustomer.inquiries@hp.com Poison Information Centre telephone number (24 hours) Contact with skin and eyes may result in irritation. Ingestion may result in nausea, vomiting and diarrhea. May cause sensitization of susceptible persons. Any potential hazards are presumed to be due to exposure to the components. Contact with skin may result in irritation. Contact with skin may result in irritation. Contact with eyes may result in irritation. Contact with eyes may result in irritation. Inhalation may result in respiratory irritation. Inhalation may result in respiratory irritation. Ingestion may result in nausea, vomiting and diarrhea. Diethylene glycol Harmful if swallowed. May cause kidney and liver damage. May depress the central nervous system. Potential routes of overexposure to this product are skin and eye contact Inhalation of vapor and ingestion are not expected to be significant routes of exposure for this product under normal use conditions. Complete toxicity data are not available for this specific formulation Carcinogenicity Classification Carbon black is classified by the IARC as a Group 2B carcinogen (the substance is possibly carcinogenic to humans). Carbon black in this preparation, due to its bound form, does not present this carcinogenic risk. None of the other ingredients in this preparation are classified as carcinogens according to ACGIH, EU, IARC, MAK, NTP or OSHA. Australia: Non-hazardous substance. Non-dangerous goods. Not classified. 1 / 5

2 Physical hazards Health hazards Environmental hazards Not classified as a physical hazard. Not classified as a health hazard. Not classified as an environmental hazard. 3. COMPOSITION/INFORMATION ON INGREDIENTS Components CAS # Percent EC-No. Classification Water > < Xi;R36/38 Proprietary < 10 Proprietary Carbon black < Diethylene glycol < Xn;R22 Triethanolamine < Xi;R36/38 Composition comments This ink supply contains an aqueous ink formulation. This product was evaluated according to the criteria of the National Occupational Health and Safety Commission (NOHSC) Australia. 4. FIRST AID MEASURES Inhalation Skin contact Eye contact Ingestion 5. FIRE-FIGHTING MEASURES Flash point Suitable extinguishing media Extinguishing media which must not be used for safety reasons Unusual fire & explosion hazards Specific methods Hazardous combustion products Carbon black is present only in a bound form in this preparation. Move to fresh air. If symptoms persist, get medical attention. Wash affected areas thoroughly with mild soap and water. If irritation persists get medical attention. Do not rub eyes. Immediately flush with large amounts of clean, warm water (low pressure) for at least 15 minutes or until particles are removed. If irritation persists get medical attention. If material is ingested, immediately contact a physician or poison control centre C (200 F) Pensky-Martens Closed Cup CO2, water, dry chemical, or foam None known. Combustion generates toxic fumes of fluoride/fluorine compounds; aldejydes; ketones; potential for acetylene. None established. Refer to section ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions 7. HANDLING AND STORAGE Handling Storage Wear appropriate personal protective equipment. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational exposure limits ACGIH Do not let product enter drains. Do not flush into surface water or sanitary sewer system. Soak up with inert absorbent material. Slowly vacuum or sweep the material into a bag or other sealed container. Dispose of in compliance with federal, state, and local regulations. See also section 13 Disposal considerations. Avoid contact with skin, eyes and clothing. Remove and wash contaminated clothing before re-use. Keep out of the reach of children. Keep away from excessive heat or cold. Store away from strong oxidizers. Components Type Value Carbon black ( ) Triethanolamine ( ) mg/m mg/m3 2 / 5

3 Australia Components Type Value Carbon black ( ) mg/m3 Diethylene glycol ( ) ppm mg/m3 Triethanolamine ( ) mg/m3 Additional exposure data Engineering measures Personal protective equipment Respiratory protection Eye protection Skin and body protection General Hygiene measures Exposure limits have not been established for this product. Use in a well ventilated area. For use other than intended use (such as in the event of a large spill), goggles and respirators may be required. Not required under intended use. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical state Form Color Odor Odour threshold Protected gloves not required under intended use. Use personal protective equipment to minimize exposure to skin and eye. Handle in accordance with good industrial hygiene and safety practice. Liquid Black. ph 9.3 Vapor pressure Vapor density Boiling point Freezing point Melting point Solubility (water) Specific gravity 1 Relative density Flash point Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Auto-ignition temperature Evaporation rate VOC Soluble in water 93.3 C (200 F) Pensky-Martens Closed Cup < 192 g/l 10. STABILITY AND REACTIVITY Chemical stability Materials to avoid Hazardous decomposition products Hazardous polymerization Stable under recommended storage conditions. Incompatible with strong bases and oxidizing agents. Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. aldehydes, ketones, hydrogen fluoride, fluorinated hydrocarbons Will not occur. 11. TOXICOLOGICAL INFORMATION Carcinogenicity IARC Monographs. Overall Evaluation of Carcinogenicity Carbon black is classified as a carcinogen by the IARC (possibly carcinogenic to humans, Group 2B) and by the State of California under Proposition 65. In their evaluations of carbon black, both organizations indicate that exposure to carbon black, per se, does not occur when it remains bound within a product matrix, specifically, rubber, ink, or paint. 2B Possibly carcinogenic to humans. 3 / 5

4 IARC Monographs: Evidence of carcinogenicity in humans Serious eye damage/eye irritation Further information 12. ECOLOGICAL INFORMATION Aquatic toxicity 13. DISPOSAL CONSIDERATIONS Disposal instructions 14. TRANSPORT INFORMATION ADG Further information IATA IMDG Proper shipping name Hazard class UN number Packing group Packaging exceptions RID Inadequate data. This ink formulation has not been tested for toxicological effects. Refer to Section 2 for potential health effects and Section 4 for first aide measures. LC50/96h/Fathead minnows => 750 mg/l Dispose of in compliance with federal, state, and local regulations. HP's Planet Partners (trademark) supplies recycling program enables simple, convenient recycling of HP original inkjet and LaserJet supplies. For more information and to determine if this service is available in your location, please visit Not a dangerous good under DOT, IATA, ADR, IMDG, or RID. Not applicable Not applicable None N/A None 15. REGULATORY INFORMATION Regulatory information Australia HVIC: Listed substance Diethylene glycol (CAS ) 16. OTHER INFORMATION Disclaimer Issue date Manufacturer information All chemical substances in this HP product have been notified or are exempt from notification under chemical substances notification laws in the following countries: US (TSCA), EU (EINECS/ELINCS), Switzerland, Canada (DSL/NDSL), Australia, Japan, Philippines, South Korea, New Zealand, and China. Listed. Listed. This MSDS was prepared in compliance with the NOHSC document "National Code of Practice for the Preparation of Material Safety Data Sheets", This Safety Data Sheet document is provided without charge to customers of Hewlett-Packard Company. Data is the most current known to Hewlett-Packard Company at the time of preparation of this document and is believed to be accurate. It should not be construed as guaranteeing specific properties of the products as described or suitability for a particular application. This document was prepared to the requirements of the jurisdiction specified in Section 1 above and may not meet regulatory requirements in other countries. 09-Aug-2011 Hewlett-Packard Company 1000 NE Circle Boulevard Corvallis, OR US (Direct) (Toll-free within the US) / 5

5 Explanation of abbreviations ACGIH CAS CERCLA CFR COC DOT EPCRA IARC NIOSH NTP OSHA PEL RCRA REC REL SARA STEL TCLP TLV TSCA VOC American Conference of Governmental Industrial Hygienists Chemical Abstracts Service Comprehensive Environmental Response Compensation and Liability Act Code of Federal Regulations Cleveland Open Cup Department of Transportation Emergency Planning and Community Right-to-Know Act (aka SARA) International Agency for Research on Cancer National Institute for Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Resource Conservation and Recovery Act Recommended Recommended Exposure Limit Superfund Amendments and Reauthorization Act of 1986 Short-term exposure limit Toxicity Characteristics Leaching Procedure Threshold Limit Value Toxic Substances Control Act Volatile Organic Compounds 5 / 5