1. Identification of the substance/mixture and of the company/undertaking

Transcription

1 Safety data sheet Page: 1/10 1. Identification of the substance/mixture and of the company/undertaking Product identifier Plurafac LF 220 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: Raw material for the chemical-technical industry Details of the supplier of the safety data sheet Company: BASF SE Ludwigshafen GERMANY Operating Division Care Chemicals Telephone: address: Emergency telephone number International emergency number: Telephone: Hazards Identification Label elements Globally Harmonized System, EU (GHS) Pictogram:

2 Page: 2/10 Signal Word: Warning Hazard Statement: H319 Causes serious eye irritation. Precautionary Statements (Prevention): P280d Wear eye/face protection. P264 Wash with plenty of water and soap thoroughly after handling. Precautionary Statements (Response): P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P311 If eye irritation persists: Call a POISON CENTER or doctor/physician. According to Regulation (EC) No 1272/2008 [CLP] Hazard determining component(s) for labelling: fatty alcohol alkoxylate 4 / Ref.No.: According to Directive 67/548/EEC or 1999/45/EC as in Annex VI of Directive 67/548/EEC Hazard symbol(s) Xi Irritant. R-phrase(s) R36/38 Irritating to eyes and skin. This surfactant complies with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them at their direct request or at the request of a detergent manufacturer. Hazard determining component(s) for labelling: fatty alcohol alkoxylate 4 / Ref.No.: Classification of the substance or mixture According to Regulation (EC) No 1272/2008 [CLP] Eye Dam./Irrit. 2 According to Directive 67/548/EEC or 1999/45/EC Possible Hazards: Irritating to eyes and skin.

3 Page: 3/10 For the classifications not written out in full in this section the full text can be found in section 16. Other hazards According to Regulation (EC) No 1272/2008 [CLP] No specific dangers known, if the regulations/notes for storage and handling are considered. 3. Composition/Information on Ingredients Mixtures Chemical nature fatty alcohol alkoxylate 4 / Ref.No.: in water Hazardous ingredients (GHS) according to Regulation (EC) No. 1272/2008 fatty alcohol alkoxylate 4 / Ref.No.: Content (W/W): >= 90 % - <= 100 Eye Dam./Irrit. 2 % H319 CAS Number: Hazardous ingredients according to Directive 1999/45/EC fatty alcohol alkoxylate 4 / Ref.No.: Content (W/W): >= 90 % - <= 100 % CAS Number: Hazard symbol(s): Xi R-phrase(s): 36/38 For the classifications not written out in full in this section, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, the full text is listed in section First-Aid Measures Description of first aid measures Immediately remove contaminated clothing. If inhaled: Keep patient calm, remove to fresh air, seek medical attention.

4 Page: 4/10 On skin contact: Wash thoroughly with soap and water. On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. On ingestion: Immediately rinse mouth and then drink ml of water, seek medical attention. Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11. Indication of any immediate medical attention and special treatment needed Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Extinguishing media Suitable extinguishing media: water spray, dry powder, foam Special hazards arising from the substance or mixture harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Advice for fire-fighters Special protective equipment: Wear a self-contained breathing apparatus. Further information: The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations. 6. Accidental Release Measures Personal precautions, protective equipment and emergency procedures Use personal protective clothing. Information regarding personal protective measures see, section 8. Environmental precautions Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater. Methods and material for containment and cleaning up

5 Page: 5/10 For large amounts: Pump off product. For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance with regulations. Reference to other sections Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and Handling and Storage Precautions for safe handling Shut containers immediately after taking product because product takes up the humidity of air. Protection against fire and explosion: Take precautionary measures against static discharges. Conditions for safe storage, including any incompatibilities Further information on storage conditions: Containers should be stored tightly sealed in a dry place. The product is not damaged by low temperatures or by frost. Protect from temperatures above: 70 C Properties of the product change irreversibly on exceeding the limit temperature. Specific end use(s) For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed. 8. Exposure Controls/Personal Protection Control parameters Components with workplace control parameters none Exposure controls Personal protective equipment Respiratory protection: Respiratory protection in case of vapour/aerosol release. Particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2) Hand protection: Chemical resistant protective gloves (EN 374) Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): nitrile rubber (NBR) mm coating thickness

6 Page: 6/10 Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing. Manufacturer's directions for use should be observed because of great diversity of types. Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166) Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN in case of splashes or EN ISO in case of dust). General safety and hygiene measures Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. 9. Physical and Chemical Properties Information on basic physical and chemical properties Form: liquid Colour: colourless to yellowish Odour: product specific Odour threshold: not determined ph value: approx. 7 (50 g/l, 20 C) (DIN EN 1262) solidification temperature: approx. 10 C (DIN ISO 2207) Boiling point: > 100 C Flash point: > 100 C (DIN 51758) Evaporation rate: No data available. Flammability: not self-igniting Lower explosion limit: not determined Upper explosion limit: not determined Ignition temperature: > 200 C (DIN 51794) Vapour pressure: < 0.1 hpa (20 C) Density: approx g/cm3 (DIN 51757) (23 C) Relative density: approx (23 C) Relative vapour density (air): not determined Solubility in water: soluble

7 Page: 7/10 Solubility (qualitative) solvent(s): petroleum spirit, ethanol; ethyl alcohol, propan-2-ol; isopropyl alcohol; isopropanol soluble Partitioning coefficient n-octanol/water (log Kow): not determined Self ignition: not self-igniting Thermal decomposition: > 300 C Viscosity, dynamic: approx. 90 mpa.s (25 C) 150 mpa.s (23 C) Explosion hazard: not explosive Fire promoting properties: Based on its structural properties the product is not classified as oxidizing. Other information Miscibility with water: miscible in all proportions 10. Stability and Reactivity Reactivity No hazardous reactions if stored and handled as prescribed/indicated. Corrosion to metals: Corrosive effects to metal are not anticipated. Chemical stability The product is stable if stored and handled as prescribed/indicated. Possibility of hazardous reactions No hazardous reactions when stored and handled according to instructions. Conditions to avoid Avoid humidity. See MSDS section 7 - Handling and storage. Incompatible materials Substances to avoid: caustics, halogens, Alkalines, acids, reactive chemicals Hazardous decomposition products Hazardous decomposition products: No hazardous decomposition products known.

8 Page: 8/ Toxicological Information Information on toxicological effects Acute toxicity Experimental/calculated data: LD50 rat (oral): > 2,000 mg/kg Irritation Experimental/calculated data: Skin corrosion/irritation rabbit: mildly irritating (OECD Guideline 404) Serious eye damage/irritation rabbit: Irritant. (OECD Guideline 405) Other relevant toxicity information The product has not been tested. The statements on toxicology have been derived from products of a similar structure and composition. 12. Ecological Information Toxicity Toxicity to fish: LC50 (96 h) 1-10 mg/l, Leuciscus idus The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Microorganisms/Effect on activated sludge: EC10 > 1,000 mg/l, activated sludge (DEV-L2) Persistence and degradability Elimination information: >= 90 % Bismuth-active substance (mod. OECD 303A) > 60 % BOD of the ThOD (28 d) (OECD 301F; ISO 9408; 92/69/EEC, C.4-D) Readily biodegradable. Bioaccumulative potential Bioaccumulation potential: Accumulation in organisms is not to be expected. Mobility in soil (and other compartments if available) Assessment transport between environmental compartments: The substance will not evaporate into the atmosphere from the water surface.

9 Page: 9/10 Adsorption to solid soil phase is possible. Results of PBT and vpvb assessment According to Annex XIV of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH): The product does not contain a substance fullfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vpvb (very persistent/very bioaccumulative) criteria. Self classification Additional information Sum parameter Chemical oxygen demand (COD): 2,260 mg/g Adsorbable organically-bound halogen (AOX): This product contains no organically-bound halogen. Other ecotoxicological advice: Inhibition of degradation activity in activated sludge is not to be anticipated during correct introduction of low concentrations. 13. Disposal Considerations Waste treatment methods Must be disposed of or incinerated in accordance with local regulations. Contaminated packaging: Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents. 14. Transport Information Land transport ADR RID Not classified as a dangerous good under transport regulations Not classified as a dangerous good under transport regulations Inland waterway transport ADN

10 Page: 10/10 Not classified as a dangerous good under transport regulations Sea transport IMDG Not classified as a dangerous good under transport regulations Air transport IATA/ICAO Not classified as a dangerous good under transport regulations 15. Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture If other regulatory information applies that is not already provided elsewhere in this safety data sheet, then it is described in this subsection. 16. Other Information Full text of the classifications, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, if mentioned in section 2 or 3: Xi Irritant. 36/38 Irritating to eyes and skin. Eye Dam./Irrit. Serious eye damage/eye irritation H319 Causes serious eye irritation. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product's properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed. Vertical lines in the left hand margin indicate an amendment from the previous version.